The influence of superplasticizer on the yield stress of cement pastes with recycled powder(RP)was examined in the study.Four superplasticizers were used to obtain the similar fluidity by adjusting the dosage.The resu...The influence of superplasticizer on the yield stress of cement pastes with recycled powder(RP)was examined in the study.Four superplasticizers were used to obtain the similar fluidity by adjusting the dosage.The results show that the 10%RP decreases the yield stress of paste compared to the reference paste at the same fluidity,but 20%and 30%RP increases the yield stress,ranging from 11 to 599%.The superplasticizer with adsorptive group of phosphate-type minimizes the yield stress of paste than that of polycarboxylate-type,but it made a significant increment in yield stress as the incorporating of RP increased.Besides,the polycarboxylate superplasticizer with the higher molecular weight of side chain and charge density led to lower yield stress.Based on the Yodel model,the yield stress of paste with RP was analyzed by the polymer adsorption and particle packing density of particles to reveal the influence of RP with different superplasticizers on the colloidal interaction and contact network among the particles.The packing density of particles with recycled powder was a little higher than the reference paste,but the higher fraction of fine particles made a stronger PSD effect,which improved the particle contact interaction.On the other hand,due to the higher polymer adsorption of recycled powder than cement,especially for superplasticizer with phosphate group,the average surface coverage was increased,which extended the separation distance,so that colloidal interaction among particles was weaken.展开更多
基金supported by a Youth Program of National Natural Science Foundation of China(Grant No:52008190).
文摘The influence of superplasticizer on the yield stress of cement pastes with recycled powder(RP)was examined in the study.Four superplasticizers were used to obtain the similar fluidity by adjusting the dosage.The results show that the 10%RP decreases the yield stress of paste compared to the reference paste at the same fluidity,but 20%and 30%RP increases the yield stress,ranging from 11 to 599%.The superplasticizer with adsorptive group of phosphate-type minimizes the yield stress of paste than that of polycarboxylate-type,but it made a significant increment in yield stress as the incorporating of RP increased.Besides,the polycarboxylate superplasticizer with the higher molecular weight of side chain and charge density led to lower yield stress.Based on the Yodel model,the yield stress of paste with RP was analyzed by the polymer adsorption and particle packing density of particles to reveal the influence of RP with different superplasticizers on the colloidal interaction and contact network among the particles.The packing density of particles with recycled powder was a little higher than the reference paste,but the higher fraction of fine particles made a stronger PSD effect,which improved the particle contact interaction.On the other hand,due to the higher polymer adsorption of recycled powder than cement,especially for superplasticizer with phosphate group,the average surface coverage was increased,which extended the separation distance,so that colloidal interaction among particles was weaken.
