BaFe12O19 fibers was prepared via an aqueous sol-gel process using Fe（OH）（HCOO）2 synthesized in laboratory and Ba（CH3COO）2 as the original materials and citrate as the chelate. The rheological behaviour of spinn...BaFe12O19 fibers was prepared via an aqueous sol-gel process using Fe（OH）（HCOO）2 synthesized in laboratory and Ba（CH3COO）2 as the original materials and citrate as the chelate. The rheological behaviour of spinnable sol was characterized on rheometer, and the development of gel fibers to barium ferrite fibers was studied by IR, TG and XRD. Morphology observation of the fibers was given on SEM, and the diameter of the obtained fibers was between 5 and 10 um corresponding to different additives. The additives affected the surface tension of the precursor sol which had close relation to the microstructure of fibers. Sucrose and hydroxyethylic cellulose could improve the surface tension while diethanolamine and hexadecylamine reduce that of the decylamine as an additive, well-structured BaFe12O19 precursor sol. And using diethanolamine or hexafibers could be obtained.展开更多
A series of water absorption tests on dried soft rock have been conducted by the intelligent testing system for water absorption tests in deep soft rock, including tests of water absorption with and without pres- sure...A series of water absorption tests on dried soft rock have been conducted by the intelligent testing system for water absorption tests in deep soft rock, including tests of water absorption with and without pres- sure. The results show that the water absorbing capacity of rock with a certain pressure is larger than that of rock without pressure： however, the relationship between the water absorbing percentage and the time can be expressed by w（t） = a（l - e^-bt）. In hi-logarithmic coordinates, the hydrophilic relationship with time in tests with pressure could be characterized by linearity, while they present concave or convex in tests without pressure. Based on the hypothesis that each influential factor is irrelevant and they have a linear correlation with the water absorbing capacity, we calculated the weight coefficient of each factor according to experimental results under different conditions. The calculations demonstrate that the effec- tive porosity, content of smectite and kaolinite are all positively correlated with the water absorption capacity of rock; meanwhile, the fractal dimension of the effective pores presents a negative correlation with the water absorption capacity of rock. The water absorption capacity with pressure increases with increasing illite, chlorite and chlorite/smectite formation and a decrease in illite/smectite formation and the fractal dimension of the effective pores, while it is opposite in tests without pressure. The weight coefficient of smectite is smallest among positive factors, and the fractal dimension of the effective pores is the smallest amongst the negative factors.展开更多
The fractal characteristics of drainage in the ten kongduis of the upper Yellow River were obtained using the box counting dimension, and the evolution stages of the watershed topography were defined by different rang...The fractal characteristics of drainage in the ten kongduis of the upper Yellow River were obtained using the box counting dimension, and the evolution stages of the watershed topography were defined by different ranges of the fractal dimensions of river networks（D_g）. The results show that the fractal scaleless range of the Maobula River is 20–370 m based on a combination of artificial judgment, correlation coefficient test and fitting error. Other kongduis show good fractal characteristics in this fractal scaleless range as well. The box counting dimension can be used as a quantitative index of watershed topography fractal characteristics. The fractal dimension of stream networks is independent of the threshold contributing area used for extracting the drainage networks from the DEM. The values of D_g in the upper ten kongduis are in the range of 1.08-1.14. Both the runoff yield and the sediment yield are positively and linearly related with D_g. The positive relation between the sediment yield and D_g reflects the effect of landform features on sediment yield in the young and/or mature stages of landform evolution of the study area. By revising the critical value of D_g, the value of D_g of the basin in the young evolution stage is less than 1.06, while it is more than 1.06 for the basin in mature or old evolution stage. The upper ten kongduis are in the mature stage of landform evolution.展开更多
基金Supported by National Natural Science Foundation of China(No.50506020)Natural Science Foundation of Tianjin(No.043605211)Young Teacher Foundation of Tianjin University(No.5110103)
文摘BaFe12O19 fibers was prepared via an aqueous sol-gel process using Fe（OH）（HCOO）2 synthesized in laboratory and Ba（CH3COO）2 as the original materials and citrate as the chelate. The rheological behaviour of spinnable sol was characterized on rheometer, and the development of gel fibers to barium ferrite fibers was studied by IR, TG and XRD. Morphology observation of the fibers was given on SEM, and the diameter of the obtained fibers was between 5 and 10 um corresponding to different additives. The additives affected the surface tension of the precursor sol which had close relation to the microstructure of fibers. Sucrose and hydroxyethylic cellulose could improve the surface tension while diethanolamine and hexadecylamine reduce that of the decylamine as an additive, well-structured BaFe12O19 precursor sol. And using diethanolamine or hexafibers could be obtained.
文摘A series of water absorption tests on dried soft rock have been conducted by the intelligent testing system for water absorption tests in deep soft rock, including tests of water absorption with and without pres- sure. The results show that the water absorbing capacity of rock with a certain pressure is larger than that of rock without pressure： however, the relationship between the water absorbing percentage and the time can be expressed by w（t） = a（l - e^-bt）. In hi-logarithmic coordinates, the hydrophilic relationship with time in tests with pressure could be characterized by linearity, while they present concave or convex in tests without pressure. Based on the hypothesis that each influential factor is irrelevant and they have a linear correlation with the water absorbing capacity, we calculated the weight coefficient of each factor according to experimental results under different conditions. The calculations demonstrate that the effec- tive porosity, content of smectite and kaolinite are all positively correlated with the water absorption capacity of rock; meanwhile, the fractal dimension of the effective pores presents a negative correlation with the water absorption capacity of rock. The water absorption capacity with pressure increases with increasing illite, chlorite and chlorite/smectite formation and a decrease in illite/smectite formation and the fractal dimension of the effective pores, while it is opposite in tests without pressure. The weight coefficient of smectite is smallest among positive factors, and the fractal dimension of the effective pores is the smallest amongst the negative factors.
基金National Natural Science Foundation of China(41371036)
文摘The fractal characteristics of drainage in the ten kongduis of the upper Yellow River were obtained using the box counting dimension, and the evolution stages of the watershed topography were defined by different ranges of the fractal dimensions of river networks（D_g）. The results show that the fractal scaleless range of the Maobula River is 20–370 m based on a combination of artificial judgment, correlation coefficient test and fitting error. Other kongduis show good fractal characteristics in this fractal scaleless range as well. The box counting dimension can be used as a quantitative index of watershed topography fractal characteristics. The fractal dimension of stream networks is independent of the threshold contributing area used for extracting the drainage networks from the DEM. The values of D_g in the upper ten kongduis are in the range of 1.08-1.14. Both the runoff yield and the sediment yield are positively and linearly related with D_g. The positive relation between the sediment yield and D_g reflects the effect of landform features on sediment yield in the young and/or mature stages of landform evolution of the study area. By revising the critical value of D_g, the value of D_g of the basin in the young evolution stage is less than 1.06, while it is more than 1.06 for the basin in mature or old evolution stage. The upper ten kongduis are in the mature stage of landform evolution.
