水膨性暂堵剂的制备及表征

以丙烯酰胺、丙烯酸钠为聚合单体,膨润土为填充剂,聚乙二醇二丙烯酸酯、N,N'-亚甲基双丙烯酰胺为交联剂、过硫酸钾与亚硫酸钠为氧化还原引发剂,制备了环保的可降解水膨性暂堵剂并研究了其性能。采用水溶液聚合法,通过改变膨润土、淀粉、交联剂、引发剂量,考察各因素对暂堵剂的性能影响。结果表明,当反应温度50℃,交联剂用量占单体的0.02%,引发剂用量占单体的0.6%,膨润土添加量5%(占总质量的百分数),该条件下合成的暂堵剂韧性较好,吸水率达184 g/g,19 h完全降解。在原有配方中分别加AMPS、淀粉以提高暂堵剂降解速度,并通过SEM对暂堵剂进行表征。

锂皂石的人工合成及其结构和性能的研究

采用碱金属硅酸盐、天然粘土为原料以水热反应制备了在水分散状态下具有优异透明度的合成锂皂石。该产物具有优越的水膨润性和较大的增粘速度。用X射线衍射、差热分析对合成锂皂石的结构特征进行了研究,对其结构特征和胶体性能的关系作了探讨。提出了粘土积层不规则性的测定及计算方法。

Optimization of Channel Structure of Alkaline Water Electrolyzer by Using an Expanded Mesh as a Bipolar Plate

Alkaline water electrolysis(AWE)is the most mature technology for hydrogen production by water electrolysis.Alkaline water electrolyzer consists of multiple electrolysis cells,and a single cell consists of a diaphragm,electrodes,bipolar plates and end plates,etc.The existing industrial bipolar plate channel is concave-convex structure,which is manufactured by complicated and high-cost mold punching.This structure still results in uneven electrolyte flow and low current density in the electrolytic cell,further increasing in energy consumption and cost of AWE.Thereby,in this article,the electrochemical and flow model is firstly constructed,based on the existing industrial concave and convex flow channel structure of bipolar plate,to study the current density,electrolyte flow and bubble distribution in the electrolysis cell.The reliability of the model was verified by comparison with experimental data in literature.Among which,the electrochemical current density affects the bubble yield,on the other hand,the generated bubbles cover the electrode surface,affecting the active specific surface area and ohmic resistance,which in turn affects the electrochemical reaction.The result indicates that the flow velocity near the bottom of the concave ball approaches zero,while the flow velocity on the convex ball surface is significantly higher.Additionally,vortices are observed within the flow channel structure,leading to an uneven distribution of electrolyte.Next,modelling is used to optimize the bipolar plate structure of AWE by simulating the electrochemistry and fluid flow performances of four kinds of structures,namely,concave and convex,rhombus,wedge and expanded mesh,in the bipolar plate of alkaline water electrolyzer.The results show that the expanded mesh channel structure has the largest current density of 3330 A/m^(2)and electrolyte flow velocity of 0.507 m/s in the electrolytic cell.Under the same current density,the electrolytic cell with the expanded mesh runner structure has the smallest potential and energy consumption.This work provides a useful guide for the comprehensive understanding and optimization of channel structures,and a theoretical basis for the design of large-scale electrolyzer.

储层改造可降解暂堵剂的制备及表征

采用水溶液聚合法,以丙烯酰胺（AM）、丙烯酸钠为聚合单体,膨润土为填充剂,聚乙二醇二丙烯酸酯（PEGDA）为交联剂、过硫酸钾与亚硫酸钠为氧化还原引发剂制备了一种暂堵剂。考察了膨润土质量分数、交联剂质量分数、引发剂质量分数、丙烯酸中和度对暂堵剂性能的影响,采用FTIR和SEM对聚合物进行了表征。结果表明：当反应温度50℃、PEGDA质量分数0.02%（以单体质量为基准,下同）、引发剂质量分数0.6%（以单体质量为基准,下同）、膨润土质量分数5%（以总质量为基准,下同）、丙烯酸中和度80%时,合成的暂堵剂性能最好,吸水倍率达184 g/g,80℃水浴下,21 h完全降解。另外,2-丙烯酰胺-2-甲基丙磺酸（AMPS）和磺化沥青的引入提高了暂堵剂耐盐性及降解速度,岩心封堵实验表明封堵效果好。

Effect of suction change on water content and total volume of an expansive clay

A laboratory study was carried out on both natural and compacted specimens to investigate the complex soil-water interaction in an unsaturated expansive clay. The laboratory study includes the measurement of soil-water characteristic curves, 1D free swelling tests, measurement of swelling pressure and shrinkage tests. The test results revealed that the air-entry value of the natural specimen was quite low due to cracks and fissures present. The hydraulic hysteresis of the natural specimen was relatively insignificant as compared with the compacted specimen. Within a suction range 0 to 500 kPa, a bilinear relationship between free swelling strain (or swelling pressure) and initial soil suction was observed for both the natural and compacted specimens. As a result of over-consolidation and secondary structures such as cementation and cracks, the natural specimens exhibited significant lower swelling (or swelling pressure) than the compacted specimen. The change of matric suction exerts a more significant effect on the water phase than on the soil skeleton for this expansive clay.

Stability of long trench in soft soils by bentonite-water slurry

A series of centrifuge model tests exploring the effects of different types of slurry on long-trench stability in soft clay were conducted. The influence of groundwater conditions relative to trench stability was examined by constructing long trenches using different slurries. The soil deformation and surface settlement induced by the excavation of the trench are found to be closely related to slurry type and excavation depth of the long trench. Increasing the bentonite concentration of the slurry has beneficial effects on stability: 1) larger particles can improve local and global stability in cases where filter cakes do not form, and 2) larger viscosity can promote filter cake formation on the walls of long trenches excavated in soft clay and enhance their stability.

Synthesis and property of temperature and pH sensitive xanthan–MA/PNIPAAm hydrogels

A novel class of xanthan-maleic anhydride (Xan-MA)/poly(N-isopropylacrylamide) hybrid hydrogels was designed and synthesized by solution polymerization. The xanthan-based precursor (Xan-MA) was prepared by substituting the hydroxyl groups in Xan by MA. This Xan-MA precursor was then polymerized with a known temperature sensitive precursor (N-isopropylacrylamide, NIPAAm) to form hybrid hydrogels with a series range of composition ratio of Xan-MA to NIPAAm precursors. These smart hydrogels were characterized by Fourier transform infrared spectroscopy for structural determination, differential scanning calorimertry for thermal property. And maximum swelling ratio, swelling kinetics and temperature response kinetics were studied. The data obtained clearly show that these smart hydrogels are responsive to the external changes of temperature as well as pH value. The magnitudes of smart and hydrogel properties of these hybrid hydrogels depend on the feed composition ratio of the two precursors. With the increase of the content of Xan-MA the maximum swelling ratio, reswelling ratio and thermo-sensitivities increase, and the feed composition ratio of Xan-MA/NIPAAm increases the maximum swelling ratio augment from 13.88 to 23.21. From XMN0, XMN1, XMN3 to XMN5, the lower critical solution temperatures (LCSTs) are 33.02, 36.15, 40.28 and 41.92 ℃, respectively. By changing the composition ratio of these two precursors, the LCST of the hybrid hydrogels could also be adjusted to be or near the body temperature for the potential applications in bioengineering and biotechnology fields.

Consolidation behavior of the expansive clay treated with cement and zeolite

The expansive clays are extremely sensitive to the slight moisture alteration,exhibiting sequentially volume change.Uneven settlement of the buildings and infrastructures underlying expansive soil is a critical challenge that geotechnical engineers have to deal with.Therefore,the objective of this study is to assess the alteration in the compressibility behavior of expansive clay respecting partial replacement of cement by zeolite in cemented samples.For this purpose,7 and 28 d cured samples treated with 6%,8%,10%,and 12%cement addition and 0,10%,30%,50%,70%,and 90%cement replacement by zeolite were investigated through Atterberg limit and a series of one-dimensional consolidation tests to evaluate the consistency limits and compressibility alteration.The liquid limits of the soil samples indicated a decremental trend as the cement content rose.Afterward,the increase of zeolite replacement up to 30%in each specific cement content diminished liquid limit to its lowest value.Further increment of zeolite replacement increased the liquid limit of the soil-binder mixtures.The lowest plasticity index was also achieved at the 30%zeolite replacement percentage;hence,the lowest swelling potential would be resulted,concerning an indirect classification.The results of the consolidation experimentations disclosed that zeolite replacement had adverse influence on consolidation parameters of cemented samples such as compression index,swell index,coefficient of compressibility,coefficient of volume compressibility,and coefficient of consolidation after 7 d of curing whereas after 28 d of curing,the 30%zeolite-replaced samples represented the best consolidation parameters.Eventually,it can be stated that the addition of cement alongside the partial substitution of cement by zeolite can be a beneficial strategy for the geo-environmental targets of this study.

Swelling Properties of Water-Swelling Materials Exposed to Organic Water Pollution

A water-swelling material is one of the rubbery impermeable materials which mixed synthetic resin elastomers as a base material, high absorbency polymers, filler and solvents. In this study, swelling characteristics of the water-swelling material on the water polluted with COD and BOD, as an impermeable material at coastal landfill sites, are examined by laboratory swelling ratio test. Furthermore, the factor in which it influences the swelling pressure of water-swelling material is clarified by measuring the swelling pressure. As the results, the COD nor the BOD concentrations in the soaked water influence the swelling ratio of the water-swelling material. When the thicknesses of water-swelling material are 2 mm and 3 mm, the maximum swelling pressure of 0.5 MPa or more that corresponds to hydraulic pressure by depth of 50 m is possessed.

Stability analysis of slopes of expansive soils considering rainfall effect

Typical failure types of slopes of expansive soils are divided to two kinds： slip in surface layer and slip in shallow layer. Based on total strength law of expansive soils, the relationship between its water content and shear strength inculding cohesion and friction angle, was studied in detail. Acoording to change of water content and depth effect during rainfall, distribution of shear strength in slopes of expansive soils was analyzed. Finally, with a slope of expansive soils in Nanning city of Guangxi Autonomous Region of China as a case, safety factor and slip surface was studied.

Development of a novel modified EGSB reactor for municipal sewage treatment at ambient temperatures

A novel modified expanded granular sludge bed(EGSBm) reactor was developed for anaerobic treatment of municipal sewage with mixed liquid recirculation instead of effluent recirculation commonly adopted by a conventional EGSB(EGSBc) reactor.Performances of these two reactors were compared in treating municipal sewage at ambient temperatures ranging from 8 to 26 ℃.At an upflow liquid velocity(Vup) of 10.3 m/h,the mean concentrations of filtrated COD(CODfilt) and COD of the EGSBm effluent were determined to be 59.4 and 95.9 mg/L,respectively,which were significantly lower than those of the EGSBc effluent operated under identical experimental conditions.When the organic loading rate was suddenly increased from 1.2 to 7.2 kg COD/(m3·d),the EGSBm regained the removal efficiency of previous operation phase in 10 d.Hydrodynamic characteristics of the reactors were compared using the residence time distribution(RTD) model.It was found that the treatment efficiency of EGSBm kept increasing as the Vup increased.The polymerase Chain Reaction-Denaturing Gradient Gel Electrophoresis(PCR-DGGE) technique was used to analyze the microbial diversity in EGSBm.Fingerprinting pattern indicated that some species in the inoculating sludge were still reserved in the granular sludge of EGSBm,moreover,several new species occurred.

ELASTOPLASTIC ANALYSIS OF THICK-WALLCYLINDER CONSIDERING THE MATERIAL'S DILATANCY CHARACTER

Impermeable bentonite or its mixtures have been proposed as candidate materials to be used in the geotechnical disposal of radioactive nuclear waste. These materials are filled in the space between a canister containing radioactive nuclear waste and an underground chamber to absorb the radionuclide emitting from the canister and simultaneously retard its migration accompanying the perrneation of underground water to prevent the surrounding environment from po1lution. On the basis of the established elastoplastic strain-hardening mechanical model considering the material’s dilatancy character,the authors carry out the stress-strain analysis of a thick-wa1l cylinder in a plane strain state subJected to a pressure difference between internal and external pressures. The analysis may be expected to be a theoretical basis for developing a coupled shear and permeability test apparatus for conducting a permeability test along a sheared plane in a specimen. The apparatus will be used to study the effects of shear strain on the variation of geotechnical materials’ permeability coefficient in order to evaluate the influence of shear strain caused by nonuniform deformation and/or earthquake on the long-term safety of the disposal system of radioactive nuclear waste. The theoretlcal analysls methods in this paper can be directly spread to the analysis of the deformation and stability of tunnels or roadways driven in soft soils or high moisture-bearing soft rocks.

Exact Solutions of Atmospheric(2+1)-Dimensional Nonlinear Incompressible Non-hydrostatic Boussinesq Equations

Exact solutions of the atmospheric(2+1)-dimensional nonlinear incompressible non-hydrostatic Boussinesq(INHB) equations are researched by Combining function expansion and symmetry method. By function expansion, several expansion coefficient equations are derived. Symmetries and similarity solutions are researched in order to obtain exact solutions of the INHB equations. Three types of symmetry reduction equations and similarity solutions for the expansion coefficient equations are proposed. Non-traveling wave solutions for the INHB equations are obtained by symmetries of the expansion coefficient equations. Making traveling wave transformations on expansion coefficient equations, we demonstrate some traveling wave solutions of the INHB equations. The evolutions on the wind velocities, temperature perturbation and pressure perturbation are demonstrated by figures, which demonstrate the periodic evolutions with time and space.