The paper reports the effects of surface fractal structures on the rheological behavior and combustion kinetics of raw brown coal and three modified coal water slurries （CWSs）. The results show that the fractal stru...The paper reports the effects of surface fractal structures on the rheological behavior and combustion kinetics of raw brown coal and three modified coal water slurries （CWSs）. The results show that the fractal structures and physicochemical properties of samples are dependent on various modification processes. The apparent viscosities of the coal water slurries increase with increasing surface fractal dimensions （D）, especially with decreasing shear rates. Fur- thermore, it has been proved that the ignition temperatures and apparent activation energies of modified CWSs are lower than that of raw coal water slurry. Compared with the traditional qualitative analysis of the effect of pore structures on CWSs properties, D can more efficiently indicate the quantificational effect of pore structures on the rheological behavior and combustion kinetics of CWSs.展开更多
A series of zeolites,including USY zeolites without sodium,Na-USY at different Na contents,La-USY with different rare earth（RE） contents and La-Na-USY with RE and Na were prepared by an ion exchange method.They were...A series of zeolites,including USY zeolites without sodium,Na-USY at different Na contents,La-USY with different rare earth（RE） contents and La-Na-USY with RE and Na were prepared by an ion exchange method.They were investigated to understand the activation barriers for the destruction of Y zeolite structure under hydrothermal treatment and the effect of V using the solid-state kinetic model.The results showed that the pathways for Y zeolite destruction were dealumination,desiliconization and the disappearance of La-O bonds.Zeolites were destroyed by steam through acid hydrolysis,which was accelerated by V.In addition,Na and V exerted a synergistic effect on the framework destruction,and the formation of NaOH was the rate-determining step.The presence of RE elements decreased hydrolysis and stabilized the structure of the zeolites.The interaction between V and RE destroyed zeolite structure by eliminating the stabilizing La-O[RE-OH-RE]^（5＋）bridges in the sodalite cages.展开更多
This paper numerically investigates the influence of separation variation of the outriggers on the hydrodynamic performance of a high speed trimaran （HST） aiming at improving its applicability in diverse realistic d...This paper numerically investigates the influence of separation variation of the outriggers on the hydrodynamic performance of a high speed trimaran （HST） aiming at improving its applicability in diverse realistic disciplines. The present investigation was performed within the framework of the 2-D slender body method （SBM） by calculating the resistance of three symmetric trimaran series moving in a calm free surface of deep water. Each trimaran series comprises of 4681 configurations generated by considering 151 staggers （-50%≤a≤＋ 100%）, and 31 separations （100%≤β≤400%） for 81 Froude numbers （0.20≤Fn≤ 1.0）. In developing the three trimaran series, Wigley-st. AMECRC-09, and NPL-4a models were used separately for both the main and side hulls of each individu;d series models. A computer macro named Tri-PL was created using the Visual Basic for Applications~. Tri-PL~ sequentially interfaced Maxsurfe then Hullspeed to generate the models of the three trimaran series together with their detailed hydrostatic particulars, followed by their resistance components. The numerical results were partially validated against the available published numerical calculations and experimental results, to benchmark the Tri-PL macro and hence to rely on the analysis outcomes. A graph template was creaLed within the framework of SigmaPlot to visualize the significant results of the Tri-PL properlv.展开更多
The main phase transition temperature of a lipid membrane, which is vital for its biomedical applications such as controllable drug release, can be regulated by encapsulating hydrophobic nanoparticles into the membran...The main phase transition temperature of a lipid membrane, which is vital for its biomedical applications such as controllable drug release, can be regulated by encapsulating hydrophobic nanoparticles into the membrane. However, the exact relationship between surface properties of the encapsulating nanoparticles and the main phase transition temperature of a lipid membrane is far from clear. In the present work we performed coarse-grained molecular dynamics simulations to meet this end. The results show the surface roughness of nanoparticles and the density of surface-modifying molecules on the nanoparticles are responsible for the regulation. Increasing the surface roughness of the nanoparticles increases the main phase transition temperature of the lipid membrane, whereas it can be decreased in a nonlinear way via increasing the density of surface-modifying molecules on the nanoparticles. The results may provide insights for understanding recent experimental studies and promote the applications of nanoparticles in controllable drug release by regulating the main phase transition temperature of lipid vesicles.展开更多
We investigate an electron transport bilayer fabricated at 〈110℃ to form all low-temperature processed, thermally stable, efficient perovskite solar cells with negligible hysteresis. The components of the bilayer cr...We investigate an electron transport bilayer fabricated at 〈110℃ to form all low-temperature processed, thermally stable, efficient perovskite solar cells with negligible hysteresis. The components of the bilayer create a symbiosis that results in improved devices compared with either of the components being used in isolation. A sol-gel derived ZnO layer facilitates improved energy level alignment and enhanced charge carrier extraction and a [6,6]-phenyl-C61-butyric acid methyl ester （PCBM） layer to reduce hysteresis and enhance perovskite thermal stability. The creation of a bilayer structure allows materials that are inherently unsuitable to be in contact with the perovskite active layer to be used in efficient devices through simple surface modification strategies.展开更多
文摘The paper reports the effects of surface fractal structures on the rheological behavior and combustion kinetics of raw brown coal and three modified coal water slurries （CWSs）. The results show that the fractal structures and physicochemical properties of samples are dependent on various modification processes. The apparent viscosities of the coal water slurries increase with increasing surface fractal dimensions （D）, especially with decreasing shear rates. Fur- thermore, it has been proved that the ignition temperatures and apparent activation energies of modified CWSs are lower than that of raw coal water slurry. Compared with the traditional qualitative analysis of the effect of pore structures on CWSs properties, D can more efficiently indicate the quantificational effect of pore structures on the rheological behavior and combustion kinetics of CWSs.
基金supported by the Exploratory Research Program of Petrochemical Research Institute,PetroChina~~
文摘A series of zeolites,including USY zeolites without sodium,Na-USY at different Na contents,La-USY with different rare earth（RE） contents and La-Na-USY with RE and Na were prepared by an ion exchange method.They were investigated to understand the activation barriers for the destruction of Y zeolite structure under hydrothermal treatment and the effect of V using the solid-state kinetic model.The results showed that the pathways for Y zeolite destruction were dealumination,desiliconization and the disappearance of La-O bonds.Zeolites were destroyed by steam through acid hydrolysis,which was accelerated by V.In addition,Na and V exerted a synergistic effect on the framework destruction,and the formation of NaOH was the rate-determining step.The presence of RE elements decreased hydrolysis and stabilized the structure of the zeolites.The interaction between V and RE destroyed zeolite structure by eliminating the stabilizing La-O[RE-OH-RE]^（5＋）bridges in the sodalite cages.
文摘This paper numerically investigates the influence of separation variation of the outriggers on the hydrodynamic performance of a high speed trimaran （HST） aiming at improving its applicability in diverse realistic disciplines. The present investigation was performed within the framework of the 2-D slender body method （SBM） by calculating the resistance of three symmetric trimaran series moving in a calm free surface of deep water. Each trimaran series comprises of 4681 configurations generated by considering 151 staggers （-50%≤a≤＋ 100%）, and 31 separations （100%≤β≤400%） for 81 Froude numbers （0.20≤Fn≤ 1.0）. In developing the three trimaran series, Wigley-st. AMECRC-09, and NPL-4a models were used separately for both the main and side hulls of each individu;d series models. A computer macro named Tri-PL was created using the Visual Basic for Applications~. Tri-PL~ sequentially interfaced Maxsurfe then Hullspeed to generate the models of the three trimaran series together with their detailed hydrostatic particulars, followed by their resistance components. The numerical results were partially validated against the available published numerical calculations and experimental results, to benchmark the Tri-PL macro and hence to rely on the analysis outcomes. A graph template was creaLed within the framework of SigmaPlot to visualize the significant results of the Tri-PL properlv.
文摘The main phase transition temperature of a lipid membrane, which is vital for its biomedical applications such as controllable drug release, can be regulated by encapsulating hydrophobic nanoparticles into the membrane. However, the exact relationship between surface properties of the encapsulating nanoparticles and the main phase transition temperature of a lipid membrane is far from clear. In the present work we performed coarse-grained molecular dynamics simulations to meet this end. The results show the surface roughness of nanoparticles and the density of surface-modifying molecules on the nanoparticles are responsible for the regulation. Increasing the surface roughness of the nanoparticles increases the main phase transition temperature of the lipid membrane, whereas it can be decreased in a nonlinear way via increasing the density of surface-modifying molecules on the nanoparticles. The results may provide insights for understanding recent experimental studies and promote the applications of nanoparticles in controllable drug release by regulating the main phase transition temperature of lipid vesicles.
基金the China Scholarship Council for financial support for PhD studiessupport through the EPSRC Centre for Doctoral Training in Plastic Electronics(EP/L016702/1)
文摘We investigate an electron transport bilayer fabricated at 〈110℃ to form all low-temperature processed, thermally stable, efficient perovskite solar cells with negligible hysteresis. The components of the bilayer create a symbiosis that results in improved devices compared with either of the components being used in isolation. A sol-gel derived ZnO layer facilitates improved energy level alignment and enhanced charge carrier extraction and a [6,6]-phenyl-C61-butyric acid methyl ester （PCBM） layer to reduce hysteresis and enhance perovskite thermal stability. The creation of a bilayer structure allows materials that are inherently unsuitable to be in contact with the perovskite active layer to be used in efficient devices through simple surface modification strategies.
