为探索脉冲爆轰水冲压发动机水下工作时导水器内燃气射流发展特性,利用可燃气体的爆轰在水下受限空间内产生脉动气泡,对爆轰管在圆筒形受限空间内的水下爆轰燃气射流进行了数值仿真与实验验证。基于雷诺时均基本方程组与k-ε两方程模型...为探索脉冲爆轰水冲压发动机水下工作时导水器内燃气射流发展特性,利用可燃气体的爆轰在水下受限空间内产生脉动气泡,对爆轰管在圆筒形受限空间内的水下爆轰燃气射流进行了数值仿真与实验验证。基于雷诺时均基本方程组与k-ε两方程模型耦合流体体积气液界面追踪方法的相输运方程建立受限空间中水下单次燃气射流流场流动模型,使用OpenFOAM中的Compressible Inter Foam求解器对受限空间中脉冲爆轰燃气射流进行数值求解。结果表明:受限空间对水下爆轰的前导激波的影响较小,前导激波幅值与自由空间相比变化不大,由爆轰燃气射流所引起的压力扰动大幅升高且持续时间明显增加,受限空间中各处压力显著高于受限空间之外;受限空间中燃气泡的脉动周期延长至60 ms左右,然而受限空间径向尺寸对燃气泡的脉动周期影响较小。可见,受限空间可提高水下爆轰管出口近场压力并延长燃气射流作用时间,研究结果对脉冲爆轰水冲压发动机推力性能提升方法研究具有重要指导作用。展开更多
Hydrogen, serving as a clean, sustainable energy source, may be mainly produced from electrolysis water. Herein, we report cobalt disulphide encapsulated in self-catalyzed carbon nanotubes (S, N-CNTs/ CoS2@Co) servi...Hydrogen, serving as a clean, sustainable energy source, may be mainly produced from electrolysis water. Herein, we report cobalt disulphide encapsulated in self-catalyzed carbon nanotubes (S, N-CNTs/ CoS2@Co) serving as a bifunctional catalyst, which exhibits excellent hydrogen evolution reaction perfor-mance (10.0 mAcm^-2 at 0.112 V, and low Tafel slope for 104.9 mV dec^-1 ) and oxygen evolution reaction performance (10.0 mAcm^-2 at 1.57 V, and low Tafel slope for 76.1 mV dec^-1), meanwbile with a strong stability at various current densities. In-depth study reveals that the excellent catalytic properties can be mainly attributed to the increased catalytic sites induced by S, N co-doping, the improved electronic con-ductivity derived from the carbon nanotubes, and Mott-Schottky effect between the metal cobalt and semiconductive cobalt disulfide. Notably, when the bifunctional catalysts are applied to overall water splitting, a low potential of 1.633 V at the current density of 10.0 mAcm^-2 is achieved, which can com-pete with the precious metal catalyst benchmarks in alkaline media, demonstrating its promising prac-ticability in the realistic water splitting application. This work elucidates a practicable way to the design of transition metal and nano-carbon composite catalysts for a broad application in the fields of energy chemistry.展开更多
文摘为探索脉冲爆轰水冲压发动机水下工作时导水器内燃气射流发展特性,利用可燃气体的爆轰在水下受限空间内产生脉动气泡,对爆轰管在圆筒形受限空间内的水下爆轰燃气射流进行了数值仿真与实验验证。基于雷诺时均基本方程组与k-ε两方程模型耦合流体体积气液界面追踪方法的相输运方程建立受限空间中水下单次燃气射流流场流动模型,使用OpenFOAM中的Compressible Inter Foam求解器对受限空间中脉冲爆轰燃气射流进行数值求解。结果表明:受限空间对水下爆轰的前导激波的影响较小,前导激波幅值与自由空间相比变化不大,由爆轰燃气射流所引起的压力扰动大幅升高且持续时间明显增加,受限空间中各处压力显著高于受限空间之外;受限空间中燃气泡的脉动周期延长至60 ms左右,然而受限空间径向尺寸对燃气泡的脉动周期影响较小。可见,受限空间可提高水下爆轰管出口近场压力并延长燃气射流作用时间,研究结果对脉冲爆轰水冲压发动机推力性能提升方法研究具有重要指导作用。
基金financially supported by the National Natural Science Foundation of China(21576056 and 21576057)Guangdong Natural Science Foundation(2017A030311016)+4 种基金Major Scientific Project of Guangdong University(2017KZDXM059)Science and Technology Research Project of Guangdong Province(2016A010103043)Science and Technology Research Project of Guangzhou(201607010232)Guangzhou University’s 2017 Training Program for Young Top-Notch Personnel(BJ201704)Australian Research Council(ARC)through Discovery Early Career Researcher Award(DE150101306)and Linkage Project(LP160100927)
文摘Hydrogen, serving as a clean, sustainable energy source, may be mainly produced from electrolysis water. Herein, we report cobalt disulphide encapsulated in self-catalyzed carbon nanotubes (S, N-CNTs/ CoS2@Co) serving as a bifunctional catalyst, which exhibits excellent hydrogen evolution reaction perfor-mance (10.0 mAcm^-2 at 0.112 V, and low Tafel slope for 104.9 mV dec^-1 ) and oxygen evolution reaction performance (10.0 mAcm^-2 at 1.57 V, and low Tafel slope for 76.1 mV dec^-1), meanwbile with a strong stability at various current densities. In-depth study reveals that the excellent catalytic properties can be mainly attributed to the increased catalytic sites induced by S, N co-doping, the improved electronic con-ductivity derived from the carbon nanotubes, and Mott-Schottky effect between the metal cobalt and semiconductive cobalt disulfide. Notably, when the bifunctional catalysts are applied to overall water splitting, a low potential of 1.633 V at the current density of 10.0 mAcm^-2 is achieved, which can com-pete with the precious metal catalyst benchmarks in alkaline media, demonstrating its promising prac-ticability in the realistic water splitting application. This work elucidates a practicable way to the design of transition metal and nano-carbon composite catalysts for a broad application in the fields of energy chemistry.