水-力作用下黏土孔隙结构演化规律研究进展

黏土的微结构直接决定宏观水-力学特性,然而现阶段绝大多数模型都是基于宏观参数所建立,由于缺乏微观机制的支撑,己经难以满足科研和工程需求。因此开展孔隙结构演化研究可以加深对非饱和土复杂水-力学特性的认识。在详细阐述黏土的孔径分布特征及双孔模型的基础上,全面回顾和总结了近年来水-力作用下黏土孔隙结构演化规律的研究成果与最新进展,并进行了相关讨论。结果表明:考虑颗粒集聚体的双孔模型(集聚体间孔隙与集聚体内孔隙)可以更好地解释黏土复杂的水-力学特性。水-力作用对黏土孔隙结构的影响机制不同,根据文献试验数据和理论分析初步总结出水-力作用下土孔隙结构的演化规律。外力荷载只显著影响集聚体间孔隙,对集聚体内孔隙基本不影响;含水率变化会改变土颗粒相对位置,继而影响这两类孔隙结构,但是土水相互作用复杂,导致含水率变化对土孔隙结构影响机制仍不清晰,并且没有统一认识。鉴于此,在研究土水相互作用对微观孔隙影响时应充分考虑物理-化学作用,并构建微观孔隙结构演化与宏观变形的定量关系,这也是今后需要深入研究的方向。

水-力作用下红砂岩多裂纹宏-微观断裂机理研究

在深部开采工程中,裂隙岩石在水-力作用下容易发生起裂、扩展而导致失稳破坏。针对目前关于水-力作用下多裂纹断裂机理大多为定性研究而缺乏相关定量研究的问题,基于水-力作用下多裂纹扩展准则预测水-力作用下含双裂纹红砂岩的扩展过程和断裂模式,并通过开展含不同相对位置非等长非平行双裂纹的红砂岩长方体试样的水-力作用双轴压缩断裂试验和断口扫描电镜试验,研究裂纹几何参数和外载条件对多裂纹应力-应变曲线及扩展轨迹的影响规律,揭示水-力作用双轴压缩下岩石多裂纹宏-微观断裂机理。研究结果表明:对于水-力作用双轴压缩下含双裂纹的红砂岩试件,当裂纹相对倾角和相对垂直间距减小(或增大)且减小(或增大)幅度越大时,峰值荷载均随之减小(或增加)且减小(或增加)幅度也越大。对于任意相对位置的双裂纹,水力裂纹总是先起裂,天然裂纹一般后起裂或不起裂;断裂机理多为Ⅱ型(剪切)断裂,裂尖断口亦可观察到强烈的剪切断裂特征;增加水平侧压可抑制Ⅰ型断裂而促进Ⅱ型断裂。预测结果和试验结果吻合较好,验证了水-力作用多裂纹扩展准则。研究成果可为深部岩体工程的强度计算、止裂控制和安全评估等提供重要的理论和现实依据。

Influence of wave and current on deep-sea mining transporting system

As a solution to the breaking of pipeline under high axial force,carbon fiber composite pipe with low density and high intensity is applied to deep-sea mining transporting system.Based on the fact that the transporting pipe is under the forces of gravity,inner liquid,buoyancy as well as hydrodynamic force,geometric nonlinear finite element theory has been applied to analyzing the transporting system.Conclusions can be drawn as follows.Under the interaction of waves and currents,node forces FX and FZ acted by the transporting pipe on the mining vehicle are less than 2 kN,which indicates that waves and currents have little influence on the spatial shape of the transporting pipe and the mining vehicle movement.On the other hand,the horizontal force acting on the mining ship could be as large as 106 830 N,which has great influence on the mining system.

Analysis of the wave propagation and the flow char-acteristics around cylinder due to dam break water

Dam breaks are easily triggered by heavy rains due to extreme weather such as typhoons,causing serious economic losses and casualties.Through the investigation of Chaoshan coastal zone,it is found that there have been dam breaks caused by geological disasters.In the design and management of water conservancy project,it is very important to analyze the effect of disastrous flow caused by dam break on the building.In this paper,the effect of the dam break flow on the cylinder is simulated numerically by taking the water body with initial velocity as the dam break flow,and the flow characteristics around the cylinder and the water body are analyzed.Numerical model adopted the Renault Average Navier-Stokes(RANS)model and volume of fluid(VOF)method to analyze the evolution of free water surface.It is found that there are different patterns of water movement in the process of dam break resulting in the creation of several isolated convex hull forms of dam-break waves on the stationary water surface,which causes longer disturbances in the water near the cylinder and makes the cylinder more vulnerable to fatigue damage.The increase of the height of the dam breaking water will lead to the increase of the hydrodynamic force on the pipeline.This study has guiding significance for the study of dam break and dam body design in water conservancy projects.

Coupling model for assessing anti-seepage behavior of curtain under dam foundation

The seepage under a dam foundation is mainly controlled by the performance of the curtain.Its anti-seepage behavior may be weakened by the long term physic-chemical actions from groundwater.According to seepage hydraulics and geochemistry theory,a coupling model for assessing the behavior of the curtain under a dam foundation is set up,which consists of seepage module,solute transport module,geochemistry module and curtain erosion module,solved by FEM.A case study was carried out.The result shows that the curtain efficiency is weakened all the time.Aqueous calcium from the curtain is always in dissolution during the stress period for simulation,which leads to the increasing amount in groundwater reaching 846.35-865.312 g/m3.Within the domain,reaction extent differs in different parts of the curtain.The dissolution of Ca(OH)2 accounts to 877.884 g/m3 near the bottom and is much higher than that of the other parts.The erosion is much more serious near the bottom of the curtain than the other parts,which is the same to the upstream and downstream.Calcium dissolution is mainly controlled by hydraulic condition and dispersion,and it varies in a non-linear way within the domain.

A CFD Based Investigation of the Unsteady Hydrodynamic Coefficients of 3-D Fins in Viscous Flow

The motion of the fins and control surfaces of underwater vehicles in a fluid is an interesting and challenging research subject.Typically the effect of fin oscillations on the fluid flow around such a body is highly unsteady, generating vortices and requiring detailed analysis of fluid-structure interactions.An understanding of the complexities of such flows is of interest to engineers developing vehicles capable of high dynamic performance in their propulsion and maneuvering.In the present study, a CFD based RANS simulation of a 3-D fin body moving in a viscous fluid was developed.It investigated hydrodynamic performance by evaluating the hydrodynamic coefficients (lift, drag and moment) at two different oscillating frequencies.A parametric analysis of the factors that affect the hydrodynamic performance of the fin body was done, along with a comparison of results from experiments.The results of the simulation were found in close agreement with experimental results and this validated the simulation as an effective tool for evaluation of the unsteady hydrodynamic coefficients of 3-D fins.This work can be further be used for analysis of the stability and maneuverability of fin actuated underwater vehicles.

String and Ball-Like TiO_2/rGO Composites with High Photo-catalysis Degradation Capability for Methylene Blue

Novelthree-dimensionalstring and ball-like titanium dioxide/reduced graphene oxide, TiO_2/rGO(STG) composites were prepared using a one-step hydrolysis process followed by a low-temperature hydrothermaltreatment. The STG composites exhibited excellent photo-catalytic degradation performance for methylene blue owing to a good synergistic effect between TiO_2 and rGO. The STG composites with 1.0 wt% of rGO loading exhibited the highest removalrate of 86.0% for methylene blue and its reaction rate constant(5.27 × 10^(-3) min^(-1)) was much higher than those of pure string and ball-like TiO_2(ST). In addition, the STG composites also showed an outstanding capability for the photo-catalysis degradation of other cationic dyes. In addition, a possible photo-catalytic degradation mechanism for the STG composite was postulated, in which~?O_2^- and~·OH were the main oxidizing groups. This work of fers new insights into a better design and preparation of novelcomposite materials for the removalof organic dyes.

Thermodynamic behaviors of Cu in interaction with chlorine, sulfur, phosphorus and minerals during sewage sludge co-incineration

Thermodynamic equilibrium calculations were performed to reveal effects of interactions among Cl, S, P and other minerals on Cu migration. Our results showed that HCl（g）, SO2（g） and （P2O5）2（g） were released from the sewage sludge co-incineration. Cl was found to weaken adsorption of Cu by Al2O3, CaO and Fe2O3, while S de- layed reactions of Fe2O3 and Al2O3 with Cu, with P having no effect on reactions between the minerals and Cu. Among the coupled systems ofCl, S and P, the co-existences of Cl and S, and Cl, S and P were determined to inhibit Cu volatilization, and the co-existence of Cl and P had an enhancing effect Cu migration was affected only by S in the S and P system. With the SiO2, CaO and Al2O3 system, both Cl alone and Cl and P led to failed reactions be- tween the minerals and Cu. In the systems of S, S and Cl, S and P, and S, Cl and P, the migration behavior of Cu was mainly affected by S at low temperatures and by Cl at high temperatures, whereas P had no effect on Cu mi- gration during the entire nrocess.

Inclusion behavior of oxybutynin with hydroxypropyl-β-cyclodextrin

Inclusion behavior of oxybutynin （OBN） with hydroxypropyl-β-cyclodextrin （HP-β-CD） was investigated by ultraviolet absorption spectrum and fluorescence spectrum. A reliable determination of the complex stoichiometry was provided by the continuous variation technique. Alcohol was added to further investigate the mechanism of the inclusion behavior. Thermodynamic constants AG, AH and AS for inclusion interaction of OBN and HP-β-CD were determined. The results show that host-guest complex with molar ratio of 1：1 is formed, and inclusion stability constant between OBN and HP-β-CD is 54.9 L/mol determined by ultraviolet spectrum and 11.1 L/mol determined by fluorescence spectrum. OBN has weak binding ability with HP-β-CD in aqueous solution （stability constant 〈102 L/mol） and addition of alcohol leads to a decrease of stability constant, which indicates that the hydrophobic force contributes to the inclusion process. AG, AH and AS are all less than zero, which indicates that the inclusion process is a spontaneous and exothermic process.

Wave-induced seepage and its possible contribution to the formation of pockmarks in the Huanghe(Yellow) River delta

Wave-induced seepage and its possible contribution to the formation of pockmarks in the Huanghe(Yellow) River delta were investigated experimentally and numerically. Laboratory experiments were carried out to explore the response of a layered silty seabed with various saturation conditions under cyclic wave loads,in which the pore pressure and seepage-related phenomena were particularly monitored. Numerical models to simulate wave-induced seepage in the seabed were presented and evaluated,then applied to the Huanghe River delta. The experimental results show that the excess pore pressure decreases more rapidly at the surface layer,while the seepage-related phenomena are more pronounced when large cyclic loads are applied and the underlying layer is less saturated. The proposed numerical models were verified by comparing with the experiments. The calculated seepage depth agreed well with the depth of the pockmarks in the Huanghe River delta. The experimental and numerical results and the existing insitu investigations indicate that the wave-induced seepage may be a direct cause of the pockmarks in the Huanghe River delta. Extreme storm waves and the dual-layered structure of hard surface layer and weak underlying layer are essential external and internal factors,respectively. Wave- or current-induced scour and transport are possible contributors to the reformation of pockmarks at a later stage.

Salt Effect on the Liquid-Liquid Equilibrium of （Water ＋ Propionic Acid ＋ Cyclohexanol） System at T=（298.2,303.2,and 308.2） K

Effects of salt and temperature on the liquid phase equilibrium of the(water + propionic acid + cyclohexanol) system were investigated.The liquid-liquid equilibrium data in the presence of KCl for various salt ionic strength of 0.5,1.0,1.5,2.0,and 2.5 mol·dm3 and in absence of the salt at T=(298.2,303.2,and 308.2)K were determined.The experimental results were correlated based on the Othmer-Tobias equation and Pitzer ion-interaction model.Thermodynamic properties such as distribution coefficients and activity coefficients of propionic acid in water + cyclohexanol were determined.In addition,the separation factor,S,of the chosen solvent was obtained for the investigated system.

Optimal rotor wear design in hypotrochoidal gear pump using genetic algorithm

The wear rate between the rotors of a hypotrochoidal gear pump is characterized.Using the knowledge of shape design on the rotors,the contact stresses without hydrodynamic effect between the rotor teeth were evaluated through the calculation of the Hertzian contact stress.Based on the above results and the sliding velocity between the rotors,a genetic algorithm (GA) was used as an optimization technique forminimizing the wear rate proportional factor (WRPF).The result shows that the wear rate or the WRPF can be reduced considerably,e.g.approximately 12.8%,throughout the optimization using GA.

Physical simulation of hydrodynamic conditions in high rank coalbed methane reservoir formation

In order to select highly productive and enriched areas of high rank coalbed methane reservoirs, based on hydrologic geology as one of the main factors controlling coalbed methane （CBM） reservoir formations, the effect of hydrodynamic forces controlling CBM reservoir formations was studied by a physical simulation experiment in which we used CBM reservoir simulation facilities. The hydrodynamic conditions of high coal rank reservoirs in the Qinshui basin were analyzed. Our experiment shows the following results： under strong hydrodynamic alternating action, 6C~ of coalbed methane reservoir changed from the start at -2.95% ~ -3.66%, and the lightening process occurred in phases; the CI-I4 volume reduced from 96.35% to 12.42%; the CO2 vo- lume decreased from 0.75% in sample 1 to 0.68% in sample 2, then rose to 1.13% in sample 3; the N2 volume changed from 2.9% in sample 1 to 86.45% in sample 3. On one hand, these changes show the complexity of CBM reservoir formation; on the other hand, they indicate that strong hydrodynamic actions have an unfavorable impact on CBM reservoir formation. It was found that the gas volume and hydrodynamic intensity were negatively correlated and low hydrodynamic flow conditions might result in highly productive and enriched areas of high rank CBM.

Computation of Ship Hydrodynamic Interaction Forces in Restricted Waters using Potential Theory

A computer code based on the double-body potential flow model and the classic source panel method has been developed to study various problems of hydrodynamic interaction between ships and other objects with solid boundaries including the seabed. A peculiarity of the proposed implementation is the application of the so-called ＂moving-patch＂ method for simulating steady boundaries of large extensions. The method is based on an assumption that at any moment just the part of the boundary （＂moving patch＂） which lies close to the interacting ship is significant for the near-field interaction. For a specific case of the fiat bottom, comparative computations were performed to determine optimal dimensions of the patch and of the constituting panels based on the trade-off between acceptable accuracy and reasonable efficiency. The method was applied to estimate the sway force on a ship hull moving obliquely across a dredged channel. The method was validated for a case of ship-to-ship interaction when tank data were available. This study also contains a description of a newly developed spline approximation algorithm necessary for creating consistent discretizations of ship hulls with various degrees of refinement.

Performance of simultaneous nitrification and denitrification in lateral flow biological aerated filter

A new wastewater treatment facility—lateral flow biological aerated filter (LBAF) was developed aiming at solving energy consumption and operational problems in wastewater treatment facilities in small towns. It has the function of nitrification and removing organic substrate. In this study, we focused on the denitrification performance of LBAF and its possible mechanism under thorough aeration. We identified the existence of simultaneous nitrification and denitrification (SND) by analyzing nitrogenous compounds along the flow path of LBAF and supportive microbial microscopy, and studied the effects of air/water ratio and hydraulic loading on the performance of nitrogen removal and on SND in LBAF to find out the optimal operation condition. It is found that for saving operation cost, aeration can be reduced to some degree that allows desirable removal efficiency of pollutants, and the optimal air/water ratio is 10:1. Hydraulic loading less than 0.43 m h?1 hardly affects the nitrification and denitrification performance; whereas higher hydraulic loading is unfavorable to both nitrification and denitrification, far more unfavorable to denitrification than to nitrification.

Dynamic Interaction of Parallel Moving Ships in Close Proximity

Nowadays,there are many studies conducted in the field of marine hydrodynamics which focus on two vessels traveling and floating in sufficiently close proximity to experience significant interactions.The hydrodynamic behavior of parallel moving ships in waves is an interesting and important topic of late.A numerical investigation has been carried out for the prediction of wave exciting forces and motion responses of parallel moving ships in regular waves.The numerical solution was based on 3D distribution technique and using the linear wave theory to determine the exciting forces and ship＇s motion.The speed effects have been considered in the Green function for more realistic results.The numerical computations of wave exciting forces and motion responses were carried out for a Mariner and Series 60 for the purpose of discovering different Froude numbers and different separation distances in head sea conditions.Based on the numerical computations,it was revealed that the sway,roll and yaw have a significant effect due to hydrodynamic interaction.

Effects of Body Weight and Water Temperature on Maximum Food Consumption of JuvenileSebastodes fuscescens (Houttuyn)

Maximum rate of food consumption (C max) was determined for juvenile Sebastodes fuscescens (Houttuyn) at water temperature of 10, 15, 20 and 25℃. The relationships of C max to the body weight (W) at each temperature were described by a power equation: lnC max = a + b lnW. Covariance analysis revealed significant interaction of the temperature and body weight. The relationship of adjusted C max to water temperature (T) was described by a quadratic equation: C max =-0.369 + 0.456T - 0.0117T 2. The optimal feeding temperature calculated from this equation was 19.5℃. The coefficients of the multiple regression estimation relating C max to body weight (W) and water temperature (T) were given in the Table 2.

FEM for Stability Analysis Against Overturning of Portal Water Injection Sheet Pile

Portal water injection sheet pile (PWISP), as a retaining wall, appeared in seashore engineering in 2000. Although there have been many systematic methods addressing the issue, there are very few focusing on the new structure because of the difficulties in defining the earth pressure between the two piles. A new method is proposed in this paper to obtain the earth pressure between the PWISPs. Stability analysis against overturning follows as a consequence. Using Finite Element Analysis (FEA) software ANSYS, both the nonlinear characteristics of the soil and those of the contact elements are taken into account to obtain the earth pressure distribution on the contact surface. Based on the results of the FEA, Rankin’s theory and the slip plane theory, the formula of the earth pressure on the inner surfaces between the piles is given. Assuming the PWISP as the analysis object and the earth pressure as an outside force acting upon it, the equation of stability against overturning of the PWISP is presented. Finally, some parameters are discussed about the stability of the PWISP against overturning, such as the embedded depth of the front pile, the distance between the two rows of piles, the internal friction angle and the cohesion of the earth. The results show that the increase of the cohesion and the internal friction angle will decrease the distance and the embedded depth, and therefore enhance the stability against overturning. Specifically, when the distance is 1/3-2/3 of the maximal excavation depth, the two rows of piles give the best performance in stability.

Dynamics study on effect of temperature to Nitrous nitrification reaction of coking wastewater

Dynamic effects of NO2--N accumulation were discussed owing to temperature.In different temperature,a series of vmax and Ks were found considering the relation between the temperature and rate of ammonia nitrogen transforming into NO2--N.The kinetics models,which reflected the conditions of ammonia nitrogen transforming into NO2--N in the treatment process of the coking wastewater,were built up.The characteristic coefficient temperature was determined according to Arrhenius.

Dynamic simulation of hydrodynamic model of drum level wave action and sloshing

In order to build the model of the drum level wave action and sloshing, based on the method of modularization modeling, the hydrodynamic model of drum level wave action and sloshing was developed, and dynamic simulation researches were carried out based on the model. The results indicate that both drum level and drum length have functional relations with period of drum level wave action and sloshing. When the drum level decreases or drum length increases, the period of drum level wave action and sloshing increases, density of liquid and number of sub-module division have little influence on the period of drum level wave action and sloshing. The model was validated by the analytical solution theory of liquid’s wave action and sloshing in cuboid container, and the 3D graphics of drum level wave action and sloshing was also obtained. The model can dynamically reflect the rules of wave action and sloshing of water in the container exactly.