水-温作用下沥青混合料疲劳性能分析

针对我国南方湿热多雨的气候条件,采用冻融循环的试验方法模拟湿热地区沥青混合料的水-温作用,通过CRT-NU14气动伺服沥青材料试验机对高速公路沥青路面下面层常用AC-25沥青混合料进行间接拉伸疲劳试验,得到不同水-温条件下的疲劳曲线和疲劳方程,并从疲劳寿命、力学性能、疲劳特征参数和疲劳破坏特征4个方面分析水-温作用下沥青混合料的疲劳规律。研究结果表明:不同水-温条件下沥青混合料的应力与疲劳寿命在双对数坐标中均呈良好的线性关系,可为沥青路面疲劳寿命预估提供依据;水作用和温度升高对沥青混凝土的疲劳寿命和力学性能影响显著,可使混合料的抗疲劳特性大幅衰减;水-温作用下试件疲劳破坏表现为剪切和劈裂联合作用形式,证明用冻融循环处理条件模拟沥青混凝土处于水-温作用的合理性。

水-温作用下水工隧洞钢筋混凝土衬砌开裂特性分析

在水工隧洞具体充水加压中,速度以及温度的改变不一定同步,基于对时差性的考虑,此次研究采用实体本构模型,根据某一发电引水隧洞,在水-温联合作用之下,对衬砌结构的开裂特性进行分析,旨在为有关人士提供借鉴。

基于水-温联合影响下高模量沥青混合料的路用性能分析

首先阐述了对高模量沥青混合料研究的意义。然后研究原材料性能及配合比设计,最后对吸水试验结果及路用性能进行分析。研究发现:骨料在同一级配条件下,高模量剂类型、用量对混合料的油石比影响不大;AC-20C、AC-13C沥青混合料在同样的实验条件下,AC-20C混合料高温性能优于AC-13C,AC-13C低温及水稳性均优于AC-20C;RA高模量剂对两种混合料的抗高温及水稳性均有较好的改善作用,而PR.M高模量剂对两种混合料的低温稳定性的促进作用更优。

水-温相互作用下高模量沥青混合料路用性能研究

为减少沥青路面病害的形成,延长其使用年限及服务水平,引入高模量沥青混合料理念,从矿料级配、含水率、试验温度、养生周期、高模量剂种类及掺量等方面对高模量沥青路面的高温抗车辙、低温抗开裂及抗水损害性能等进行研究。结果表明,矿料级配相同时,高模量剂种类及掺量对混合料油石比的影响较小;相同条件下,AC-20C沥青混合料的高温性能较好,AC-13C沥青混合料的低温及水稳定性能较好;RA高模量剂对2种混合料高温及水稳定性能的改善效果最优,PR.M高模量剂对2种混合料低温性能的改善效果最优。

水-温-荷耦合作用下沥青混凝土疲劳寿命

对粗、中、细3种不同级配类型的AC-25沥青混凝土进行冻融和未冻融条件下劈裂疲劳试验,得到应力疲劳方程和应变疲劳方程,分析了水、温、荷耦合对沥青混凝土疲劳寿命的影响.研究结果表明：沥青混凝土疲劳寿命与其劈裂强度呈现明显的相关性,劈裂强度越低,相应疲劳寿命越小;不同级配类型的沥青混凝土疲劳性能优劣顺序依次为粗〉细〉中;在应变模式下,温度对沥青混凝土疲劳寿命的影响不明显,且可将不同温度下应变疲劳方程采用统一的表达式进行拟合,揭示了沥青混凝土应变疲劳过程与温度无关的规律;对于未冻融的粗级配沥青混凝土,其疲劳寿命随温度提高而明显缩短;经一次冻融循环后,在同一应力比下疲劳寿命降低约10%~35%,而在同一应力水平下疲劳寿命降低约75%~80%.

Protection of ultrastructure in chilling-stressed banana leaves by salicylic acid

Objective： Chilling tolerance of salicylic acid （SA） in banana seedlings （Musa acuminata cv., Williams 8818） was investigated by changes in ultrastructure in this study. Methods： Light and electron microscope observation. Results： Pretreatment with 0.5 mmol/L SA under normal growth conditions （30/22 ℃） by foliar spray and root irrigation resulted in many changes in ultrastructure of banana cells, such as cells separation from palisade parenchymas, the appearance of crevices in cell walls, the swelling of grana and stromal thylakoids, and a reduction in the number of starch granules. These results implied that SA treatment at 30/22 ℃ could be a type of stress. During 3 d of exposure to 7 ℃ chilling stress under low light, however, cell ultrastructure of SA-pretreated banana seedlings showed less deterioration than those of control seedlings （distilled water-pretreated）. Conclusion： SA could provide some protection for cell structure of chilling-stressed banana seedling.

Oxidative Desulfurization of Non-hydrotreated Kerosene Using Hydrogen Peroxide and Acetic Acid

The oxidative desulfurization of a real refinery feedstock (i.e.,non-hydrotreated kerosene with total sulfur mass content of 0.16%) with a mixture of hydrogen peroxide and acetic acid was studied.The influences of various operating parameters including reaction temperature (T),acid to sulfur molar ratio (nacid/nS),and oxidant to sulfur molar ratio (nO/nS) on the sulfur removal of kerosene were investigated.The results revealed that an increase in the reaction temperature (T) and nacid/nS enhances the sulfur removal.Moreover,there is an optimum nO/nS related to the reaction temperature and the best sulfur removal could be obtained at nO/nS=8 and 23 for the reaction temperatures of 25 and 60°C,respectively.The maximum observed sulfur removal in the present oxidative desulfurization system was 83.3%.

String and Ball-Like TiO_2/rGO Composites with High Photo-catalysis Degradation Capability for Methylene Blue

Novelthree-dimensionalstring and ball-like titanium dioxide/reduced graphene oxide, TiO_2/rGO(STG) composites were prepared using a one-step hydrolysis process followed by a low-temperature hydrothermaltreatment. The STG composites exhibited excellent photo-catalytic degradation performance for methylene blue owing to a good synergistic effect between TiO_2 and rGO. The STG composites with 1.0 wt% of rGO loading exhibited the highest removalrate of 86.0% for methylene blue and its reaction rate constant(5.27 × 10^(-3) min^(-1)) was much higher than those of pure string and ball-like TiO_2(ST). In addition, the STG composites also showed an outstanding capability for the photo-catalysis degradation of other cationic dyes. In addition, a possible photo-catalytic degradation mechanism for the STG composite was postulated, in which~?O_2^- and~·OH were the main oxidizing groups. This work of fers new insights into a better design and preparation of novelcomposite materials for the removalof organic dyes.

Ultrasonic Studies of 4-Aminobutyric Acid in Aqueous Salbutamol Sulphate Solutions at Different Temperatures

Ultrasonic speeds of 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·kg^-1 aqueous salbutamol sulphate（SBS） solutions are measured at 308.15,313.15 and 318.15 K.Isentropic compressibility kS,change in isentropic compressibility△k S,relative change in isentropic compressibility（ △kS /kS^0） ,apparent molal compressibility kφ,limiting apparent molal compressibility kφ^0 ,transfer limiting apparent molal compressibility k φ^0,hydration number nH,pair and triplet interaction parameters kAS,kASS are estimated.The above parameters are used to interpret the solute-solute and solute-solvent interactions of 4-aminobutyric acid in the aqueous salbutamol sulphate solutions.

Effect of NH_4^+ exchange on CuY catalyst for oxidative carbonylation of methanol

NaY and ion exchanged NaNH4Y zeolite with NH4NO3 were used as the support to prepare CuY cata‐lysts by a high temperature anhydrous interaction between the support and copper （II） acety‐lacetonate Cu（acac）2. The catalysts were used for the oxidative carbonylation of methanol to dime‐thyl carbonate （DMC） at atmospheric pressure. The textural and acidic properties of NaNH4Y zeolite and the CuY catalysts were investigated by X‐ray diffraction, scanning electron microscopy, N2 ad‐sorption‐desorption, temperature programmed reduction of H2, X‐ray photoelectron spectroscopy and temperature programmed desorption of NH3. With increasing NH4NO3 concentration, the NH4＋exchange degree increased while the crystallinity of the zeolite remained intact. Crystalline CuO was formed when the NH4＋exchange degree of NaNH4Y was low, and the corresponding CuY catalyst showed low catalytic activity. With increasing of the NH4＋exchange degree of NaNH4Y, the content of surface bound Cu＋active centers increased and the catalytic activity of the corresponding CuY catalyst also increased. The surface bound Cu＋content reached its maximum when the NH4＋ex‐change degree of NaNH4Y reached towards saturation. The CuY exhibited optimal catalytic activity with 267.3 mg/（g·h） space time yield of DMC, 6.9%conversion of methanol, 68.5%selectivity of DMC.

Vegetation/Soil Synthesis Water Index Using MODIS Data

In consideration of the spectral character of MODIS (Moderate Resolution Imaging Spectroradiometer) dataand the reflective spectrum of vegetation and soil, NDVI (Normalized Difference Vegetation Index) and NDWI (Nor-malized Difference Water Index) are deduced using one visible band (0.66μm) and two near-infrared bands (0.86μm,1.24 μm). Vegetation canopy temperature is derived using two thermal infrared bands (8.6 μm and 11μm). Then thevegetation/soil synthesis water index (VSWI) is acquired through analyzing the coupling character of three indexeswhich can reflect the water condition of vegetation. Finally, the synthesis index is verified by equivalent water contentof a single leaf. The matching results show that the synthesis index is directly proportional to the modeled data,which means that the vegetation water content can be reflected using the synthesis index effectively.

Effects of Body Weight and Water Temperature on Maximum Food Consumption of JuvenileSebastodes fuscescens (Houttuyn)

Maximum rate of food consumption (C max) was determined for juvenile Sebastodes fuscescens (Houttuyn) at water temperature of 10, 15, 20 and 25℃. The relationships of C max to the body weight (W) at each temperature were described by a power equation: lnC max = a + b lnW. Covariance analysis revealed significant interaction of the temperature and body weight. The relationship of adjusted C max to water temperature (T) was described by a quadratic equation: C max =-0.369 + 0.456T - 0.0117T 2. The optimal feeding temperature calculated from this equation was 19.5℃. The coefficients of the multiple regression estimation relating C max to body weight (W) and water temperature (T) were given in the Table 2.

Dynamics study on effect of temperature to Nitrous nitrification reaction of coking wastewater

Dynamic effects of NO2--N accumulation were discussed owing to temperature.In different temperature,a series of vmax and Ks were found considering the relation between the temperature and rate of ammonia nitrogen transforming into NO2--N.The kinetics models,which reflected the conditions of ammonia nitrogen transforming into NO2--N in the treatment process of the coking wastewater,were built up.The characteristic coefficient temperature was determined according to Arrhenius.

Magnesium (II) Adsorption from Aqueous Solutions on China Clay and the Stability Constants for Complex Formation

China clay was employed as an adsorbent for the removal of Mg 2+ from water at pH 7.0 within the temperature range of 303～328 K. The linearity of the plots indicated Langmuir type isotherms. The reaction was exothermic. A maximum removal of 35% was obtained at 0.50 mmol L -1 metal concentration and a pH of 7.0 at 303 K. The H + rel /Mg 2+ ads ratio changed from a fractional value to 2.5. Strong chemical bondings took place between oxygen atom of the surface and Mg 2+ , resulting in a surface complex species. Temperature had a significant effect on H + rel , and the stability constants also increased with increasing temperature.

Evaluation and classification of seawater corrosiveness by environmental factors

According to the data of main environmental factors and the depth of localized corrosion of carbon steel and low alloy steels in China seas, combined with the result of grey interrelation analysis, double-factor method was proposed to evaluate and classify seawater corrosiveness. According to the temperature of seawater and the biologically adhesive area on steels, the corrosiveness of seawater from low to high level is classified into five levels （C l-C5）, which was identified by the data of corrosion depth of carbon steel immersed in water for one year.

Novel Control Structure Design of Differential Pressure Thermally Coupled Reactive Distillation for Methyl Acetate Hydrolysis

In this paper, the novel control structures of differential pressure thermally coupled reactive distillation process for methyl acetate hydrolysis were proposed. The RadFrac module of Aspen Plus was adopted in the steady-state simulation. Sensitive analysis was applied to find the stable intial value and provide a basis for the improved control structure design. The Aspen Dynamics software was adopted to study the process dynamic behaviors, and two novel control structures provided with feed ratio controllers and sensitive tray temperature controllers were proposed. The reflux ratio controllers were applied in the improved novel control structures. Both control structures abandoned the composition controllers that were replaced by simpler controllers with which the product purity could meet the specification requiring under a ± 20% disturbance to the total feed flowrate / MeAc composition.

IMPACTS OF TWO TROPICAL CYCLONES EXPERIENCING EXTRATROPICAL TRANSITION DURING NORTHWARD PROGRESSION ON THE RAINFALL OF LIAODONG PENINSULA

Both of Typhoon Winnie (9711) and Matsa (0509) underwent an extratropical transition (ET) process when they moved northward after landfall and affected Liaodong Peninsula. However, Matsa produced half as much rainfall as Winnie, although it struck Liaodong Peninsula directly while Winnie passed through the Bohai Sea. The relations between the ET processes and the precipitation over Liaodong Peninsula are examined. The result shows that the precipitation difference between Winnie and Matsa was closely related to the interactions between the westerly systems and typhoons during their ET processes. Winnie was captured by the upper westerly trough and then coupled with it when moving to the mid-latitudes, and the positive anomaly of moist potential vorticity (MPV) was transported downward from the upper troposphere over the remnant circulation of the tropical cyclone (TC). It was favorable to the interaction between tropical warm and wet air and westerly cold air, causing convective cloud clusters to form and develop. The rain belt composed of several meso-β cloud clusters over the Liaodong Peninsula, resulting in heavy rainfall. On the other hand, Matsa did not couple with any upper trough during its ET process and the positive anomaly of MPV in the upper troposphere and its downward transfer were weak. Only one meso-β cloud cluster occurred in Matsa’s rain belt during its ET process that tended to lessen rainfall over Liaodong Peninsula.

Tidally Induced Water Temperature Change in Artesian Wells

Water temperature observation in wells,as a precursor observation project in China,aims to capture stress-strain information during the preparation of earthquakes. The study of the water temperature tidal effect has important significance,for water temperature tidal effect is both a reflection of stress-strain in crust and an interference factor of precursor observations. With a view of thermal conditions in artesian wells,the paper holds that there are two mechanisms for interpreting tidally induced water temperature changes in artesian wells. Namely,thermal conduction mechanisms and thermal convection mechanism. The paper then derives the quantitative relationship between water temperature and tidal volumetric strain changes in an ideal artesian well. Finally,the water temperature tidal effect in the Benxi artesian well is analyzed. The results show that the water temperature tidal effect in Benxi well is the result of joint action of thermal conduction mechanism and thermal convection mechanism,in which thermal conduction mechanism plays a leading role.

Electricity Generation from Low Temperature Waste Heat with Application to Hydrogen Production from Water

This paper presents an extensive study of the heat pump cycle and associated working fluids to generate electricity from low temperature industrial waste heat. An Aspen Plus simulation has been developed to evaluate the effect of various working fluids on the net heat pump efficiency over a wide range of turbine inlet temperatures between 50℃ and 250℃. One hundred eight （108） refi＇igerants were investigated from the environmental classifications of Hydrochlorofluorocarbons （HCFC）, Hydrofluorocarbons （HFC）, Chlorofluorocarbons （CFC） and Hydrocarbons （HC） with boiling points between -88.65 ℃ and 110.65℃. Net efficiency, which ranged from 0.1% to 25.8% in this work tends to increases with the temperature of the waste heat. Results of the present study demonstrate that working fluid R41 （with source temperature of 44 ℃） provides the maximum efficiency among those evaluated. Refrigerants R13B1 and R32 provide the best efficiency for waste heat source temperatures ranges 60 - 67 ℃ and 68 - 78℃ respectively. Ammonia shows the highest efficiency from 79℃ to 132 ℃. Refrigerants R31, R21, 17,30 and benzene perform well in the temperature ranges 133-151 ℃, 152-178 ℃, 179-236℃ and 237-250 ℃respectively. The optimal heat pump systems are applied to the hybrid copper sulfate-copper oxide thermochemical cycle for hydrogen production from water. 100.8 MW of electrical energy is produced, which increased the efficiency from 24.1% to 25.9%.