A series of microcrystalline silicon thin films were fabricated by very high frequency plasma enhanced chemical vapor deposition (VHF-PECVD) at different silane concentrations in a P chamber. Through analysis of the...A series of microcrystalline silicon thin films were fabricated by very high frequency plasma enhanced chemical vapor deposition (VHF-PECVD) at different silane concentrations in a P chamber. Through analysis of the structural and electrical properties of these materials,we conclude that the photosensitivity slightly decreased then increased as the silane concentration increased,while the crystalline volume fraction indicates the opposite change. Results of XRD indicate that thin films have a (220) preferable orientation under certain conditions. Microcrystalline silicon solar cells with conversion efficiency 4. 7% and micromorph tandem solar cells 8.5% were fabricated by VHF-PECVD (p layer and i layer of microcrystalline silicon solar cells were deposited in P chamber), respectively.展开更多
In Japan, various countermeasures have been taken to improve the water quality of public waters such as rivers and lakes. Though water quality has improved, it is still insufficient. In summer, eutrophication is seen ...In Japan, various countermeasures have been taken to improve the water quality of public waters such as rivers and lakes. Though water quality has improved, it is still insufficient. In summer, eutrophication is seen in lakes and inner bays, as well as rivers. As a countermeasure to prevent eutrophication, the removal treatment of nutrient salts such as nitrogen and phosphorus is done, in addition to organic substance elimination in the domestic sewerage system. This report will show the water quality characteristics of rivers and ponds in Japan. It is considered that these investigative results are effective when the water quality improvement of the stabilization ponds where eutrophication occurs are examined in China.展开更多
A promising preparation method for lithium hexafluorophosphate(LiPF6)was introduced.Phosphorus pentafluoride(PF5) was first prepared using CaF2 and P2O5 at 280℃for 3 h.LiPF6 was synthesized in acetonitrile solvent by...A promising preparation method for lithium hexafluorophosphate(LiPF6)was introduced.Phosphorus pentafluoride(PF5) was first prepared using CaF2 and P2O5 at 280℃for 3 h.LiPF6 was synthesized in acetonitrile solvent by LiF and PF5 at room temperature(20-30℃)for 4 h.The synthesized LiPF6 was characterized by infrared spectrometry and X-ray diffraction(XRD). Atomic absorption and ion chromatography results show that the purity of synthesized LiPF6 reaches 99.98%.Thermal stability of self-synthesized LiPF6 was analyzed by differential thermal analysis and thermogravimetry.The results indicate that the self-synthesized LiPF6 has higher purity,lower impurity contents and better thermal stability than the commercial LiPF6.展开更多
The article studies the oscillation features of the water in the square moon pool under the circumstances of wave-flow combined conditions. Comparing with the results of experiments of the square moon pool, a series o...The article studies the oscillation features of the water in the square moon pool under the circumstances of wave-flow combined conditions. Comparing with the results of experiments of the square moon pool, a series of studies reveal that the water piston oscillation phenomenon is quite similar to that of the circular one. Two types of oscillation are exhibited under different incoming wave periods, i.e. self-excited oscillation and forced oscillation. The difference between the circular and square moon pool is that the attack angle makes greater influences on the square one. "Beating phenomenon" is also found in the square moon pool which is not mentioned of the circular one.展开更多
For All-Solid-State battery applications, Mg2+-ion conducting polymer electrolytes and Mg-metal electrode are currently considered as alternate choices in place of Li+-ion conducting polymer electrolytes/Li-metal el...For All-Solid-State battery applications, Mg2+-ion conducting polymer electrolytes and Mg-metal electrode are currently considered as alternate choices in place of Li+-ion conducting polymer electrolytes/Li-metal electrode. Present paper reports fabrication of All-Solid-State battery based on the following Mg2+-ion conducting nano composite polymer electrolyte (NCPE) films: [85PEO: 15Mg(C104)2] + 5% TiO2 (〈 100 nm), [85PEO: 15Mg(CIO4)2] + 3% SiO2(-8 nm). [85PEO: 15Mg(CIO4)2] + 3% MgO (〈 100 nm), [85PEO:15Mg(C1O4)2] + 3% MgO (-44 μm). NCPE films were prepared by hot-press technique. Solid Polymer Electrolyte (SPE) composition: [85PEO: 15Mg(CIO4)2], identified as high conducting film at room temperature, has been used as ISt--phase host and nano/micro particles of active (MgO)/passive (SiO2, TiO2) fillers as IInd-phase dispersoid. Filler particle dependent conductivity studies identified above mentioned NCPE films as optimum conducting composition (OCC) at room temperature. Ion transport behavior of SPE/NCPE film materials was investigated previously. Present paper reports materials characterization and cell performance studies on All-Solid-State batteries: Mg (Anode) Ⅱ SPE or NCPE films tt C+MnO2+Electrolyte (Cathode). Open circuit voltage (OCV) obtained was in the range: 1.79-1.92 V. The batteries were discharged at room temperature under different load conditions and some important battery parameters have been evaluated from plateau region of cell-potential discharge profiles. All the batteries performed quite satisfactorily specially under low current drain states.展开更多
This paper deals with geochemical features of gas emitted from the Hubin Springs. The Hubin Springs zone, a strong thermal emission zone, is are locatedd at the north edge of the Tianchi caldera lake. Very young depos...This paper deals with geochemical features of gas emitted from the Hubin Springs. The Hubin Springs zone, a strong thermal emission zone, is are locatedd at the north edge of the Tianchi caldera lake. Very young deposits with uncertain eruption date are found on the top area of the Tianwenfeng, which might have been formed in one of the recent eruptions or the Millennium Eruption. It is of significance to study the geochemistry features of the emitting gas from the Hubin Springs to understand the activities of the Tianchi Volcano. This paper systematically sampled and analyzed the gases emitted from the Hubin Springs and discussed their geochemistry features. The results show that there is a high content of deep derived gases, such as CO2, He, CH4 and Ar in Hubin Springs zone. The isotopic ratio of He lies between 4. 18 and 5. 95 Ra. The averaged mantle derived gas content calculated from the ^4He/2^20Ne ratio and He content reaches 67.1%. All these show that the Hubin Springs are located on a special belt of deep gases released in high intensity and large scale. The spatial distribution of Helium isotope is characterized by concavity, showing that this special area may be related to the volcanic edifice. It is highly possible that the released gases represent the residual gas samples of the latest eruptions from the Tianchi Volcano. However more detailed studies are demanded.展开更多
Using the 1961–1995 monthly averaged meteorological data from 148 surface stations in the Qinghai-Xizang Plateau (QXP) and its surrounding areas, calculation of the 35-year atmospheric heat source/sink (<Qi>) a...Using the 1961–1995 monthly averaged meteorological data from 148 surface stations in the Qinghai-Xizang Plateau (QXP) and its surrounding areas, calculation of the 35-year atmospheric heat source/sink (<Qi>) and an analysis on its climatic features and relation to rainfall in China have been made. It is found that on the average, the atmospheric heat source over the QXP is the strongest in June (78 W / m2) and cold source is the strongest in December (?72 W/m2). The sensible heat of the surface increases remarkably over the southwest of the QXP, causing the obvious increase of <Qi> there in February and March, which makes a center of the atmospheric heat source appear over the north slope of the Himalayas. Afterwards, this center continues to intensify and experiences noticeable migration westwards twice, separately occurring in April and June. The time when the atmosphere over the east of the QXP becomes heat source and reaches strongest is one month later than that over the southwest of the QXP. In summer, the latent heat of condensation becomes a heating factor as important as the sensible heat and is also a main factor that makes the atmospheric heat source over the east of the QXP continue growing. On the interdecadal time scale, (Q1) of the QXP shows an abrupt change in 1977 and a remarkable increase after 1977. The atmospheric heat source of the spring over the QXP is a good indicator for the subsequent summer rainfall over the valleys of the Changjiang and Huaihe rivers and South China and North China. There is remarkable positive correlation between the QXP heat source of summer and the summer rainfall in the valleys of the Changjiang River.展开更多
The olivine-typed cathode material of Li Fe PO4 was prepared via sol-gel method,and the bromine was doped into Li Fe PO4.The crystal structure,morphology,and electrochemical properties of the samples were investigated...The olivine-typed cathode material of Li Fe PO4 was prepared via sol-gel method,and the bromine was doped into Li Fe PO4.The crystal structure,morphology,and electrochemical properties of the samples were investigated by X-ray diffraction,scanning electron microscopy and charge–discharge cycle measurements.The results showed that the electrochemical performance of Li Fe PO4 had been improved by bromine doping,and the best doping amount of bromine is 2%.The discharge capacity of this sample can reach 152 m Ah/g at 0.2 C.展开更多
Premenstrual syndrome(PMS) is a collection of physical and emotional symptoms occurring two weeks prior to woman's menstruation, such as tension, emotional upset, attention deficit, irritability, depression and anx...Premenstrual syndrome(PMS) is a collection of physical and emotional symptoms occurring two weeks prior to woman's menstruation, such as tension, emotional upset, attention deficit, irritability, depression and anxiety, insomnia, headache and distending breasts, which vanish shortly after the start of menses. Serious PMS can affect the sufferers' work,展开更多
The Ba Ce0.8Y0.2O2.9-Ce0.85Sm0.15O1.925 composite electrolytes were prepared with Ba Ce0.8Y0.2O2.9(BCY) and Ce0.85Sm0.15O1.925(SDC). The SDC and BCY powders were mixed in the weight ratio of 95:5, 85:15, and 75:25, re...The Ba Ce0.8Y0.2O2.9-Ce0.85Sm0.15O1.925 composite electrolytes were prepared with Ba Ce0.8Y0.2O2.9(BCY) and Ce0.85Sm0.15O1.925(SDC). The SDC and BCY powders were mixed in the weight ratio of 95:5, 85:15, and 75:25, respectively(named as BS95, BS85, and BS75). Because of the composite effect between the SDC and BCY phases, the BS95 and BS85 exhibit improved conductivity compared with the pure SDC and BCY. The conductivity of BS95 is higher than that of BS85, indicating that the composite effect of BS95 is greater than that of BS85. Nevertheless, the composite effect in BS75 does not exist. Hence, we conclude that the composite effect in the BCY-SDC composites will decrease with the increase of the amount of BCY and even disappear when the amount of BCY exceeds a certain value. In our case, the optimum composition of the composite electrolyte is 95 wt% SDC and 5 wt% BCY. The BS95 has the highest conductivity(σ1t=0.07808 S cm-1, at 800 °C) and the fuel cell based on the BS95 shows the best performance(the maximum power density reaches as high as 526 mw cm-2 at 750 °C). The encouraging results suggest that the BCY-SDC composites are the very promising electrolyte materials for IT-SOFCs.展开更多
Temperature-dependent aggregation is a key property for some donor polymers to realize favorable bulk-heterojunction(BHJ)morphologies and high-efficiency(>10%) polymer solar cells.Previous studies find that an impo...Temperature-dependent aggregation is a key property for some donor polymers to realize favorable bulk-heterojunction(BHJ)morphologies and high-efficiency(>10%) polymer solar cells.Previous studies find that an important structural feature that enables such temperature-dependent aggregation property is the 2nd position branched alkyl chains sitting between two thiophene units.In this report,we demonstrate that an optimal extent of fluorination on the polymer backbone is a second essential structural feature that enables the strong temperature-dependent aggregation property.We compare the properties of three structurally similar polymers with 0,2 or 4 fluorine substitutions in each repeating unit through an in-depth morphological study.We show that the non-fluorinated polymer does not aggregate in solution(0.02 mg mL^(-1) in chlorobenzene) at room temperature,which results in poor polymer crystallinity and extremely large polymer domains.On the other hand,the polymer with four fluorine atoms in each repeating unit exhibits an excessively strong tendency to aggregate,which makes it difficult to process and causes a large domain.Only the polymer with two fluorine atoms in each repeating unit exhibits a suitable extent of temperature-dependent aggregation property.As a result,its blend film achieves a favorable morphology and high power conversion efficiency.This provides another key design rationale for developing donor polymers with suitable temperature-dependent aggregation properties and thus high performance.展开更多
A biotrickling filter packed with the regular ceramic spheres was designed and fabricated to purify the low toluene-concentration waste gas.Particular attention was made to the study of the start-up behavior of the bi...A biotrickling filter packed with the regular ceramic spheres was designed and fabricated to purify the low toluene-concentration waste gas.Particular attention was made to the study of the start-up behavior of the biotrickling filter.Moreover,the steady performances were investigated to establish the experimental correlation between the operation factors and removal efficiency.It was found that the start-up process of the biotrickling filter exhibited three stages including the biofilm formation,biofilm development,and biofilm stabilization.The OD600 nm of the circulated liquid,gas pressure drop,elimination capacity,and temperature rise maintained at a rather low level in the biofilm formation stage,then increased rapidly in the biofilm development stage,and finally reached a stable value in the biofilm stabilization stage.It was also found that the removal efficiency of the biotrickling filter in the stable period decreased with increase in the waste gas flow rate,circulated liquid flow rate,and diameter of the ceramic sphere.More interestingly,it was revealed the operation modes have a significant influence on the removal efficiency of the biotrickling filter,and the microorganism show a high activity under the operating temperature ranging from 30°C to 40°C.The experimental correlations for describing the effect of operation factors on the removal efficiency of the biotrickling filters under both the co-current and counter-current operation modes were obtained.The correlation results are in good agreement with the experimental data.展开更多
The electronic structure characters are calculated for the Zn1-∞MxO alloys with some Zn atoms in ZnO substituted by 3d transition-metal atoms (M), in order to find out which of these alloys could provide an interme...The electronic structure characters are calculated for the Zn1-∞MxO alloys with some Zn atoms in ZnO substituted by 3d transition-metal atoms (M), in order to find out which of these alloys could provide an intermediate band material used for fabricating high efficiency solar cell. Especially, among of these alloys, the electronic structure character and optical performance of Zn1-xCr∞ 0 alloys clearly show an intermediate band filled partially and isolated from the VB and the CB in energy band structure of ZnO host, and the intermediate band characters can be preserved with increasing Cr concentrations no more than 8.33% in Zn1-xCrxO alloys, at the same time, the ratio 0.52 of Eg^FC to EVE in Zn1-xCrxO, (x = 4.16%) alloy is closest to the optimal ratio of 0,57. Besides, compared to the ZnO, the optical absorption does indicate a great improved absorption below the calculated band gap of the ZnO and an enhancement of the optical absorption in the whole solar spectral energy range.展开更多
文摘A series of microcrystalline silicon thin films were fabricated by very high frequency plasma enhanced chemical vapor deposition (VHF-PECVD) at different silane concentrations in a P chamber. Through analysis of the structural and electrical properties of these materials,we conclude that the photosensitivity slightly decreased then increased as the silane concentration increased,while the crystalline volume fraction indicates the opposite change. Results of XRD indicate that thin films have a (220) preferable orientation under certain conditions. Microcrystalline silicon solar cells with conversion efficiency 4. 7% and micromorph tandem solar cells 8.5% were fabricated by VHF-PECVD (p layer and i layer of microcrystalline silicon solar cells were deposited in P chamber), respectively.
文摘In Japan, various countermeasures have been taken to improve the water quality of public waters such as rivers and lakes. Though water quality has improved, it is still insufficient. In summer, eutrophication is seen in lakes and inner bays, as well as rivers. As a countermeasure to prevent eutrophication, the removal treatment of nutrient salts such as nitrogen and phosphorus is done, in addition to organic substance elimination in the domestic sewerage system. This report will show the water quality characteristics of rivers and ponds in Japan. It is considered that these investigative results are effective when the water quality improvement of the stabilization ponds where eutrophication occurs are examined in China.
基金Project(2007CB613607)supported by the National Basic Research Program of China
文摘A promising preparation method for lithium hexafluorophosphate(LiPF6)was introduced.Phosphorus pentafluoride(PF5) was first prepared using CaF2 and P2O5 at 280℃for 3 h.LiPF6 was synthesized in acetonitrile solvent by LiF and PF5 at room temperature(20-30℃)for 4 h.The synthesized LiPF6 was characterized by infrared spectrometry and X-ray diffraction(XRD). Atomic absorption and ion chromatography results show that the purity of synthesized LiPF6 reaches 99.98%.Thermal stability of self-synthesized LiPF6 was analyzed by differential thermal analysis and thermogravimetry.The results indicate that the self-synthesized LiPF6 has higher purity,lower impurity contents and better thermal stability than the commercial LiPF6.
基金support of "111" project which was from China Education Department( No. B07019)
文摘The article studies the oscillation features of the water in the square moon pool under the circumstances of wave-flow combined conditions. Comparing with the results of experiments of the square moon pool, a series of studies reveal that the water piston oscillation phenomenon is quite similar to that of the circular one. Two types of oscillation are exhibited under different incoming wave periods, i.e. self-excited oscillation and forced oscillation. The difference between the circular and square moon pool is that the attack angle makes greater influences on the square one. "Beating phenomenon" is also found in the square moon pool which is not mentioned of the circular one.
文摘For All-Solid-State battery applications, Mg2+-ion conducting polymer electrolytes and Mg-metal electrode are currently considered as alternate choices in place of Li+-ion conducting polymer electrolytes/Li-metal electrode. Present paper reports fabrication of All-Solid-State battery based on the following Mg2+-ion conducting nano composite polymer electrolyte (NCPE) films: [85PEO: 15Mg(C104)2] + 5% TiO2 (〈 100 nm), [85PEO: 15Mg(CIO4)2] + 3% SiO2(-8 nm). [85PEO: 15Mg(CIO4)2] + 3% MgO (〈 100 nm), [85PEO:15Mg(C1O4)2] + 3% MgO (-44 μm). NCPE films were prepared by hot-press technique. Solid Polymer Electrolyte (SPE) composition: [85PEO: 15Mg(CIO4)2], identified as high conducting film at room temperature, has been used as ISt--phase host and nano/micro particles of active (MgO)/passive (SiO2, TiO2) fillers as IInd-phase dispersoid. Filler particle dependent conductivity studies identified above mentioned NCPE films as optimum conducting composition (OCC) at room temperature. Ion transport behavior of SPE/NCPE film materials was investigated previously. Present paper reports materials characterization and cell performance studies on All-Solid-State batteries: Mg (Anode) Ⅱ SPE or NCPE films tt C+MnO2+Electrolyte (Cathode). Open circuit voltage (OCV) obtained was in the range: 1.79-1.92 V. The batteries were discharged at room temperature under different load conditions and some important battery parameters have been evaluated from plateau region of cell-potential discharge profiles. All the batteries performed quite satisfactorily specially under low current drain states.
基金sponsored by the National Natural Foundation (40172033),China
文摘This paper deals with geochemical features of gas emitted from the Hubin Springs. The Hubin Springs zone, a strong thermal emission zone, is are locatedd at the north edge of the Tianchi caldera lake. Very young deposits with uncertain eruption date are found on the top area of the Tianwenfeng, which might have been formed in one of the recent eruptions or the Millennium Eruption. It is of significance to study the geochemistry features of the emitting gas from the Hubin Springs to understand the activities of the Tianchi Volcano. This paper systematically sampled and analyzed the gases emitted from the Hubin Springs and discussed their geochemistry features. The results show that there is a high content of deep derived gases, such as CO2, He, CH4 and Ar in Hubin Springs zone. The isotopic ratio of He lies between 4. 18 and 5. 95 Ra. The averaged mantle derived gas content calculated from the ^4He/2^20Ne ratio and He content reaches 67.1%. All these show that the Hubin Springs are located on a special belt of deep gases released in high intensity and large scale. The spatial distribution of Helium isotope is characterized by concavity, showing that this special area may be related to the volcanic edifice. It is highly possible that the released gases represent the residual gas samples of the latest eruptions from the Tianchi Volcano. However more detailed studies are demanded.
基金the National Natural Science Foundation of China (Grant No. 40075018).
文摘Using the 1961–1995 monthly averaged meteorological data from 148 surface stations in the Qinghai-Xizang Plateau (QXP) and its surrounding areas, calculation of the 35-year atmospheric heat source/sink (<Qi>) and an analysis on its climatic features and relation to rainfall in China have been made. It is found that on the average, the atmospheric heat source over the QXP is the strongest in June (78 W / m2) and cold source is the strongest in December (?72 W/m2). The sensible heat of the surface increases remarkably over the southwest of the QXP, causing the obvious increase of <Qi> there in February and March, which makes a center of the atmospheric heat source appear over the north slope of the Himalayas. Afterwards, this center continues to intensify and experiences noticeable migration westwards twice, separately occurring in April and June. The time when the atmosphere over the east of the QXP becomes heat source and reaches strongest is one month later than that over the southwest of the QXP. In summer, the latent heat of condensation becomes a heating factor as important as the sensible heat and is also a main factor that makes the atmospheric heat source over the east of the QXP continue growing. On the interdecadal time scale, (Q1) of the QXP shows an abrupt change in 1977 and a remarkable increase after 1977. The atmospheric heat source of the spring over the QXP is a good indicator for the subsequent summer rainfall over the valleys of the Changjiang and Huaihe rivers and South China and North China. There is remarkable positive correlation between the QXP heat source of summer and the summer rainfall in the valleys of the Changjiang River.
文摘The olivine-typed cathode material of Li Fe PO4 was prepared via sol-gel method,and the bromine was doped into Li Fe PO4.The crystal structure,morphology,and electrochemical properties of the samples were investigated by X-ray diffraction,scanning electron microscopy and charge–discharge cycle measurements.The results showed that the electrochemical performance of Li Fe PO4 had been improved by bromine doping,and the best doping amount of bromine is 2%.The discharge capacity of this sample can reach 152 m Ah/g at 0.2 C.
文摘Premenstrual syndrome(PMS) is a collection of physical and emotional symptoms occurring two weeks prior to woman's menstruation, such as tension, emotional upset, attention deficit, irritability, depression and anxiety, insomnia, headache and distending breasts, which vanish shortly after the start of menses. Serious PMS can affect the sufferers' work,
基金supported by the Natural Science Foundation of Liaoning Province(2013020010)
文摘The Ba Ce0.8Y0.2O2.9-Ce0.85Sm0.15O1.925 composite electrolytes were prepared with Ba Ce0.8Y0.2O2.9(BCY) and Ce0.85Sm0.15O1.925(SDC). The SDC and BCY powders were mixed in the weight ratio of 95:5, 85:15, and 75:25, respectively(named as BS95, BS85, and BS75). Because of the composite effect between the SDC and BCY phases, the BS95 and BS85 exhibit improved conductivity compared with the pure SDC and BCY. The conductivity of BS95 is higher than that of BS85, indicating that the composite effect of BS95 is greater than that of BS85. Nevertheless, the composite effect in BS75 does not exist. Hence, we conclude that the composite effect in the BCY-SDC composites will decrease with the increase of the amount of BCY and even disappear when the amount of BCY exceeds a certain value. In our case, the optimum composition of the composite electrolyte is 95 wt% SDC and 5 wt% BCY. The BS95 has the highest conductivity(σ1t=0.07808 S cm-1, at 800 °C) and the fuel cell based on the BS95 shows the best performance(the maximum power density reaches as high as 526 mw cm-2 at 750 °C). The encouraging results suggest that the BCY-SDC composites are the very promising electrolyte materials for IT-SOFCs.
基金supported by the National Basic Research Program of China(2013CB834705)HK JEBN Limited(Hong Kong)+3 种基金the Hong Kong Research Grants Council(T23-407/13-N,N_HKUST623/13,606012)HKUST President's Office through SSTSP scheme(EP201)the National Natural Science Foundation of China(21374090,21504066,21534003,51320105014)supported by the Director,Office of Science,Office of Basic Energy Sciences,of the US Department of Energy under Contract No.DE-AC02-05CH11231
文摘Temperature-dependent aggregation is a key property for some donor polymers to realize favorable bulk-heterojunction(BHJ)morphologies and high-efficiency(>10%) polymer solar cells.Previous studies find that an important structural feature that enables such temperature-dependent aggregation property is the 2nd position branched alkyl chains sitting between two thiophene units.In this report,we demonstrate that an optimal extent of fluorination on the polymer backbone is a second essential structural feature that enables the strong temperature-dependent aggregation property.We compare the properties of three structurally similar polymers with 0,2 or 4 fluorine substitutions in each repeating unit through an in-depth morphological study.We show that the non-fluorinated polymer does not aggregate in solution(0.02 mg mL^(-1) in chlorobenzene) at room temperature,which results in poor polymer crystallinity and extremely large polymer domains.On the other hand,the polymer with four fluorine atoms in each repeating unit exhibits an excessively strong tendency to aggregate,which makes it difficult to process and causes a large domain.Only the polymer with two fluorine atoms in each repeating unit exhibits a suitable extent of temperature-dependent aggregation property.As a result,its blend film achieves a favorable morphology and high power conversion efficiency.This provides another key design rationale for developing donor polymers with suitable temperature-dependent aggregation properties and thus high performance.
基金supported by the National Natural Science Foundation of China (Grant No. 50806086)the National Science Fund of China for Distinguished Young Scholars (Grant No. 50825602)
文摘A biotrickling filter packed with the regular ceramic spheres was designed and fabricated to purify the low toluene-concentration waste gas.Particular attention was made to the study of the start-up behavior of the biotrickling filter.Moreover,the steady performances were investigated to establish the experimental correlation between the operation factors and removal efficiency.It was found that the start-up process of the biotrickling filter exhibited three stages including the biofilm formation,biofilm development,and biofilm stabilization.The OD600 nm of the circulated liquid,gas pressure drop,elimination capacity,and temperature rise maintained at a rather low level in the biofilm formation stage,then increased rapidly in the biofilm development stage,and finally reached a stable value in the biofilm stabilization stage.It was also found that the removal efficiency of the biotrickling filter in the stable period decreased with increase in the waste gas flow rate,circulated liquid flow rate,and diameter of the ceramic sphere.More interestingly,it was revealed the operation modes have a significant influence on the removal efficiency of the biotrickling filter,and the microorganism show a high activity under the operating temperature ranging from 30°C to 40°C.The experimental correlations for describing the effect of operation factors on the removal efficiency of the biotrickling filters under both the co-current and counter-current operation modes were obtained.The correlation results are in good agreement with the experimental data.
基金Supported by the State Key Program for Basic Research of China under Grant No.2006CB921803Project of High Technology Research&Development of China(Project No.2007AA03Z404)+1 种基金National Natural Science Foundation of China under Grant Nos.61274058,60990312,and 61025020Natural Science Foundation of Anhui Province under Grant No.1208085QF116
文摘The electronic structure characters are calculated for the Zn1-∞MxO alloys with some Zn atoms in ZnO substituted by 3d transition-metal atoms (M), in order to find out which of these alloys could provide an intermediate band material used for fabricating high efficiency solar cell. Especially, among of these alloys, the electronic structure character and optical performance of Zn1-xCr∞ 0 alloys clearly show an intermediate band filled partially and isolated from the VB and the CB in energy band structure of ZnO host, and the intermediate band characters can be preserved with increasing Cr concentrations no more than 8.33% in Zn1-xCrxO alloys, at the same time, the ratio 0.52 of Eg^FC to EVE in Zn1-xCrxO, (x = 4.16%) alloy is closest to the optimal ratio of 0,57. Besides, compared to the ZnO, the optical absorption does indicate a great improved absorption below the calculated band gap of the ZnO and an enhancement of the optical absorption in the whole solar spectral energy range.