A numerical tool, called Hydro-Geosphere, was used to simulate unsaturated water flow and contaminants migration around an open pit filled with mining wastes. Numerical simulations had been carried out to assess the i...A numerical tool, called Hydro-Geosphere, was used to simulate unsaturated water flow and contaminants migration around an open pit filled with mining wastes. Numerical simulations had been carried out to assess the influence of various factors on water flow and solute transport in and around the surface openings including recharge, properties of the waste material and presence of fractures in the surrounding rock mass. The effect of the regional hydraulic gradient was also investigated. The analyses were conducted by simulating various 2D cases using experimentally obtained material properties and controlled boundary conditions. The effects of the hydrogeological properties of the filling material(i.e., water retention curve and hydraulic conductivity function), fracture network characteristics and conductivity of the joints were assessed. The results illustrate that fractures control water flow and contaminants transport around the waste disposal area. A fracture network can desaturate the system and improve the regional gradient effect.展开更多
The pollutants from the 15 rivers inflowing into Lake Taihu accounted for about 80% of the total amount of the pollutants inflowing into Lake Taihu. Therefore, overall treatment of the inflowing rivers of Taihu Lake i...The pollutants from the 15 rivers inflowing into Lake Taihu accounted for about 80% of the total amount of the pollutants inflowing into Lake Taihu. Therefore, overall treatment of the inflowing rivers of Taihu Lake is of great importance to the improvement of water environment in the valley and the eutrophication status in th lake. Firstly, the basic ideas, key taches and main methods for water pollution control of inflow rivers of Taihu Lake was put forward in this article, Basic on these theories, the pollutant source status in the comprehensive treatment zone of the 15 major inflow rivers was analysized, the countermeasures of pollution control and main regulation projects were introduced, and the total abatement of pollutants was predicted. With the implement of regulation projects, the number of rivers with water quality worse than Grade V among the 15 major inflow rivers had come from 9 to 3, and the eutrophication status of Taihu Lake had changed from medium level to light level. The overall treatment of the major inflow rivers of the Taihu Lake had achieved initial success.展开更多
A greenhouse experiment was conducted using stratified paddy field models, which were prepared by polluted soil with 12.5 cm soil dressing. The paddy models were assembled with open and closed percolation system to fo...A greenhouse experiment was conducted using stratified paddy field models, which were prepared by polluted soil with 12.5 cm soil dressing. The paddy models were assembled with open and closed percolation system to focus the effect of percolation pattern on accumulation of cupper (Cu) and cadmium (Cd) in rice plants in contaminated paddy filed with soil dressing models. Percolation pattern has significant effect on soil environment, especially redox potential that may influence mobilization of Cd, Cu and other elements. In open system percolation models, the plowsole and subsoil were in oxidative condition (600 mV), whereas reduction condition (-200 mV) was measured in closed system percolation models. Accumulations of Cu and Cd in all parts of rice plants (roots, grains, stems and leaves) were found higher in an open system percolation with the paddy field model comparatively than in a closed system percolation. The soil redox (Eh) condition influenced by the percolation pattern might be one of the main factors for uptake and accumulation of Cu and Cd in rice plants. The plant height and stem number were found lower in open system percolation comparatively to closed system percolation. In the yields section, the average panicle length, number of panicle and rice grain/hill and weight of grain/hill were lower in open system percolation than the closed system percolation.展开更多
To evaluate the long-term environmental effect of the nitrobenzene precipitated into Songhua River caused by the explosion accident of CNPC Jilin Petrochemical Company, we have proved that three selected cross section...To evaluate the long-term environmental effect of the nitrobenzene precipitated into Songhua River caused by the explosion accident of CNPC Jilin Petrochemical Company, we have proved that three selected cross sections were all in a completely mixed state which was not affected by the neighborhood flow firstly. The research of the main flux of contaminants indicates that the nitrobenzene flux in all cross sections is less and less, and the attenuation trend is gradually slowing down. From the residual remnant of nitrobenzene in different segments calculated according to the related experimental data, we suppose that parts of nitrobenzene remnant are transferred by the bottom sludge adsorption and resolution. A general analysis model was set up from the one-dimensional counter-flow equation, and functions of atmosphere-water exchange process, deposit-water interaction, and river turbulent mixing and dissemination. The results of this quantification analysis are different from the real calculation, while the gross transformation trend is the same, which indicates that both analyses are based on reality and can reflect the transport and transformation of nitrobenzene actually.展开更多
Eddy-covariance observations from the Beijing 325-m meteorological tower are used to evaluate the effects of coordinate rotation on the turbulent exchange of momentum and scalars during wintertime haze pollution(Janua...Eddy-covariance observations from the Beijing 325-m meteorological tower are used to evaluate the effects of coordinate rotation on the turbulent exchange of momentum and scalars during wintertime haze pollution(January-February 2013). Two techniques are used in the present evaluation; namely, the natural wind coordinate(NWC) and the planar fit coordinate(PFC), with the latter being applied by means of two methods for linear regression(i.e., overall and sector-wise). The different techniques show a general agreement in both turbulent fluxes and transport efficiencies, especially evident at the lower, 140-m level above the ground(compared to the higher, 280-m level), perhaps implying that the selection of a technique for coordinate rotation(NWC or PFC) is less of a concern for a sufficiently low level, despite the complexities of urban terrain. Additionally, sector-wise regression is a recommended approach for practical application of the PFC in a complex urban environment subjected to particulate pollution, because this method is found to produce a better correlation between the mean vertical velocity at the 140- and 280-m heights.展开更多
The Nanfei River (Anhui Province, China) is a severely polluted urban river that flows into Chaohu Lake. In the present study, sediments were collected from the river and analyzed for their heavy metal contents. Mul...The Nanfei River (Anhui Province, China) is a severely polluted urban river that flows into Chaohu Lake. In the present study, sediments were collected from the river and analyzed for their heavy metal contents. Multivariate statistics and the fuzzy comprehensive assessment method were used to determine the sources of pollution, the current pollution status, and spatial and temporal variations in heavy metal pollution in sediments. The concentrations of arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), nickel (Ni), lead (Pb), and zinc (Zn) in sediments ranged from 5.67-113, 0.08-40.2, 41.6-524, 15.5-460, 0.03-4.84, 13.5-180, 18.8-250, and 47.9-1 996 mg/kg, and the average concentrations of each metal were 1.7, 38.7, 1.8, 5.5, l 8.8, 1.3, 2.5, and 11.1 times greater than the background values, respectively. Multivariate statistical analysis demonstrated that Hg, Cu, Cr, Cd, and Ni may have originated from industrial activities, whereas As and Pb came from agricultural activities. The fuzzy comprehensive assessment method, based on the fuzzy mathematics theory, was used to obtain a detailed assessment of the sediment quality in the Nanfei River watershed. The results indicated that the pollution was moderate in the downstream tributaries of the Nianbu and Dianbu Rivers, but was severe in the main channel of the Nanfei River and in the upstream tributaries of the Sill and Banqiao Rivers. Therefore, sediments in the Nanfei River watershed are heavily polluted and urgent measures should be taken to remedy the status.展开更多
Recent improvements to sewerage systems have meant that the relative contribution of point sources of pollution to the overall pollutant loads of streams has decreased markedly. Consequently, the potential increase in...Recent improvements to sewerage systems have meant that the relative contribution of point sources of pollution to the overall pollutant loads of streams has decreased markedly. Consequently, the potential increase in non-point source pollution means that it may be necessary to focus more on pollution loads from non-point sources in the future. This study examined pollution loads from non-point sources in streams flowing through forested areas. In addition, the relationship between runoff and pollution loads was also clarified. The small streams in the Tohoku University Botanical Gardens, in Sendai city, Japan, were sampled during a dry weather period and their water quality parameters were characterized. Chemical Oxygen Demand (COD) concentration increased with distance downstream, possibly because the soils in downstream areas contained high amounts of organic matter. Conversely, the concentration of nitrate nitrogen (NO3-N) decreased with distance downstream, probably because upstream soils were generally in an oxidized state while those further downstream were reduced. COD concentration increased with air temperature, while NO3-N levels decreased with an increase in air temperatures.展开更多
Arsenic (As), Barium (Ba), Cadmium (Cd), Cobalt (Co), Chromium (Cr), Copper (Cu), Iron (Fe), Manganese (Mn), Lead (Pb) and Zinc (Zn) concentrations were investigated in sediments collected from six...Arsenic (As), Barium (Ba), Cadmium (Cd), Cobalt (Co), Chromium (Cr), Copper (Cu), Iron (Fe), Manganese (Mn), Lead (Pb) and Zinc (Zn) concentrations were investigated in sediments collected from sixteen sampling sites in the Lubumbashi river basin and five sites in Kafubu, Kimilolo and Kinkalabwamba rivers during February, March and April 2016. Analyses of the samples were carried out using a portable X-RFS (X-Ray Fluorescence Spectrometer). Water pH and OM (Organic Matter) content of the sediments were also determined. Trace metal toxicity risk to aquatic organisms was assessed using SQGs (Sediment Quality Guidelines)---TELs (Threshold Effect Levels) and PELs (Probable Effect Levels)---for freshwater sediments. Mean values ofpH and OM ranged from 4.2 to 7.8 and from 1.27% to 6.22%, respectively. The highest mean levels of trace metals in sediments were 5,438 mg·kg-1·dw and 902.5 mg·kg-1·dw for Cu and Co, respectively in Lubumbashi river 1.45 kilometer downward the Lubumbashi Slag heap, 1,534.5 mg·kg-1·dw and 342 mg·kg-1·dwdw for Zn and Pb, respectively at the confluence of Lubumbashi and Kafubu rivers, 108,900 mg·kg-1·dw, 547 mg·kg-1·dw and 174.5 mg·kg-1·dw for Fe, Ba and Cr, respectively in Kinkalabwamba river, 531 mg·kg-1·dw and 22 mg-kgl'dw for Mn and Cd, respectively in Kimilolo river, and 37 mg·kg-1·dw for As at the confluence of Tshondo and Lubumbashi rivers. The mean concentrations of As, Cd, Cr, Cu, Pb and Zn in the sediments exceeded the corresponding SQGs' PELvalues and could have adverse effects on aquatic organisms of those rivers. Trace metal contamination of the studied sediments might he partially attributed to natural processes, unplanned urbanization and poor waste management and mostly to abandoned and ongoing mining and ore processing activities in Lubumbashi city.展开更多
Laboratory research and engineering applications demonstrated that oxygen aeration can rapidly increase the level of dissolved oxygen in the water of severely polluted rivers. This method was capable of eliminating th...Laboratory research and engineering applications demonstrated that oxygen aeration can rapidly increase the level of dissolved oxygen in the water of severely polluted rivers. This method was capable of eliminating the odorous substances from black odorous water and reducing the color shade of water, but could not remove the NH3-N, COD, TP or other common pollutants. Therefore, oxygen aeration can be implemented to rapidly eliminate black odorous from rivers, lakes and reservoirs, but cannot be used as a permanent method for treating pollution of rivers.展开更多
Using the RMA4 water quality model to simulate the water quality of Neijiang river in Zhenjiang, the result showed that: in the dry season the ranges of the concentration of various pollutants simulation of Neijiang ...Using the RMA4 water quality model to simulate the water quality of Neijiang river in Zhenjiang, the result showed that: in the dry season the ranges of the concentration of various pollutants simulation of Neijiang were BOD5 3.2-5.2 mg/L, CODMn 4.7-6.8 mg/L, NH3-N 0.46-1.8 mg/L, TP 0.23-0.48 mg/L, and in the rainy period, the ranges of the concentration of various pollutants simulation of Neijiang were BOD5 0.69-0.73 mg/L, CODM, 1.9-2.3 mg/L, NH3-N 0.25-0.38 mg/L, TP 0.14-0.17 mg/L.These simulated values were closed to the monitoring values of pollution concentrations of Neijiang, which indicated that RMA4 was certain practical in the river water quality simulation, and simulation results have a certain degree of reliability, and it provides a scientific planning and management method for the river pollution control.展开更多
River water plays a key role in human health, and in social and economic development, and is often affected by both natural factors and human activities. An in-depth understanding of the role of these factors can help...River water plays a key role in human health, and in social and economic development, and is often affected by both natural factors and human activities. An in-depth understanding of the role of these factors can help in developing an effective catchment management strategy to protect precious water resources. This study analyzed river water quality, patterns of terrestrial and riparian ecosystems, intensity of agricultural activities, industrial structure, and spatial distribution of pollutant emissions in the Haihe River Basin in China for the year of 2010, identifying the variables that have the greatest impact on river water quality. The area percentage of farmland in study area, the percentage of natural vegetation cover in the 1000-m riparian zone, rural population density, industrial Gross Domestic Product(GDP)/km^2, and industrial amino nitrogen emissions were all significantly correlated with river water quality(P < 0.05). Farming had the largest impact on river water quality, explaining 43.0% of the water quality variance, followed by the coverage of natural vegetation in the 1000-m riparian zone, which explained 36.2% of the water quality variance. Industrial amino nitrogen emissions intensity and rural population density explained 31.6% and 31.4% of the water quality variance, respectively, while industrial GDP/km^2 explained 26.6%. Together, these five indicators explained 67.3% of the total variance in water quality. Consequently, water environmental management of the Haihe River Basin should focus on adjusting agricultural activities, conserving riparian vegetation, and reducing industrial pollutant emissions by optimizing industrial structure. The results demonstrate how human activities drive the spatial pattern changes of river water quality, and they can provide reference for developing land use guidelines and for prioritizing management practices to maintain stream water quality in a large river basin.展开更多
This study addressed the relationship of river water pollution characteristics to land covers and human activities in the catchments in a complete river system named Cao-E River in eastern China.Based on the hydrogeoc...This study addressed the relationship of river water pollution characteristics to land covers and human activities in the catchments in a complete river system named Cao-E River in eastern China.Based on the hydrogeochemical data collected monthly over a period of 3 years,cluster analysis(CA) and principal component analysis(PCA) were adopted to categorize the river reaches and reveal their pollution characteristics.According to the differences of water quality in the river reaches and land use patterns and average population densities in their catchments,the whole river system could be categorized into three groups of river reaches,i.e.,non-point sources pollution reaches(NPSPR),urban reaches(UR) and mixed sources pollution reaches(MSPR).In UR and MSPR,the water quality was mainly impacted by nutrient and organic pollution,while in NPSPR nutrient pollution was the main cause.The nitrate was the main nitrogen form in NPSPR and particulate phosphorus was the main phosphorus form in MSPR.There were no apparent trends for the variations of pollutant concentrations with increasing river flows in NPSPR and MSPR,while in UR the pollutant concentrations decreased with increasing river flows.Thus dry season was the critical period for water pollution control in UR.Therefore,catchment land covers and human activities had significant impact on river reach water pollution type,nutrient forms and water quality responses to hydrological conditions,which might be crucial for developing strategies to combat water pollution in watershed scale.展开更多
We present a systematic study to reveal the effect of host galaxy contamination to the identification of X-ray "unobscured" Seyfert 2 galaxies.We compiled a sample of 14 X-ray "unobscured" Seyfert ...We present a systematic study to reveal the effect of host galaxy contamination to the identification of X-ray "unobscured" Seyfert 2 galaxies.We compiled a sample of 14 X-ray "unobscured" Seyfert 2 galaxies and 29 X-ray obscured Seyfert 2s,with infrared [Ne II] and [O IV] emission line flux measurements.In this work we classify Seyfert 2s as "unobscured" or obscured in X-ray simply based on X-ray spectral fitting.We find that our X-ay "unobscured" Seyfert 2s have statistically higher [Ne II]/[O IV] line ratios,compared with obscured ones.Since the [Ne II]/[O IV] line ratio reflects the relative strength of star formation activity comparing with the SMBH accretion,the observed differences in [Ne II]/[O IV] line ratios clearly indicate relatively stronger X-ray contamination from star formation in the host galaxies in X-ray "unobscured" Seyfert 2s.Therefore we could attribute the X-ray "unobscured" appearance to host galaxy contamination for most(if not all) of our X-ray "unobscured" Seyfert 2s.Further analysis indicates that "unobscured" Seyfert 2s have intrinsically lower AGN luminosity but similar star formation rates,compared with obscured ones.This is also consistent with previous studies showing most X-ray "unobscured" Seyfert 2s are at lower luminosities,and relatively stronger contaminations from the host galaxies are thus expected.Finally we develop a screening criterion to distinguish potential pure Seyfert 2s from X-ray "unobscured" appearances which could be caused by strong host galaxy contamination.展开更多
基金financial support of the Natural Sciences and Engineering Research Council of Canada (NSERC)the partners of Research Institute on Mines and the Environment (RIME UQAT-Polytechnique)
文摘A numerical tool, called Hydro-Geosphere, was used to simulate unsaturated water flow and contaminants migration around an open pit filled with mining wastes. Numerical simulations had been carried out to assess the influence of various factors on water flow and solute transport in and around the surface openings including recharge, properties of the waste material and presence of fractures in the surrounding rock mass. The effect of the regional hydraulic gradient was also investigated. The analyses were conducted by simulating various 2D cases using experimentally obtained material properties and controlled boundary conditions. The effects of the hydrogeological properties of the filling material(i.e., water retention curve and hydraulic conductivity function), fracture network characteristics and conductivity of the joints were assessed. The results illustrate that fractures control water flow and contaminants transport around the waste disposal area. A fracture network can desaturate the system and improve the regional gradient effect.
文摘The pollutants from the 15 rivers inflowing into Lake Taihu accounted for about 80% of the total amount of the pollutants inflowing into Lake Taihu. Therefore, overall treatment of the inflowing rivers of Taihu Lake is of great importance to the improvement of water environment in the valley and the eutrophication status in th lake. Firstly, the basic ideas, key taches and main methods for water pollution control of inflow rivers of Taihu Lake was put forward in this article, Basic on these theories, the pollutant source status in the comprehensive treatment zone of the 15 major inflow rivers was analysized, the countermeasures of pollution control and main regulation projects were introduced, and the total abatement of pollutants was predicted. With the implement of regulation projects, the number of rivers with water quality worse than Grade V among the 15 major inflow rivers had come from 9 to 3, and the eutrophication status of Taihu Lake had changed from medium level to light level. The overall treatment of the major inflow rivers of the Taihu Lake had achieved initial success.
文摘A greenhouse experiment was conducted using stratified paddy field models, which were prepared by polluted soil with 12.5 cm soil dressing. The paddy models were assembled with open and closed percolation system to focus the effect of percolation pattern on accumulation of cupper (Cu) and cadmium (Cd) in rice plants in contaminated paddy filed with soil dressing models. Percolation pattern has significant effect on soil environment, especially redox potential that may influence mobilization of Cd, Cu and other elements. In open system percolation models, the plowsole and subsoil were in oxidative condition (600 mV), whereas reduction condition (-200 mV) was measured in closed system percolation models. Accumulations of Cu and Cd in all parts of rice plants (roots, grains, stems and leaves) were found higher in an open system percolation with the paddy field model comparatively than in a closed system percolation. The soil redox (Eh) condition influenced by the percolation pattern might be one of the main factors for uptake and accumulation of Cu and Cd in rice plants. The plant height and stem number were found lower in open system percolation comparatively to closed system percolation. In the yields section, the average panicle length, number of panicle and rice grain/hill and weight of grain/hill were lower in open system percolation than the closed system percolation.
基金the National Basic Research Program of China(973 Program) (Grant No.2004CB4185).
文摘To evaluate the long-term environmental effect of the nitrobenzene precipitated into Songhua River caused by the explosion accident of CNPC Jilin Petrochemical Company, we have proved that three selected cross sections were all in a completely mixed state which was not affected by the neighborhood flow firstly. The research of the main flux of contaminants indicates that the nitrobenzene flux in all cross sections is less and less, and the attenuation trend is gradually slowing down. From the residual remnant of nitrobenzene in different segments calculated according to the related experimental data, we suppose that parts of nitrobenzene remnant are transferred by the bottom sludge adsorption and resolution. A general analysis model was set up from the one-dimensional counter-flow equation, and functions of atmosphere-water exchange process, deposit-water interaction, and river turbulent mixing and dissemination. The results of this quantification analysis are different from the real calculation, while the gross transformation trend is the same, which indicates that both analyses are based on reality and can reflect the transport and transformation of nitrobenzene actually.
基金funded by the National Basic Research Program of China(Grant No.2014CB447900)National High Technology Research and Development Program(Grant No.2014AA06A512)Ministry of Environmental Protection of China through its Special Funds for Scientific Research on Public Welfare(Grant No.201409001)
文摘Eddy-covariance observations from the Beijing 325-m meteorological tower are used to evaluate the effects of coordinate rotation on the turbulent exchange of momentum and scalars during wintertime haze pollution(January-February 2013). Two techniques are used in the present evaluation; namely, the natural wind coordinate(NWC) and the planar fit coordinate(PFC), with the latter being applied by means of two methods for linear regression(i.e., overall and sector-wise). The different techniques show a general agreement in both turbulent fluxes and transport efficiencies, especially evident at the lower, 140-m level above the ground(compared to the higher, 280-m level), perhaps implying that the selection of a technique for coordinate rotation(NWC or PFC) is less of a concern for a sufficiently low level, despite the complexities of urban terrain. Additionally, sector-wise regression is a recommended approach for practical application of the PFC in a complex urban environment subjected to particulate pollution, because this method is found to produce a better correlation between the mean vertical velocity at the 140- and 280-m heights.
基金Supported by the Major Science and Technology Program for Water Pollution Control and Treatment(No.2012ZX07103-005)
文摘The Nanfei River (Anhui Province, China) is a severely polluted urban river that flows into Chaohu Lake. In the present study, sediments were collected from the river and analyzed for their heavy metal contents. Multivariate statistics and the fuzzy comprehensive assessment method were used to determine the sources of pollution, the current pollution status, and spatial and temporal variations in heavy metal pollution in sediments. The concentrations of arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), nickel (Ni), lead (Pb), and zinc (Zn) in sediments ranged from 5.67-113, 0.08-40.2, 41.6-524, 15.5-460, 0.03-4.84, 13.5-180, 18.8-250, and 47.9-1 996 mg/kg, and the average concentrations of each metal were 1.7, 38.7, 1.8, 5.5, l 8.8, 1.3, 2.5, and 11.1 times greater than the background values, respectively. Multivariate statistical analysis demonstrated that Hg, Cu, Cr, Cd, and Ni may have originated from industrial activities, whereas As and Pb came from agricultural activities. The fuzzy comprehensive assessment method, based on the fuzzy mathematics theory, was used to obtain a detailed assessment of the sediment quality in the Nanfei River watershed. The results indicated that the pollution was moderate in the downstream tributaries of the Nianbu and Dianbu Rivers, but was severe in the main channel of the Nanfei River and in the upstream tributaries of the Sill and Banqiao Rivers. Therefore, sediments in the Nanfei River watershed are heavily polluted and urgent measures should be taken to remedy the status.
文摘Recent improvements to sewerage systems have meant that the relative contribution of point sources of pollution to the overall pollutant loads of streams has decreased markedly. Consequently, the potential increase in non-point source pollution means that it may be necessary to focus more on pollution loads from non-point sources in the future. This study examined pollution loads from non-point sources in streams flowing through forested areas. In addition, the relationship between runoff and pollution loads was also clarified. The small streams in the Tohoku University Botanical Gardens, in Sendai city, Japan, were sampled during a dry weather period and their water quality parameters were characterized. Chemical Oxygen Demand (COD) concentration increased with distance downstream, possibly because the soils in downstream areas contained high amounts of organic matter. Conversely, the concentration of nitrate nitrogen (NO3-N) decreased with distance downstream, probably because upstream soils were generally in an oxidized state while those further downstream were reduced. COD concentration increased with air temperature, while NO3-N levels decreased with an increase in air temperatures.
文摘Arsenic (As), Barium (Ba), Cadmium (Cd), Cobalt (Co), Chromium (Cr), Copper (Cu), Iron (Fe), Manganese (Mn), Lead (Pb) and Zinc (Zn) concentrations were investigated in sediments collected from sixteen sampling sites in the Lubumbashi river basin and five sites in Kafubu, Kimilolo and Kinkalabwamba rivers during February, March and April 2016. Analyses of the samples were carried out using a portable X-RFS (X-Ray Fluorescence Spectrometer). Water pH and OM (Organic Matter) content of the sediments were also determined. Trace metal toxicity risk to aquatic organisms was assessed using SQGs (Sediment Quality Guidelines)---TELs (Threshold Effect Levels) and PELs (Probable Effect Levels)---for freshwater sediments. Mean values ofpH and OM ranged from 4.2 to 7.8 and from 1.27% to 6.22%, respectively. The highest mean levels of trace metals in sediments were 5,438 mg·kg-1·dw and 902.5 mg·kg-1·dw for Cu and Co, respectively in Lubumbashi river 1.45 kilometer downward the Lubumbashi Slag heap, 1,534.5 mg·kg-1·dw and 342 mg·kg-1·dwdw for Zn and Pb, respectively at the confluence of Lubumbashi and Kafubu rivers, 108,900 mg·kg-1·dw, 547 mg·kg-1·dw and 174.5 mg·kg-1·dw for Fe, Ba and Cr, respectively in Kinkalabwamba river, 531 mg·kg-1·dw and 22 mg-kgl'dw for Mn and Cd, respectively in Kimilolo river, and 37 mg·kg-1·dw for As at the confluence of Tshondo and Lubumbashi rivers. The mean concentrations of As, Cd, Cr, Cu, Pb and Zn in the sediments exceeded the corresponding SQGs' PELvalues and could have adverse effects on aquatic organisms of those rivers. Trace metal contamination of the studied sediments might he partially attributed to natural processes, unplanned urbanization and poor waste management and mostly to abandoned and ongoing mining and ore processing activities in Lubumbashi city.
文摘Laboratory research and engineering applications demonstrated that oxygen aeration can rapidly increase the level of dissolved oxygen in the water of severely polluted rivers. This method was capable of eliminating the odorous substances from black odorous water and reducing the color shade of water, but could not remove the NH3-N, COD, TP or other common pollutants. Therefore, oxygen aeration can be implemented to rapidly eliminate black odorous from rivers, lakes and reservoirs, but cannot be used as a permanent method for treating pollution of rivers.
文摘Using the RMA4 water quality model to simulate the water quality of Neijiang river in Zhenjiang, the result showed that: in the dry season the ranges of the concentration of various pollutants simulation of Neijiang were BOD5 3.2-5.2 mg/L, CODMn 4.7-6.8 mg/L, NH3-N 0.46-1.8 mg/L, TP 0.23-0.48 mg/L, and in the rainy period, the ranges of the concentration of various pollutants simulation of Neijiang were BOD5 0.69-0.73 mg/L, CODM, 1.9-2.3 mg/L, NH3-N 0.25-0.38 mg/L, TP 0.14-0.17 mg/L.These simulated values were closed to the monitoring values of pollution concentrations of Neijiang, which indicated that RMA4 was certain practical in the river water quality simulation, and simulation results have a certain degree of reliability, and it provides a scientific planning and management method for the river pollution control.
基金Under the auspices of National Natural Science Foundation of China(No.41371538)Independent Project of State Key Laboratory of Urban and Regional Ecology,Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences(No.SKLURE2008-1-02)
文摘River water plays a key role in human health, and in social and economic development, and is often affected by both natural factors and human activities. An in-depth understanding of the role of these factors can help in developing an effective catchment management strategy to protect precious water resources. This study analyzed river water quality, patterns of terrestrial and riparian ecosystems, intensity of agricultural activities, industrial structure, and spatial distribution of pollutant emissions in the Haihe River Basin in China for the year of 2010, identifying the variables that have the greatest impact on river water quality. The area percentage of farmland in study area, the percentage of natural vegetation cover in the 1000-m riparian zone, rural population density, industrial Gross Domestic Product(GDP)/km^2, and industrial amino nitrogen emissions were all significantly correlated with river water quality(P < 0.05). Farming had the largest impact on river water quality, explaining 43.0% of the water quality variance, followed by the coverage of natural vegetation in the 1000-m riparian zone, which explained 36.2% of the water quality variance. Industrial amino nitrogen emissions intensity and rural population density explained 31.6% and 31.4% of the water quality variance, respectively, while industrial GDP/km^2 explained 26.6%. Together, these five indicators explained 67.3% of the total variance in water quality. Consequently, water environmental management of the Haihe River Basin should focus on adjusting agricultural activities, conserving riparian vegetation, and reducing industrial pollutant emissions by optimizing industrial structure. The results demonstrate how human activities drive the spatial pattern changes of river water quality, and they can provide reference for developing land use guidelines and for prioritizing management practices to maintain stream water quality in a large river basin.
基金Supported by the National Natural Science Foundation of China (No. 40871104)the National High Technology Research andDevelopment Program (863 Program) of China (No. 2007AA10Z218)
文摘This study addressed the relationship of river water pollution characteristics to land covers and human activities in the catchments in a complete river system named Cao-E River in eastern China.Based on the hydrogeochemical data collected monthly over a period of 3 years,cluster analysis(CA) and principal component analysis(PCA) were adopted to categorize the river reaches and reveal their pollution characteristics.According to the differences of water quality in the river reaches and land use patterns and average population densities in their catchments,the whole river system could be categorized into three groups of river reaches,i.e.,non-point sources pollution reaches(NPSPR),urban reaches(UR) and mixed sources pollution reaches(MSPR).In UR and MSPR,the water quality was mainly impacted by nutrient and organic pollution,while in NPSPR nutrient pollution was the main cause.The nitrate was the main nitrogen form in NPSPR and particulate phosphorus was the main phosphorus form in MSPR.There were no apparent trends for the variations of pollutant concentrations with increasing river flows in NPSPR and MSPR,while in UR the pollutant concentrations decreased with increasing river flows.Thus dry season was the critical period for water pollution control in UR.Therefore,catchment land covers and human activities had significant impact on river reach water pollution type,nutrient forms and water quality responses to hydrological conditions,which might be crucial for developing strategies to combat water pollution in watershed scale.
基金supported by the National Natural Sciences Foundation of China (Grant No. 10825321)
文摘We present a systematic study to reveal the effect of host galaxy contamination to the identification of X-ray "unobscured" Seyfert 2 galaxies.We compiled a sample of 14 X-ray "unobscured" Seyfert 2 galaxies and 29 X-ray obscured Seyfert 2s,with infrared [Ne II] and [O IV] emission line flux measurements.In this work we classify Seyfert 2s as "unobscured" or obscured in X-ray simply based on X-ray spectral fitting.We find that our X-ay "unobscured" Seyfert 2s have statistically higher [Ne II]/[O IV] line ratios,compared with obscured ones.Since the [Ne II]/[O IV] line ratio reflects the relative strength of star formation activity comparing with the SMBH accretion,the observed differences in [Ne II]/[O IV] line ratios clearly indicate relatively stronger X-ray contamination from star formation in the host galaxies in X-ray "unobscured" Seyfert 2s.Therefore we could attribute the X-ray "unobscured" appearance to host galaxy contamination for most(if not all) of our X-ray "unobscured" Seyfert 2s.Further analysis indicates that "unobscured" Seyfert 2s have intrinsically lower AGN luminosity but similar star formation rates,compared with obscured ones.This is also consistent with previous studies showing most X-ray "unobscured" Seyfert 2s are at lower luminosities,and relatively stronger contaminations from the host galaxies are thus expected.Finally we develop a screening criterion to distinguish potential pure Seyfert 2s from X-ray "unobscured" appearances which could be caused by strong host galaxy contamination.