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盐效应常数的拓扑化学研究——Ⅲ萘在盐水溶液中k_s值的计算
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作者 余训民 唐平 《商丘师范学院学报》 CAS 2001年第2期75-78,共4页
以分子拓扑理论为基础 ,提出了新的拓扑指数Y ,并用Y研究了萘在盐水溶液中的盐效应常数ks.研究表明 ,Y与萘在盐水溶液中的ks 有良好的线性关系 ,并给出了相关方程 .新方法计算方便 ,精确度高 。
关键词 拓扑指数 盐溶液 分子拓扑理论 盐效应常数 非电解质 溶解度 污染物热力学
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Presence of Contaminants in Refrigerant and Their Effect on Refrigeration Cycle
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作者 Dorota Skrzyniowska 《Journal of Energy and Power Engineering》 2014年第2期226-231,共6页
Refrigerant is a medium used in refrigeration cycle. Until now in thermodynamic models calculations of refrigerant is not considered with lubricant and moist air but as an ideal pure gas (without any contaminants). ... Refrigerant is a medium used in refrigeration cycle. Until now in thermodynamic models calculations of refrigerant is not considered with lubricant and moist air but as an ideal pure gas (without any contaminants). This is also the case in refrigeration cycle where the refrigerant is very often considered as an ideal one. Lubricant, air and water vapour are not considered in thermodynamic calculations in spite of their existence. The problems in the existing research are summarized. A further study is suggested on refrigerant systems. This circulation of such calculations is at the origin of a deviation from a theoretical behaviour. This article aims at reviewing the researches of oil-refrigerant, air-refrigerant, moist air-refrigerant or oil-moist air-refrigerant mixtures and focuses particularly on mixture enthalpy calculation. This paper deals with the description of the real mixture of refrigerant and contaminants (lubricant, water, moist air and other remains of refrigerants at elevated pressures and temperatures) which flow in a refrigerating cycle and the main point of this paper is to appoint thermodynamic parameters of such a mixture using the thermodynamic formulas. 展开更多
关键词 Refrigeration system compression system LUBRICATION OIL modeling air conditioning compressed air THERMODYNAMIC specific enthalpy.
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