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非抑制型离子色谱法测定印制电路板表面阳离子污染物 被引量:1
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作者 郑广乐 《福建分析测试》 CAS 2006年第3期29-31,共3页
本文提出了一种利用非抑制型离子色谱法测定印制电路板表面五种无机阳离子污染物的方法。样品用异丙醇水溶液提取后,用Sep-PakC18小柱净化试样,用离子色谱分离,电导检测器检测。五种阴离子的检测限介于0.01~0.02μg/ml之间,回收... 本文提出了一种利用非抑制型离子色谱法测定印制电路板表面五种无机阳离子污染物的方法。样品用异丙醇水溶液提取后,用Sep-PakC18小柱净化试样,用离子色谱分离,电导检测器检测。五种阴离子的检测限介于0.01~0.02μg/ml之间,回收率为98~103%。方法准确、可靠,可用于印制电路板洁净度的评价分析。 展开更多
关键词 印制电路板 非抑制型离子色谱法 阳离子污染
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Performance of Micelle-Clay Filters for Removing Pollutants and Bacteria from Tertiary Treated Wastewater
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作者 Mustafa Khamis Rafik Karaman +4 位作者 Mohannad Qurie Jehad Abbadit SamehNusseibeh Adnan Manassra Shlomo Nir 《Journal of Environmental Science and Engineering(A)》 2012年第2期160-168,共9页
Filters filled with a micelle-clay complex mixed with sand were employed to investigate their purification capability of tertiary treated wastewater with loose UF-membranes. The UF membrane was hollow fiber with a mol... Filters filled with a micelle-clay complex mixed with sand were employed to investigate their purification capability of tertiary treated wastewater with loose UF-membranes. The UF membrane was hollow fiber with a molecular weight cutoff of 100 kD. The complex was prepared from the organic cation octadecyltrimethylammonium (ODTMA) and the negatively charged clay-mineral, montmoriIIonite. This complex has a very large surface area, which includes large hydrophobic domains and is positively charged, about half of the cation exchange capacity of the clay. Two sets of filtration experiments were carried out at flow rates of 1.2 and 50 mL/min, which correspond to flow velocities of 3.7 and 153 cm/h, respectively. In the first case, after a passage of 1 L, the turbidity, total suspended solids (TSS), fecal coliforms (FC), and total coliforms (TC) were reduced to zero from 14 NTU, 6 ppm, 350 and 10,000 counts per 100 mL, respectively. In the second case, the numbers of FC and TC were reduced from 50,000/100 mL to zero after the passage of 14 L. The values of COD and BOD were reduced several-fold. The conclusion is that the incorporation of micelle-clay filters in the sewage treatment system with loose tertiary capability is promising and warrants larger scale experiments for optimization of the overall system. 展开更多
关键词 Clay-micelle complex wastewater treatment chemical oxygen demand biological oxygen demand microbial removal.
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Fertcel Clinoptilolite Natural Product to Optimize the Fertilization and Reduce Environmental Pollution
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作者 Jorge Alberto Febles Gonzalez Femando Borsatto Faria Miguel Soca Nunez 《Journal of Agricultural Science and Technology(B)》 2015年第3期189-192,共4页
The shortages of chemical fertilizers in Cuba in 90s caused the introduction of different research results obtained on this time for the implementation of natural zeolites in the fertilizer industry. It's known as th... The shortages of chemical fertilizers in Cuba in 90s caused the introduction of different research results obtained on this time for the implementation of natural zeolites in the fertilizer industry. It's known as the high capacity of cation exchange of the natural Cuban clinoptilolite, which contributes to reducing nutrient losses, such as ammonia, and keeping the potassium and phosphorus cations available. Extensive tests were done on the field with the objective to evaluate the agronomic effect of incorporating this mineral in fertilizer. The results obtained in this experiment contributed to almost all Cuban chemical fertilizers, which has been incorporated around 15%-20% of natural zeolite clinoptilolite in its composition by Cuban agriculture consumes, reducing the chemical carriers of the fertilizers and decreasing the contamination of the environment. Also this mineral contributes for increases in agricultural income more than 15% in all cases; additionally, a trend can be observed towards gradual recovery of some soil fertility indicators, in which the chemical fertilizers with Fertcel was applied. 展开更多
关键词 Zeolite clinoptilolite FERTILIZATION AGRICULTURE environmental pollution Fertcel.
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罐底油泥热解产物高附加值利用途径 被引量:4
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作者 杨慧芬 李真 +3 位作者 付鹏 宋振国 杨航 马文凯 《环境工程学报》 CAS CSCD 北大核心 2021年第2期717-726,共10页
为探讨罐底油泥热解产物的高附加值利用途径,利用GC-MS、XRF、XRD、SEM-EDS等方法对罐底油泥热解产物进行了详细的性能分析。在此基础上,选择3种典型阴离子Cr(Ⅵ)、PO4^(3-)和F−和3种典型阳离子Cd^(2+)、Pb^(2+)和Cu^(2+)进行了吸附去... 为探讨罐底油泥热解产物的高附加值利用途径,利用GC-MS、XRF、XRD、SEM-EDS等方法对罐底油泥热解产物进行了详细的性能分析。在此基础上,选择3种典型阴离子Cr(Ⅵ)、PO4^(3-)和F−和3种典型阳离子Cd^(2+)、Pb^(2+)和Cu^(2+)进行了吸附去除实验。结果表明:罐底油泥热解得到的油品,其烷烃化合物含量高达50.91%,碳数主要分布在(n-C12)~(n-C30),与矿物浮选药剂制备原料的性能类似;热解得到的残渣具有疏松多孔的结构,其结构骨架由元素C、S、Fe、Ca、Al、Si、O等共同构成,且以FeS、Fe_(1−x)S、Fe_(7)S_(8)、CaS、CaAl_(2)Si_(2)O_(8)晶体矿物及非晶态物相形式镶嵌在其中,在水中可起到还原剂、硫化物沉淀剂和钙盐沉淀剂的作用;热解渣对水中阴、阳离子均有很高的去除率,在热解渣用量分别为3、10、12、1、0.8和0.8 g·L^(−1)时,Cr(Ⅵ)、PO4^(3-)、F^(−)、Cd^(2+)、Pb^(2+)和Cu^(2+)去除率分别达到99.6%、98.9%、96.8%、99.3%、98.9%和99.4%。XRD分析结果表明,上述污染离子的去除是通过在热解渣表面生成FeCr_(2)O_(4)、Ca_(3)(PO_(4))_(2)、CaF_(2)、CdS、Cd(OH)_(2)、CdAl_(2)Si_(2)O_(8)、PbS、Pb(OH)_(2)、PbAl_(2)Si_(2)O_(8)、CuS、Cu(OH)_(2)、CuAl_(2)Si_(2)O_(8)沉淀而实现的。本实验结果可为罐底油泥热解产物尤其热解渣的高附加值利用途径提供参考。 展开更多
关键词 罐底油泥 油品 热解渣 污染离子 污染阳离子 吸附材料
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