Recent studies confirm that the emerging bifunctional catalysts consisting of metal oxide and zeolites can directly convert syngas into high-quality gasoline,however,the formation mechanism of iso-paraffins and the di...Recent studies confirm that the emerging bifunctional catalysts consisting of metal oxide and zeolites can directly convert syngas into high-quality gasoline,however,the formation mechanism of iso-paraffins and the difference with the conventional FT/zeolite catalyst have not been investigated.Herein,three one-dimensional SAPO zeolites with diverse micropore sizes were synthesized and assembled with ZnAlO_(x)with spinel structure.It was found that ZnAlO_(x)/SAPO-41 and ZnAlO_(x)/SAPO-11 with medium micropore sizes favored the formation of C_(5)–C_(11)hydrocarbons with a high content of iso-paraffins.The characterizations pointed out that the formation of iso-paraffins over SAPO-11 followed a pore-mouth catalysis mechanism,which means the isomerization of linear hydrocarbons can only take place near the pore mouth region of zeolites.This mechanism only allows the formation of mono-branched iso-paraffins in the C_(5)–C_(11)range,which are less prone to be cracked than their di-branched isomers.A careful comparative analysis between ZnAlO_(x)/SAPO-11 and Co/H-meso-ZSM-5 was also made in terms of product distribution,activity,and stability.展开更多
With the combination of engine and two electric machines, the power split device allows higher efficiency of the engine. The operation modes of a power split HEV are analyzed, and the system dynamic model is establish...With the combination of engine and two electric machines, the power split device allows higher efficiency of the engine. The operation modes of a power split HEV are analyzed, and the system dynamic model is established for HEV forward simulation and controller design. Considering the fact that the operation modes of the HEV are event-driven and the system dynamics is continuous time-driven for each mode, the structure of the controller is built and described with the hybrid automaton control theory. In this control structure, the mode selection process is depicted by the finite state machine （FSM）. The multi-mode switch controller is designed to realize power distribution. Furthermore, the vehicle mode operations are optimized, and the nonlinear model predictive control （NMPC） strategy is applied by implementing dynamic programming （DP） in the finite pre- diction horizon. Comparative simulation results demonstrate that the hybrid control structure is effective and feasible for HEV energy management design. The NMPC optimal strategy is superior in improving fuel economy.展开更多
The electrical properties of chemically derived graphene and graphene grown by chemical vapor deposition （CVD）, until now, have been inferior to those of mechanically exfoliated graphene. However, because graphene i...The electrical properties of chemically derived graphene and graphene grown by chemical vapor deposition （CVD）, until now, have been inferior to those of mechanically exfoliated graphene. However, because graphene is easier to produce in large quantities through CVD or growth from solid carbon sources, it has a higher potential for use in future electronics applications. Generally, modifications to the pristine lattice structure of graphene tend to adversely affect the electrical properties by shifting the doping level and changing the conductivity and the mobility. Here we show that a small degree of graphene surface functionalization, using diazonium salts with electron-withdrawing and electron-donating functional groups, is sufficient to predominantly induce p-type doping, undiminished mobility, and higher conductivity at the neutrality point. Molecules without a diazonium anchor group desorb easily and do not have a significant effect on the electronic properties of graphene devices. We further demonstrate the variability between identically fabricated pristine devices, thereby underscoring the caution needed when characterizing graphene device behaviors lest conclusions be drawn based on singular extremes.展开更多
文摘Recent studies confirm that the emerging bifunctional catalysts consisting of metal oxide and zeolites can directly convert syngas into high-quality gasoline,however,the formation mechanism of iso-paraffins and the difference with the conventional FT/zeolite catalyst have not been investigated.Herein,three one-dimensional SAPO zeolites with diverse micropore sizes were synthesized and assembled with ZnAlO_(x)with spinel structure.It was found that ZnAlO_(x)/SAPO-41 and ZnAlO_(x)/SAPO-11 with medium micropore sizes favored the formation of C_(5)–C_(11)hydrocarbons with a high content of iso-paraffins.The characterizations pointed out that the formation of iso-paraffins over SAPO-11 followed a pore-mouth catalysis mechanism,which means the isomerization of linear hydrocarbons can only take place near the pore mouth region of zeolites.This mechanism only allows the formation of mono-branched iso-paraffins in the C_(5)–C_(11)range,which are less prone to be cracked than their di-branched isomers.A careful comparative analysis between ZnAlO_(x)/SAPO-11 and Co/H-meso-ZSM-5 was also made in terms of product distribution,activity,and stability.
基金supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the National Natural Science Foundation of China(Grant Nos.51475213&51305167)the Scientific Research Innovation Projects of Jiangsu Province(Grant No.KYLX_1022)
文摘With the combination of engine and two electric machines, the power split device allows higher efficiency of the engine. The operation modes of a power split HEV are analyzed, and the system dynamic model is established for HEV forward simulation and controller design. Considering the fact that the operation modes of the HEV are event-driven and the system dynamics is continuous time-driven for each mode, the structure of the controller is built and described with the hybrid automaton control theory. In this control structure, the mode selection process is depicted by the finite state machine （FSM）. The multi-mode switch controller is designed to realize power distribution. Furthermore, the vehicle mode operations are optimized, and the nonlinear model predictive control （NMPC） strategy is applied by implementing dynamic programming （DP） in the finite pre- diction horizon. Comparative simulation results demonstrate that the hybrid control structure is effective and feasible for HEV energy management design. The NMPC optimal strategy is superior in improving fuel economy.
文摘The electrical properties of chemically derived graphene and graphene grown by chemical vapor deposition （CVD）, until now, have been inferior to those of mechanically exfoliated graphene. However, because graphene is easier to produce in large quantities through CVD or growth from solid carbon sources, it has a higher potential for use in future electronics applications. Generally, modifications to the pristine lattice structure of graphene tend to adversely affect the electrical properties by shifting the doping level and changing the conductivity and the mobility. Here we show that a small degree of graphene surface functionalization, using diazonium salts with electron-withdrawing and electron-donating functional groups, is sufficient to predominantly induce p-type doping, undiminished mobility, and higher conductivity at the neutrality point. Molecules without a diazonium anchor group desorb easily and do not have a significant effect on the electronic properties of graphene devices. We further demonstrate the variability between identically fabricated pristine devices, thereby underscoring the caution needed when characterizing graphene device behaviors lest conclusions be drawn based on singular extremes.
