废电池合金制备氯化镍溶液的工艺研究

对用废旧电池熔铸的含镍废合金制备氯化镍溶液的工艺进行了研究.采用的工艺流程为:盐酸体系膜电解→化学沉淀法除杂→萃取除杂.通过该工艺流程获得的三级萃余液中镍含量大于30 g/L、铁为痕量、钴为0.51 g/L、铜含量小于0.0183 mg/L,该溶液可直接用于电镍生产.

铁含量控制研究进展

在轻工业生产、湿法冶金、水处理等行业,铁含量控制是普遍性问题。本文主要介绍了非金属矿物、金属湿法冶金、以及水处理等行业常用的除铁方法。磁选是非金属矿物和碱性金属湿法冶金首选的除铁方法。但由于非金属矿含铁成分的多样性,以及设备和技术限制,有些产品通过磁选除铁后质量不达标,须结合化学浸出法进一步除铁。酸性湿法冶金除铁主要利用化学沉淀法,以针铁矿法应用最为广泛。氢氧化铁法,多以胶体状态,过滤性能较差。膜分离技术近年来发展迅速,目前以微滤膜(孔径>50 nm)为主,主要应用在生物医药、化工与石化、食品与饮料、特种水处理等领域。地下水除铁,广泛采用锰砂滤料——接触性催化氧化法。无机化工产品进一步提纯到很高纯度,一般通过电化学或物理方法。

Effect of Ferric Chloride on the Properties of Biological Sludge in Co-precipitation Phosphorus Removal Process

This paper studied the effect of ferric chloride on waste sludge digestion,dewatering and sedimentation under the optimized doses in co-precipitation phosphorus removal process.The experimental results showed that the concentration of mixed liquid suspended solid(MLSS) was 2436 mg.L-1 and 2385 mg.L-1 in co-precipitation phosphorus removal process(CPR) and biological phosphorous removal process(BPR),respectively.The sludge reduction ratio for each process was 22.6% and 24.6% in aerobic digestion,and 27.6% and 29.9% in anaerobic digestion,respectively.Due to the addition of chemical to the end of aeration tank,the sludge content of CPR was slightly higher than that of BPR,but the sludge reduction rate for both processes had no distinct difference.The sludge volume index(SVI) and sludge specific resistance of BPR were 126 ml.g-1 and 11.7×1012 m.kg-1,respectively,while those of CPR were only 98 ml.g-1 and 7.1×1012 m.kg-1,indicating that CPR chemical could improve sludge settling and dewatering.