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DOM对沉积物悬浮颗粒吸附铜的促进作用及机制 被引量:8
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作者 丁翔 李忠武 +5 位作者 徐卫华 黄梅 文佳骏 金昌盛 周咪 陈佳 《环境科学》 EI CAS CSCD 北大核心 2021年第8期3837-3846,共10页
沉积物悬浮颗粒对重金属吸附是重金属在湖泊中迁移的关键环节,受到多种环境条件的影响.为了探究溶解性有机质(dissolved organic matter,DOM)对沉积物悬浮颗粒吸附Cu(Ⅱ)的影响及作用机制,通过室内模拟沉积物悬浮液进行Cu(Ⅱ)吸附试验.... 沉积物悬浮颗粒对重金属吸附是重金属在湖泊中迁移的关键环节,受到多种环境条件的影响.为了探究溶解性有机质(dissolved organic matter,DOM)对沉积物悬浮颗粒吸附Cu(Ⅱ)的影响及作用机制,通过室内模拟沉积物悬浮液进行Cu(Ⅱ)吸附试验.结果表明,两种DOM(富里酸和沉积物DOM)不同程度地促进了Cu(Ⅱ)在悬浮颗粒上的吸附;吸附48 h后,吸附百分比从71.51%分别提高到了75.31%和85.69%.扫描电子显微镜-能谱结果显示,在DOM的影响下,Cu(Ⅱ)被吸附后存在于沉积物颗粒内部.紫外-可见光谱技术分析结果表明,在吸附反应过程中,Cu(Ⅱ)与DOM存在先络合后解离的过程.荧光激发发射矩阵结合平行因子分析、同步荧光光谱结合二维相关分析的结果表明,类蛋白组分能够促进Cu(Ⅱ)在沉积物悬浮颗粒上的吸附,其中类酪氨酸组分在促进Cu(Ⅱ)被沉积物颗粒吸附沉淀过程中优先发挥作用,而类腐殖酸组分几乎没有促进吸附作用.完善了湖泊重金属迁移的相关理论,为沉积物重金属污染防治提供了一定的依据. 展开更多
关键词 溶解性有机质(DOM) 沉积物悬浮颗粒 铜离子 吸附 平行因子分析 二维相关分析
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MOLAR RATIOS OF C,N,P OF PARTICULATE MATTER AND THEIR VERTICAL FLUXES IN THE YELLOW SEA 被引量:3
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作者 王保栋 战闰 徐明德 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2002年第1期91-96,共6页
The vertical fluxes and molar ratios of carbon, nitrogen and phosphorus of suspended particulate matter in the Yellow Sea were studied based on the analysis of suspended particulate matter, sediments and sinking parti... The vertical fluxes and molar ratios of carbon, nitrogen and phosphorus of suspended particulate matter in the Yellow Sea were studied based on the analysis of suspended particulate matter, sediments and sinking particles obtained by use of moored sediment traps. The POC:PON ratios indicate that most of the particulate organic matter in the Yellow Sea water column comes from marine life rather than the continent. The vertical fluxes of SPM, POC, PON and POP in the Yellow Sea are much higher than those in other seas over the world, and present a typical pattern in shallow epicontinental seas. The estimated residence time of the bioactive elements showed that the speed of the biogeochemical process of materials in the Yellow Sea is much shorter than that in the open ocean as there was high primary productivity in this region. 展开更多
关键词 vertical flux Redfield ratio particulate matter the Yellow Sea
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THE RESUSPENSION RATE OF SEDIMENTS IN 32°N SECTION ON THE EAST CHINA SEA 被引量:2
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作者 孙治涛 詹滨秋 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2002年第2期191-196,共6页
This research on the influence of sediment resuspension on the flux of materials in the margin of the East China Sea showed that the sediment resuspension rates, was 47.40%-79.18% in the surface layers, and 72.75%-96.... This research on the influence of sediment resuspension on the flux of materials in the margin of the East China Sea showed that the sediment resuspension rates, was 47.40%-79.18% in the surface layers, and 72.75%-96.96% in the bottom layers.The research confirmed that the Changjiang River runoff and the eddy area upwelling flow near 125°E were two important factors affecting the sediment resuspension in summer; the transformation of DOC to POC through the flocculation in the transitional region (123°-124°E) was also confirmed by comparison of the resuspension rate. The sediment resuspension was shown to be influenced by the seasonal factor, especially in the surface layer. 展开更多
关键词 resuspension rate POC DOC East China Sea
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重金属在河口区潮汐界面与盐度界面响应规律研究 被引量:1
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作者 刘静 郑丙辉 +4 位作者 刘录三 马迎群 林岿璇 汪星 夏阳 《环境科学》 EI CAS CSCD 北大核心 2016年第8期2989-3000,共12页
河口潮汐、盐度、悬浮颗粒物特征因影响化学物质在水体与其他介质之间分配行为,使得咸淡水生物利用度上产生差别,造成咸淡水水质基准标准的差异.重金属如铜,锌,铅,镉和铬等指标由于广泛分布在淡水及海水中,在较高的浓度下可具毒性效应,... 河口潮汐、盐度、悬浮颗粒物特征因影响化学物质在水体与其他介质之间分配行为,使得咸淡水生物利用度上产生差别,造成咸淡水水质基准标准的差异.重金属如铜,锌,铅,镉和铬等指标由于广泛分布在淡水及海水中,在较高的浓度下可具毒性效应,是现行《地表水环境质量标准》(GB 3838-2002)和《海水水质标准》(GB 3097-1997)常规监测项目.本研究以大辽河口为例,探索这些重金属指标在咸淡水河口区衔接情况和响应规律.首先,基于生物、化学和地质地理相似性确定潮汐界面(TCI)和河海边界(FSI)的位置,划分为潮汐淡水区及混合区.其次,分析了一个潮汐周期内重金属指标的变化特征,以及潮汐淡水区及混合区内盐度和悬浮颗粒物对分配系数Kd的影响,结果表明砷、镉和铬等指标更易受盐度的影响,而锌、铜、铅和镍等指标更易受悬浮颗粒物和潮汐状态的影响.最后,结合潮汐状态和分配系数研究结果,根据这些指标在TCI和FSI的变化趋势,归纳为两类响应规律:第一类如砷、镉和铬等指标,这类指标在FSI具有明显的突变点;第二类如锌、铜、铅和镍等指标,从TCI开始发生变化.两类指标在水相-沉积相-颗粒相介质的分配行为表明颗粒相和沉积相具有相似的变化趋势,尤其颗粒相中的重金属浓度,取决于悬浮颗粒物的浓度,指标响应差异主要存在于水相中.通过本研究识别出易受不同环境因子(如盐度和SS)控制的敏感指标,提出需关注河口本身特征造成的指标背景差异的必要性,将有助于我国现行水质标准制定、修订工作的实施和开展. 展开更多
关键词 重金属 河口 分配系数 水-悬浮颗粒物-沉积物 水质标准
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Particle inertia effect on sediment dispersion in turbulent open-channel flows 被引量:5
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作者 ZHANG Lei ZHONG DeYu WU BaoSheng 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第10期1977-1987,共11页
Particle inertia effect plays a significant role in sediment dispersion which has not been fully elucidated.In this paper,the profound effect of particle inertia on the sediment dispersion was analyzed.The theoretical... Particle inertia effect plays a significant role in sediment dispersion which has not been fully elucidated.In this paper,the profound effect of particle inertia on the sediment dispersion was analyzed.The theoretical expression for the drift velocity based on the two-phase mixture theory in turbulent open channels is firstly introduced.The influence of particle inertia on sediment dispersion was investigated through three different aspects including vertical dispersion,motion,and flux properties based on the drift velocity.Results show that the dispersion of suspended sediment in turbulent open-channel flows is affected by three major processes including turbulence of water sediment mixtures,particle random motion,and collisions among particles,of which the contributions of particle turbulence and collisions to the sediment dispersion are remarkable for particles of high inertia.With respect to the vertical mean velocity and sediment flux,it shows that the predictive results agree well with the measurements when the term of particle inertia is considered.As a result,particle inertia considerably affects the behavior of suspended sediment.In particular,the influence of inertia must be accounted for in circumstances of flows laden with high-inertia particles. 展开更多
关键词 INERTIA EFFECT suspended sediment DISPERSION
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