岩溶洞穴中钟乳石类沉积物色泽变化的成因浅析

在溶洞开发利用过程中发现 ,一些原为晶莹洁白的洞内钟乳石类沉积物逐渐变得色泽暗淡发红或产生其它颜色 ,失去了原有的亮丽色泽。笔者认为产生这种现象的主要原因是由于洞穴开放程度增高或当地气候等环境条件发生较大变化 ,增强了洞内空气与洞外大气的循环交替 ,洞内空气中氧含量增大 ,造成渗入洞中水氧化还原条件发生较大变化 ,致使铁、锰等金属化合物在钟乳石类沉积物中沉积所致。此外 ,泥质、有机质以及其它金属矿物等在钟乳石类沉积物表面的沉积或附着 。

南海西沙西南海域表层沉积物特征

西沙西南海域表层沉积物样品矿物成分、地球化学、微体古生物分析测试结果表明：沉积物可分为７种类型，沉积环境主要是陆坡，部分为深海平原，海洋生物、海洋化学以及火山物质的沉积起到了积极的作用，陆源物质的影响较小，它们主要来源于北部大陆和南部岛礁等物源区。

A non-parametric indicator Kriging method for generating coastal sediment type map

Coastal sediment type map has been widely used in marine economic and engineering activities, but the traditional mapping methods had some limitations due to their intrinsic assumption or subjectivity. In this paper, a non-parametric indicator Kriging method has been proposed for generating coastal sediment map. The method can effectively avoid mapping subjectivity, has no special requirements for the sample data to meet second-order stationary or normal distribution, and can also provide useful information on the quantitative evaluation of mapping uncertainty. The application of the method in the southern sea area of Lianyungang showed that much more convincing mapping results could be obtained compared with the traditional methods such as IDW, Kriging and Voronoi diagram under the same condition, so the proposed method was applicable with great utilization value.

Impact of Human Activities on Depositional Process of Tidal Flat in Quanzhou Bay of China

As a very important component of a coastal system, tidal flats come to be a focus of the studies on land-ocean interaction in the coastal zone because those areas are subjected to intense human activities and are highly sensitive to the global change. The Quanzhou Bay, located along the middle part of Fujian coast of China, covers about 136.4km^2, and the area of coastal wetland in the entire bay from intertidal to subtidal with 6m of water depth accounts for 96% of the total area. Seven short cores were collected and divided in situ with the interval of 5cm on the coastal wetlands of Quanzhou Bay on April 19, 2006. The sediment samples were scattered and the grain sizes were measured by using Mastersizer 2000. Human beings＇ activities on tidal fiat have disturbed the vertical distribution of sediments in stratigraphic sequence and accelerated the sedimentation rates. Grain size analysis results show that the grain size diameters increase and sediment becomes worse sorted towards the sea under the strong human disturbance; Spartina alterniflora can play a role of trapping the fine sediment; but near the bank, the sediment becomes coarse and there are two peak values on frequency curve influenced by the sandpile. The trough formed by human activities along the coastline changes the transport path of water and suspended sediment. The sediments are transported through the trough and deposit in it during the flood; the ebb flow is retarded by the flow output through the adjacent trough, and the deposited sediment can not be re-suspended; then, the sedimentation rate increases. In situ observation show that the sedimentation rate is about 8-10cm/yr.

Summertime community structure of intertidal macrobenthos in Changdao Archipelago,Shandong Province,China

The community structure of intertidal macrobenthos in Changdao Archipelago(north of Shandong Peninsula,between Bohai Bay and the northern Yellow Sea) was examined based on samples collected from 14 stations in five transects in June 2007.Three stations corresponding to high,medium and low tidal areas were set up for each transect.A total of 68 macrobenthic species were found in the research region,most of which belonged to Mollusca and Crustacea.The average abundance and biomass of the macrobenthos was 1 383 ind./m2 and 372.41 g/m2,respectively.The use of an arbitrary similarity level of 20% resulted in identification of five groups among the 14 stations in the research region.There were remarkable differences in the biomass,abundance and Shannon-Wiener diversity index of the different sediments.Specifically,the order of biomass was rocky shores > gravel > mud-sand > coarse sand > stiff mud,while the order of abundance was rocky shores > coarse sand > mud-sand > gravel > stiff mud,and that of the diversity index was mud-sand > gravel > stiff mud > rocky shores > coarse sand.The above results revealed that the sediment type was the most important factor affecting the structure of the macrobenthic community of the intertidal zone.

An Investigation of Elements （Mercury） Status in Marshes in South of Iraq

The study was conducted to investigate the mercury status in three major marshes in southeast Iraq. Sediments, plants （three species） and fish （five species） samples were collected at five locations along the major marshes （AL-Hammar, Cross of AI Fuhod AI Tar, Downstream of AL-Mashab ＆ AL-Salal, Hawizeh and AL-Chebayesh） in southeast Iraq and analysed for mercury concentrations. The sediments were collected at predetermined input and output sources. The mercury concentrations were extremely high in both the sediment and plant samples but variable in fish species. There was a strong relationship between mercury concentrations in the sediments and fishes. Some of the fish species have mercury levels that are considered safe by the international marketing standard/WHO recommendation while others contain mercury levels that may be considered unsafe for human consumption.

Effects of clam size, food type, sediment characteristic, and seawater carbonate chemistry on grazing capacity of Venus clam Cyclina sinensis (Gmelin, 1791)

Aquaculture in saline-alkaline water has a major problem： microalgal blooming causes the pH of water to increase dramatically, thereby causing damage to the reared organisms. To solve this problem, we set out to find a candidate filter-feeding bivalve species suitable for saline-alkaline water to graze on microalgae and to control the pH. In the current study, we investigated the effect of carbonate alkalinity （CA, 2.5, 10.0, and 20.0 meq/L） and pH （8.0, 8.5, and 9.0） on the grazing capacity （GC） of the clam Cyclina sinensis. Additionally, the effect of clam size （small, medium, and large） and microalgae species （Nannochloropsis oculata, Chaetoceros miielleri, and lsochrysis galbana）, and the effect of bottom sediment characteristic （mud, sandy mud, and muddy sand） and thickness （3 and 6 cm） were analyzed as well. The results show that the GC on L galbana was the highest and small size had the maximum GC/W （W： wet weight including body and shells）. No significant differences were observed between sediment type and thickness. Regarding CA and pH, a significant decrease in GC by the pH or by their interaction was found. The GC ofC. sinensis was not greatly reduced in the treatments ofpH≤8.5 and CA≤20.0, and also not affected by bottom sediment type, indicating that this clam is capable to manage microalgal concentrations and might be a candidate species for pH reduction in saline-alkaline water ponds.

Sedimentary ladderane core lipids as potential indicators of hypoxia in the East China Sea

Anammox （anaerobic ammonium oxidation） is an important process in many suboxic to anoxic marine environments for converting fixed nitrogen to N2, and has a major impact on the marine nitrogen cycle. Ladderane core lipids have been utilized as an indicator of the contribution of anammox to the marine nitrogen cycles. However, such studies have not been reported for the China seas and little is known about the importance of anammox within the nitrogen cycle of these marginal seas. In the research reported here, the ladderane core lipid contents of 17 surface sediment samples from the East China Sea are reported, and their spatial distribution is investigated. C^8-[5]-ladderane FAME, C20-[5]-ladderane FAME and C20-[3]- ladderane FAME have all been detected, suggesting that the anammox bacteria are widely present within the study area. The total contents of the three ladderane lipids （ZFAMEs） range from 24-355 ng/g （weight of dry sediments）, with higher contents occurring in the Minzhe Mud Zone and broadly coincident with the spatial distribution of hypoxia. It is suggested that the sedimentary ladderane core lipids are mainly produced in the water column and their sedimentary contents can be used as indicators of water column hypoxia.

Particle reworking by the sediment-living polychaetes Perinereis aibuhitensis

The infaunal polychaete Perinereis aibuhitensis Grube, distributes widelyalong Asian coasts and estuaries. In this research the particle reworking function of P.aibuhitensis was investigated in Beitang Estuary, Tianjin. The result showed that P.aibuhitensis displayed significant particle mixing function, in which small grain sizesediment particles were mixed more than the large size ones. Some small grain sizesediment particles could be ingested by P. aibuhitensis and egested with fecal pellets.

Distribution of diatoms and silicoflagellates in surface sediments of the Yellow Sea and offshore from the Changjiang River, China

The spatial distribution of siliceous microfossils （diatoms and silicoflagellates） in the surface sediments was mapped at 113 sites in the Yellow Sea and sea areas adjacent to the Chang^iang （Yangtze） River, China. In total, 267 diatom taxa and two silicoflagellate species were identified from the sediments. The spatial variations in abundance and diversity were classified into three distinct geographic patterns using Q mode clustering： a south-north geographic pattern, a coastal-offshore pattern and a unique pattern in the Changjiang River mouth. The south-north geographic pattern was related to the spatial variations in sea temperature. Coscinodiscus oculatus, a warm-water species, indicated these variations by a gradual decrease in abundance from the south to the north. The coastal-offshore pattern was in response to the spatiaJ variations in salinity. Cyclotella stylorum, Actinocyclus ehrenbergii and Dictyocha messanensis, the dominant brackish species in coastal waters, significantly decreased at the isobaths of approximately 30 m, where the salinity was higher than 31. Paralia sulcata and Podosira stelliger indicated the impact of the Yellow Sea Warm Current in the central Yellow Sea. The unique pattern in the Changjiang River mouth showed the highest species diversity but lower abundance, apparently because： freshwater input can significantly increase the proportion of brackish species; nutrients can supply the growth ofphytoplankton; and high sedimentation rates can dilute the mierofossil abundance in the sediments. Our results show that an integration of environmental factors （e.g., nutrient levels, sedimentation rate, sea temperature, salinity and water depth） determined the spatial characteristics of the siliceous micro fossils in the surface sediments.

Distribution and Provenance of Detrital Minerals in Southern Coast of Shandong Peninsula

Detrital minerals of 137 offshore and 22 river sediment samples collected from Qingdao coastal areas have been analyzed. Four mineral assemblage provinces can be classified by Q-mode cluster analysis. Factor analysis identifies two major factors that account for the total variability in most common minerals: 1) based on the relationship of quartz, hornblende, actinolite, micas, and authigenic pyrite, 41.55% of the variability is related to sediment sources; 2) based on the relationship of epidote, garnet, sphere, and ilmenite, 23.21% can be related to strong hydrodynamic conditions that control transport and sedimentation. By comparing mineral compositions of river waters in the study area, the following four mineral provenances can be identified. The Qingdao-Laoshan nearshore area has a quartz-feldspar-epidote-hornblende-limenite-limonite-sphene assemblage, which is largely attributed to relict sediment and coastal erosion. The Jimo-Haiyang nearshore area has a quartz-feldspar-hornblende-epidote-limonite-mica-actinolite assemblage, derived largely from the Wulong River and Rushan River, and is also affected by the Huanghe River, while the Qianliyan Island area in the deeper offshore area separated by a mud belt has a similar assemblage. The Haiyang-Rushan nearshore area has a quartz-feldspar-hornblende-epidote-micas-limonite assemblage, indicating multiple sources from the Rushan River, the Wulong River, the Huanghe River, and coastal erosion. The central area, located in an eddy center, has a mica-authigenic pyrite-hornblende-quartz-feldspar assemblage, indicating multiple sources dominated by Huanghe River distal sediments.

Source and composition of sedimentary organic matter in the head of Three Gorges Reservoir: a multiproxy approach using δ^(13)C,lignin phenols, and lipid biomarker analyses

A multiproxy approach including bulk organic carbon, δ^(13) C, lignin phenols, and lipid biomarker analyses were applied to characterize the source and composition of sedimentary organic matter in the head part of Three Gorges Reservoir. OM consisted of both natural(autochthonous and allochthonous) and anthropogenic inputs.The natural OM included input from vascular plants,especially non-woody angiosperms. The allochthonous input included plankton and microbial production, likely due to localized eutrophication. Anthropogenic inputs likely derived from petroleum input and/or urban activities.Other anthropogenic inputs were untreated sewage waste.These influences were concluded to be regionally specific point sources of pollution based on relative distributions and on the fact that molecular characteristics of sedimentary OM were not distributed smoothly along a gradient.

Petroleum Hydrocarbon Distribution Features in Water and Sediment off Fujian Shore

This study on the distribution features of petroleum hydrocarbon in water and sediment off the Fujian shore using data obtained from the baseline research on oceanic contamination in Fujian showed that: during the research period, petroleum hydrocarbon concentrations in water varied from 5.77 μg/L to 37.28 μg/L, averaged 14.48 μg/L; was lower in the wet season than in the dry season; and was highest in the Minjiang Estuary and Jiulong Estuary in both seasons. The petroleum hydrocarbon concentrations in shore sediment varied from 14.48 mg/kg to 784.36 mg/kg, averaged 133.3 mg/kg, and was closely related to sediment types (granularity).

Control of favorable lithology on Jinlongshan micro-fine disseminated gold deposits, southern Qinling Mountains

Jinlongshan gold orebelt, a newly discovered one in sedimentary rock region in southern Qinling Mountains, is mainly located in upper Devonian and lower Carboniferous calcareous siltstone and argillic silty limestone of later Paleozoic era. Typical disseminated gold mineralization occurred in calcareous siltstone, which is major host rock and mainly composed of silt (SiO2 mostly varies from 38% to 73%) and calcite (CaO mostly varies from 10% to 25%). Pyrite created by living beings in Nanyangshan formation may be poor in gold. Faults and favorable layers jointly control disseminated gold mineralization. The significance of this opinion is very great for gold exploration.

A new sediment type of coated grain: Oolitic sinter

As a special sedimentary grain type, the coated grain(with an ooid model) has been known for two centuries due to its fascinating special fabric and genesis developments. The leading factors in forming the coated grain consist mainly of:(1) microorganism movement field;(2) chemical sedimentary effect;(3) hydrodynamic force environment and topography condition;(4) abundant core material supply;(5) embedding condition; and(6) humic acids condition in water medium. With the development of the coated grain genesis, the single factor theory cannot reasonably explain the exact formation of the surface sediment of coated grain. Here, we find a new way to study the coated grain on the basis of traditional research methods. The Wenquan area on the northeast edge of the Qiangtang Basin is one of the few areas where the coated grain is developing, and is a rare "natural laboratory" for the study of the coated grain and the thermal spring sediment. The oolitic sinter of the area has the triaxiality modality of pea polymer, and is obviously different from the karst travertine and the normal lacustrine ooid. We found that the hot spring water in the Wenquan area has higher partial pressure of CO2(PCO2) and saturation index of the calcite(SIc) than normal. Macrocosmically, the oolitic sinter is shaped like a pea, and its grains and gap fillings are light yellow. Microcosmically, the sinter grain forms six types of fundamental lamina, and those six types are developed to be four grain types with different combinations. The C-axis of the mineral grain of sinter cement(calcite) is normal to the lamina face, and grows on it with distinct generation formations. In short, the grain type of oolitic sinter is the oncoid, with the grain development caused by the factors such as the shallow water of strong hydrodynamic force, the special hydrochemistry condition, and the extensive algae activities(diatom).

Modern pollen assemblages from surface lake sediments in northwestern China and their importance as indicators of vegetation and climate

The modern pollen assemblages of surface lake sediments and topsoils in northwestern China were studied to understand the relationship of modem pollen data with contemporary vegetation and climate, and the differences between the pollen assem- blages of surface lake sediments and topsoils. The results show that Chenopodiaceae and Artemisia are dominant elements in the pollen assemblages of northwestern China. Additionally, Ephedra, Cyperaceae, Asteraceae, Poaceae, Picea, Pinus, and Betula are also important pollen taxa. Both pollen assemblages and principal component analysis indicate that pollen data from surface lake sediments and topsoils can be used to differentiate the main vegetation types of this region （desert, steppe, mead- ow and forest）. However, differences exist between modern pollen assemblages of the two types of sediments due to the dif- ferent relevant source areas of pollen and degrees of pollen preservation. For example, the larger relevant source area of sur- face lake sediment results in a higher abundance of Betula in pollen assemblage from surface lake sediment, whereas the ten- dency to disintegrate thin-walled pollen types in topsoil leads to a higher proportion of resistant pollen, such as Asteraceae. Linear regression analysis indicates that the Artemisia/Chenopodiaceae （A/C） ratio in pollen assemblages of surface lake sedi- ments can be used to indicate humidity changes in the study area. However, the A/C ratio in topsoils should be used carefully. Our results suggest that pollen data from surface lake sediments would be better references for interpreting the fossil pollen assemblages of lake cores or lacustrine profiles.

Evolution of the East China Sea sedimentary environment in the past 14 kyr: Insights from tetraethers-based proxies

We reconstruct the environmental evolution of the East China Sea in the past 14 kyr based on glycerol dialkyl glycerol tetraethers(GDGTs) in a sediment core from the subaqueous Yangtze River Delta. Two primary phases are recognized. Phase I(13.8–8 cal kyr BP) reflects a predominantly continental influence, showing distinctly higher concentrations of branched GDGTs(averaged 143 ng/g dry sediment weight, dsw) than isoprenoid GDGTs(averaged 36 ng/g dsw), high BIT index(branched vs. isoprenoid tetraethers) values(>0.78) and a fluctuating GDGT-0/crenarchaeol ratio(R_(0/5), varied from 0.52 to 3.81). Within this interval, temporal increases of terrestrial and marine influence are attributed to Younger Dryas(YD)(ca. 12.9–12.2 cal kyr BP) cold event and melt-water pulse(MWP)-1B(11.5–11.1 cal kyr BP), respectively. The prominent transition from 8 to 7.9 cal kyr BP shows a sharp decrease in BIT index value(<0.4) and increase in crenarchaeol, which marks the beginning of phase II. Afterwards, the proxies remain relatively constant, which indicates that phase II(7.9 cal kyr BP-present) is a shelf sedimentary environment with high stand of sea level. Overall, the BIT index in our record serves as a good marker for terrestrial influence at the site, and likely reflects the flooding history of the region. The TEX_(86)(Tetra Ether Index of tetraethers consisting of 86 carbons) proxy is not applicable in phase I because of an excess terrestrial influence; but it seems to be valid for revealing the annual SST in phase II(21.6±0.9°C, n=49). In contrast, the MBT'/CBT(Methylation of Branched Tetraethers and Cyclization of Branched Tetraethers) proxy appears to faithfully record the annual mean air temperature(MAT)(14.3±0.63°C, n=68) and presents an integrated signal over the middle and lower Yangtze River drainage basin.

Experimental simulation of gas hydrate decomposition in porous sediment

Gas hydrate decomposition in sediments involves complicated multiphase flow and heat and mass transfer processes because of heat absorption by solid hydrates. Factors affecting gas hydrate decomposition in sediments include sediment type, mineral composition, pore size distribution, particle size, pore water composition, hydrate saturation distribution, initial formation pressure and temperature and cement characteristics. In this paper, experimental simulations of gas hydrate decomposition are carried out on an artificial core to investigate the effects of initial pressure and temperature, particle size and pore size. The experiments show that the characteristics of gas hydrate decomposition in sediments differ completely from those in a pure water system. The decomposition rate of hydrate sediments increases with the initial pressure increasing and decreasing temperatures. Furthermore, the decomposition rate of hydrate sediments decreases with decreasing particle size and increasing pore size.