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固态进样方式石墨炉原子吸收光谱法测定沙痕量金 被引量:2
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作者 李勇 《理化检验(化学分册)》 CAS CSCD 北大核心 2007年第9期716-718,共3页
报道了地质样品中痕量金用表面涂有磷酸三丁酯的聚氨酯泡沫塑料(PUPF)吸附富集后用石墨炉原子吸收光谱法(GF-AAS)测定,测定中采用外形改变的热解石墨管,表面吸附有金离子的PUPF毋需经过解吸操作,直接引入石墨管中进行测定。将吸附有金的... 报道了地质样品中痕量金用表面涂有磷酸三丁酯的聚氨酯泡沫塑料(PUPF)吸附富集后用石墨炉原子吸收光谱法(GF-AAS)测定,测定中采用外形改变的热解石墨管,表面吸附有金离子的PUPF毋需经过解吸操作,直接引入石墨管中进行测定。将吸附有金的PUPF固体物直接进样的方式的特点反映在两方面:①避免了因解吸操作而引起的金的损失;②降低方法的检出限至沙痕量级。在3个浓度水平上作了精密度试验,测得方法的RSD(n=11)值≤3.6%。用标准加入法作回收率试验,所得结果在102%~107%之间。该方法的检出限为10 pg·g^(-1),应用此法分析了一件标准物质样品(GBW 07242),测出的金含量与证书值相符,进一步证明了方法的准确性。 展开更多
关键词 固体直接进样 石墨炉原子吸收光谱法 沙痕量金 地质样品
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Monitoring Trace Metals in Some Cultured Freshwater Fish Species in Saudi Arabia
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作者 Aljabryn Dalal Hamad 《Journal of Food Science and Engineering》 2013年第9期481-488,共8页
Three species of freshwater fishes, Oreochromis niloticus, Clarias lazera and Cyprinus carpio, were collected in marketing size from some fish farms in Al-Kharj region, Riyadh area, Saudi Arabia and examined throughou... Three species of freshwater fishes, Oreochromis niloticus, Clarias lazera and Cyprinus carpio, were collected in marketing size from some fish farms in Al-Kharj region, Riyadh area, Saudi Arabia and examined throughout the year 2012 for the following trace metals contents: chromium (Cr), lead (Pb), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), iron (Fe) and cadmium (Cd). The results showed no detection of Cd in all examined species, however, the mean values of other tested metals were within the standard permissible levels except for Pb which showed higher mean levels ranged from 2.05 ± 0.65 mg/kg to 5.30 ± 0.60 mg/kg in O. niloticus, 0.15 ± 0.13 mg/kg to 6.40 ± 0.10 mg/kg in C. lazera and 1.7 ± 0.20 mg/kg in C. carpio compared to the maximum permissible limits recorded by Saudi Arabia Standards Organization (SASO) for fish and shellfish. Consequently, from the public health point of view, efficient routine examination of cultured fishes to control trace metals during culture processes and before marketing is recommended. 展开更多
关键词 Heavy metals fresh water Saudi Arabia fish farming.
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