Nanocrystalline ZSM-5(with a crystal size in the range of 20—30 nm) has been synthesized in only 20 h via the crystallization of ultra-concentrated homogeneous synthesis mixtures. The influence of low water content, ...Nanocrystalline ZSM-5(with a crystal size in the range of 20—30 nm) has been synthesized in only 20 h via the crystallization of ultra-concentrated homogeneous synthesis mixtures. The influence of low water content, use of compound surfactant, a proper crystallization time and SiO_2/Al_2O_3 molar ratio on the properties of the final nanocrystalline ZSM-5 has been studied. Especially, the use of compound surfactant has influenced some properties of nano-ZSM such as the morphology, crystal size and crystallization greatly. The nano-ZSM-5 zeolite was investigated using XRD, BET, SEM, NH_3-TPD, and other techniques. The evaluation results in a 200-mL hydrogenation unit indicated that the synthesized nano-ZSM-5 had excellent catalytic performance in diesel hydrodewaxing.展开更多
基金the National Natural Science Foundation(20473039) for the support of this work
文摘Nanocrystalline ZSM-5(with a crystal size in the range of 20—30 nm) has been synthesized in only 20 h via the crystallization of ultra-concentrated homogeneous synthesis mixtures. The influence of low water content, use of compound surfactant, a proper crystallization time and SiO_2/Al_2O_3 molar ratio on the properties of the final nanocrystalline ZSM-5 has been studied. Especially, the use of compound surfactant has influenced some properties of nano-ZSM such as the morphology, crystal size and crystallization greatly. The nano-ZSM-5 zeolite was investigated using XRD, BET, SEM, NH_3-TPD, and other techniques. The evaluation results in a 200-mL hydrogenation unit indicated that the synthesized nano-ZSM-5 had excellent catalytic performance in diesel hydrodewaxing.
