2011年中国炼油行业运行回顾及未来两年展望

2011年,中国炼油企业生产运营取得了较好的成绩,原油加工量和主要产品产量实现稳步增加。全年原油加工量达到4.48亿吨,同比增加约4.9%;汽、煤、柴油产量达到2.67亿吨,同比增长5.6%。为适应市场需要,炼厂调整产品结构,航煤等产品增幅较大,车用柴油质量开始全面向国Ⅲ标准升级;主要炼油技术指标明显提升;由于成品油与原油价格倒挂,炼油企业亏损加剧;资本性投资结构进一步优化,重点投资于油品质量升级、炼厂挖潜技术改造、环保和储运设施等项目。展望2012年,预计全国原油总加工量将达到4.65亿吨,增幅为4%左右;2013年中国炼油工业将继续保持发展势头,全国原油加工量将达到4.85亿吨。

2012年中国炼油行业运行回顾及未来两年展望

面对经济增长放缓、市场需求低迷的形势,中国炼油企业强化内部管理,提高营运水平,加大结构调整力度,生产运营取得了较好的成绩。全年原油加工量达到4.68亿吨,同比增加约4.5%;汽、煤、柴油产量达到2.82亿吨,同比增长5.5%。为适应市场需要,炼厂调整产品结构,增加汽油、航煤等产品的产出;主要炼油技术经济指标明显提升;资本性投资结构进一步优化,重点投资于油品质量升级、技术改造、环保设施完善等项目。预计2013年全国原油总加工量将达到4.85亿吨,增幅为3.5%左右;2014年中国炼油工业将继续保持目前的发展势头,全国原油加工量将超过5亿吨。

Analysis of Yield and Disease Resistance Traits of New Winter Rapeseed Varieties over the Past Twenty Years in China

Based on the results of the national regional trail for winter rapeseed in four groups,including the upper reaches,middle reaches and lower reaches of Yangtze River and Huang-Huai region in the past twenty years,new varieties of winter rapeseed showed upward trend in average yield,the yield level in Huang-huai group was higher than other groups.The changes of average effective pods per plant were not significant in any group,but the number of grain per pod and 1 000-grain weight showed increase trend.However,the increment of grains per pod in three Yangtze River groups was higher than that in Huang-Huai River group,while the increment of 1 000-grain weight was just opposite.The incidence rate of Sclerotinia sclerotiorum and viral disease in new varieties of winter rapeseed obviously decreased,and the incidence rate of S.sclerotiorum decreased lower than 5%.Genetic improvement for winter rapeseed should be focus on the number of grain per pod and 1 000-grain weight in the future,and yield level of new varieties in all four groups is expected to increase.

Analysis of Correlation between Yield and Quality Traits of Quality Hybrid Rapeseed

[Objective] This study aimed to investigate the correlation between yield and quality traits of rape. [Method] Taking ＂Sanbei 98＂ and ＂Youyan 599＂ as ex- periment materials, correlation between yield and quality traits of Brassica napus L. cultivars was explored by orthogonal rotation method. [Result] The results showed that： 1 In both the two varieties-Sanbei98 and Youyan599, erucic acid content had the largest coefficient of variation, but its average content was lower than 2% in both the two varieties （0.90% in Sanbei98 and 1.24% in Youyan599）, and the palmitic acid content had the smallest coefficient of variation. 2 In terms of the dif- ferences in quality traits at different yield levels, only the mean of eicosenoic acid content revealed significant difference in Sanbei98, and only the mean of seed-pro- tein content revealed significant difference in Youyan599, and there was no signifi- cant difference in any combined quality traits in both the two varieties. 3 The yield was negatively correlated with the erucic acid content or oil content, and posi- tively correlated with the content of seed-protein, linoleic acid, or linolenic acid, and the coefficient of correlation between the yield and either of the contents of glucosi- nolates, oleic acid, palmitic acid, stearic acid, and eicosenoic acid was smaller. ~, when the yield of a variety increased considerably, there was a certain decreasing trend in erucic acid content, oil content, the total amount of erucic chain fatty acids （El ＆ Er）, while there was an increasing trend in seed-protein content, linoleic acid content, linolenic acid content, saturated fatty acids （SFA）, the total amount of fat and protein （P ＆ F）, unsaturation index （IUFA）, unsaturated fatty acids （UFA）, the total amount of 18 carbon fatty acids （18-C FA）, unsaturated fatty acids [UFA/（Ei ＆ Er） ], and the sum of oleic acid and linoleic acid （OI ＆ Li）. 5 When the seed-pro- tein content is increased, the quality of rape oil cake is also improved; when the unsaturated index is increased, the oil stability is decreased. The increase in the total amount of unsaturated fatty acids, oleic acid and linoleic acid helps to increase in the total amount of fatty acids absorbed by human bodies. [Conclusion] This study provides a theoretical foundation for the cultivation of high-yielding and top- quality hybrid rape cultivars.

Comparions of Required Nitrogen Fertilizers by Hybrid Cultivar and Conventional Cultivar of Rapeseed(Brassica napus L.)

[Objective] The aim of this study was to understand the difference of N fertilizer requirement between hybrid rapeseed and conventional rapeseed. [Method] Two hybrid cultivars, ZY5628 and ZY7819, and the conventional cultivar ZS10, were compared through two field experiments. In Experiment 1, seed yield and optimum N application rate were assessed in the field with five N application treatments. In Expedment 2, N was applied uniformly at 180 kg/hm2, and plant biomass and N accumulation were measured at several developmental stages, while N use efficien- cy was calculated for rape at maturity. [Results] The experiment 1 results showed that seed yields of ZY5628 and ZY7819 were both significantly higher than that of ZS10, and compared to ZS10, optimum yield （plateau yield） was higher by 18.7% and 20.2%, while the recommended N application rate was lower by 9.5% and 9.6% for ZY5628 and ZY7819, respectively. The experiment 2 results showed that during vegetative development, all three cultivars exhibited similar accumulations of plant biomass and N, but through flowering and maturity ZY5628 and ZY7819 pro- duced more biomass, acquired more N, and utilized acquired N more efficiently to- wards seed production than ZS10. [Conclusion] With equivalent inputs, the hybrid rapeseed cultivars ZY5628 and ZY7819 tested herein yield more seed with higher N use efficiency than the conventional rapeseed ZS10. This information will be valu- able for growers seeking to improve efficiency while reducing costs of rape production in China.

Production of De-asphalted Oil and Fine Asphalt Particles by Supercritical Extraction

A continuous three-stage supercritical fluid extraction (SFE) process with a capacity of 1.0kg.h^-1 was setup to extract petroleum residue by pentane to obtain more oil for further upgrading. A discharging system integrated to the bottom of the extractor was used to recover solvent as gas while asphalt was obtained as fine particles. The influence of operating conditions on the yield and quality of extracts, i.e., deasphalted oil (DAO) and resin, was studied in the range of temperature 150-220℃, pressure of 4.0-6.0 MPa and the mass ratio of solvent to oil feed (S/O) 2.5-5.0. The particle size distribution, apparent forms and the packing density, which vary with operating pressure, were measured. The particle structures were observed by SEM as well. With the modification to conventional processes, furnace can be eliminated for solvent recovery from asphalt phase, so as to reduce energy consumption.

Production of Quality Hydrogenated Base Oils through Isodewaxing Technology

This article presents the successful experience in adopting the Isodewaxing technology in the lube oil unit of Shanghai Gaoqiao refinery. In line with the demand of different crude slate for different reaction depth, and good match between the optimal product quality and the yield, the refinery has make strenuous efforts to optimize the operation and reduce the energy consumption to manufacture high-quality hydrogenated base stocks.

Specifications and Quality of Lube Oil Base Stocks in China

The Chinese standard Q/SHR001-95 for base stocks is compared with the APIspecifications. The viscosity-temperature characteristics of base stock required by lube oil in useand market demand on oil quality are analyzed. The quality indicators of base stocks in China andother countries are compared. A new classification of base stocks in response to the requirements ofmodern lube oil is proposed and the research on new technology to produce premium base stocksmeeting API specification is recommended on the basis of current base stock processing technology.

Extra-Large Seed Germplasms of Brassica Napus Created through Microspore Culture

Thousand Seed Weight （TSW） is one of the major yield components of rapeseed （Brassica napus L.）. Here reports an extra-large seed germplasm GM01 which was obtained through isolated microspore culture. Three-way cross was made： H8--a Yunnan spring early-maturing rapeseed variety, ＂Legeney＂--a Canadian canola variety and ＂020010＂--a semi-winter late-maturing rapeseed variety. One hundred and forty eight doubled hyploid lines were obtained from the F~ plants of three-way cross through isolated mierospore culture. Among them, the TSW of GM01 amounted to 8.68 g and the TSW of 53 lines were above 5.0 g. The TSWs of GM01 were relatively stable among the multi-location field trials from 2007 to 2014 with variation being only 10%-15% among the locations and years. Compared with H8, GM01 had larger flowers, stigmas, siliques and seed diameters, but less branches, siliques per plant and seeds per silique.

Screening and Application of Oilseed Rape Varieties with High Yield and High Harvest Index

28 oilseed rape Pol CMS three-line hybrid combinations diallel-crossed were compared in the yield and harvest index and analyzed on the correlation between the experimental yields and harvest indexes in this study. The correlation coeffcient was only 0.365 4, lower than a signifcant level, which indicated that there was no signifcant positive （or negative） correlation between the economic yields and the harvest indexes in oilseed rape. Among them, 8 hybrid combinations including 7 with a harvest index〉0.30 and one with a harvest index〈0.27 increased signifcantly in the yields compared with the control, and then were screened for production experiment. Under different cultivation methods, all the 8 combinations had a stable harvest index, and the combinations with higher harvest indexes also had a stable performance in yields. An oilseed rape variety Fengyou 737 with higher yield and harvest index selected through a further screening was grown with the harvest indexhigher than 0.33 whether transplanted or directly seeded in Yangtze River Basin Demonstration Area, demonstrating stable high yields as well as good ecological adaptability. The combination of yield and harvest index in the study is conducive to breeding a new oilseed rape variety with stable yields and good tolerance to close planting.

Breeding and Application of Mianyou Series of High-erucic Acid Rapeseed Varieties

The main characteristics of Mianyou series of high-erucic acid rapeseed varieties （Mianyou 13, Mianyou 15, Mianyou 309, Mianyou 322 and Mianyou 328） were analyzed. The popularization and application measures of high-erucic acid rapeseed varieties were summarized. Finally, the future breeding emphasis, to improve the yield of erucic acid per unit area is put forward.

Strategy on Development of Gasoline and Diesel Standards in China with Reference to Overseas Practice for Upgrading Gasoline and Diesel Quality

This article analyzes the standards for car exhaust emissions and gasoline and diesel quality in Europe and the US. As revealed by the evolution of gasoline and diesel standards in China, the gasoline and diesel compositions of China and the exhaust gas emissions standard are closely related with the specifics of the petroleum refining industry and automotive industry in China. After studying the current situations of gasoline and diesel quality in China while taking into account the commonly accepted practice in the overseas this article raises some suggestions on development of gasoline and diesel standards in compliance with the actual conditions of China.

Effects of Different Concentrations of Photosynthetic Bacteria Solutions on Yield and Quality of Lactuca sativa L.

The effects of different concentrations of photosynthetic bacteria solutions （CK, 0 ml photosynthetic bacteria agent＋4 000 ml nutrient solution; T1, 200 ml pho- tosynthetic bacteria agent＋3 800 ml nutrient solution; T2, 400 ml photosynthetic bacteria agent＋3 600 ml nutrient solution; T3, 600 ml photosynthetic bacteria agent＋ 3 400 ml nutrient solution; T4, 800 ml photosynthetic bacteria agent＋3 200 ml nutrient solution; and T5, 1 000 ml photosynthetic bacteria agent＋3 000 ml nutrient solu- tion） on the leaf number, fresh mass, root vigor, vitamin C content, soluble sugar content, soluble protein content and nitrate content of hydroponic Lactuca sativa L. were investigated. The results showed that the leaf number was increased by 62.66%, the fresh mass was increased by 139.7%, the root vigor was increased by 132.04%, the vitamin C content was increased by 18.34%, the soluble protein content was increased by 16.60%, the soluble sugar content was increased by 192.37%, and the nitrate content was reduced by 69.44% in the T3 group com- pared with those in the control group. The photosynthetic bacteria solution in the T3 group reduced the content of nitrate and improved the yield and quality of hydroponic L. sativa.

Review and Outlook of China's Oil Market in 2015

Growth rate of oil demand rose again in China in the first half of 2015. Demand for oil products went on differentiating, and the demand growth of most products sped up. Growth rate of oil production rose again, oil imports increased rapidly, and external dependence of crude oil and oil broke through 60% separately. The State adjusted the prices of gasoline and diesel timely and frequently, based on pricing mechanism. Price hike was higher than reduction. Oil market got weak, yet more stable. China increased the pace of reforms in marketization. In the second half, oil demand will increase continuously but with lower growth rate, oil production will rise more slowly, imports of crude oil and oil will keep on rising rapidly, gasoline and kerosene as well as diesel will witness a net import, and the market of gasoline, kerosene and diesel will be more stable.

Enhanced exergy cost optimization of operating conditions in FCCU main fractionator

Exergy indicates the maximal energy that can do work effectively. Different from optimization of product quality or calculation of generic energy conservation in most previous studies, the application of exergy analysis and exergy cost optimization in petrochemical industry is of great economic and environmental significance. Based on the main fractionator in Jiujiang Petrochemical Complex No. 2 FCCU, an enhanced exergy cost optimization under different operating conditions by adjusting set points of temperature and valves opening degree for flow control is studied in this paper in order to reduce exergy cost and improve the quality of energy. A steadystate optimization algorithm to enhance exergy availability and an objective function comprehensively considering exergy loss are proposed. On the basis of ensuring the quality of petroleum products, the economic benefits can be improved by optimizing the controllable variables due to the fact that exergy cost is decreased.

Thermal Properties of the Product of Palm Stearin and Linseed Oil Transesterification

Triacylglycerols are the main constituents of natural fats and oils and contribute directly to their texture and flavor. The DSC （differential scanning calorimetry） of fats and oils is usually performed in order to characterize their melting and crystallization characteristics. The effect of the chemically catalyzed interesterification of two vegetable oils, i.e. palm stearin and linseed oil, on the thermal behavior of the product is studied. The objective of this study is to analyze the impact of the transesterification reaction conditions and of the initial amounts of oils on the thermal behavior of the product. This work shows that both cooling and heating DSC thermograms undergo significant changes as the result of the mixture of linseed oil and palm stearin and of their transesterification.

An Awesim Simulation Study： To Determine the Efficiency of Future Improvements on Tupras Izmit Oil Terminal

Oil and oil products occupy an important place in the industry and transportation sectors, both as bunker and raw materials. Most oil and oil products are transported by sea. The aim of this study was to evaluate the handling capacity of the Tupraslzmit Tanker Terminal, which is an important hub for Turkey with regards to the transportation ofoil and refined oil products. To assess the capacity of the port and to determine the amount of queuing that could form with regards to tug services; the Awesim simulation program was used. Based on the study results, a comparison was performed between the port＇s current annual handling capacity and the maximum amount of cargo it can handle. In addition, by using the study data, the maximum amount of queuing that can form in tug services was also calculated for days with unfavorable weather and sea conditions. This study thus represents a case study performed with the Awesim modeling program in order to determine port efficiency.

北油南调一个跨世纪课题

有人说,西煤东运,北油南调,构成中国经济增长的经纬。随着两大集团划定市场,北油如何南调更成为人们关注的焦点。