Cu–Mn bimetal catalysts were prepared to remove nitrogen oxides(NOx)from diesel engine exhaust at low temperatures.At a Cu/Mn ratio of 3:2,the NOx conversions at 200°C reached 65%and 90%on Cu–Mn/ZSM‐5 and Cu–...Cu–Mn bimetal catalysts were prepared to remove nitrogen oxides(NOx)from diesel engine exhaust at low temperatures.At a Cu/Mn ratio of 3:2,the NOx conversions at 200°C reached 65%and 90%on Cu–Mn/ZSM‐5 and Cu–Mn/SAPO‐34,respectively.After a hydrothermal treatment and reaction in the presence of C3H6,the activity of Cu–Mn/SAPO‐34 was more stable than that of Cu–Mn/ZSM‐5.No obvious variations in the crystal structure or dealumination were observed,whereas the physical structure was best maintained in Cu–Mn/SAPO‐34.The atomic concentration of Cu on the surface of Cu–Mn/SAPO‐34 was quite stable,and the consumption of octahedrally coordinated Cu2+could be recovered.Conversely,the proportion of octahedrally coordinated Cu2+on the surface of Cu–Mn/ZSM‐5 significantly decreased.Therefore,besides the structure,the redox cycle between Cu+and octahedrally coordinated Cu2+played an important role in the stability of the catalysts.展开更多
A modified mathematical model is used to study the effects of various forces on the stability of cavitation bubbles within a diesel droplet. The principal finding of the work is that viscous forces of fluids stabilize...A modified mathematical model is used to study the effects of various forces on the stability of cavitation bubbles within a diesel droplet. The principal finding of the work is that viscous forces of fluids stabilize the cavitation bubble, while inertial force destabilizes the cavitation bubble. The droplet viscosity plays a dominant role on the stability of cavitation bubbles compared with that of air and bubble. Bubble–droplet radius ratio is a key factor to control the bubble stability, especially in the high radius ratio range. Internal hydrodynamic and surface tension forces are found to stabilize the cavitation bubble, while bubble stability has little relationship with the external hydrodynamic force. Inertia makes bubble breakup easily, however, the breakup time is only slightly changed when bubble growth speed reaches a certain value(50 m·s-1). In contrast, viscous force makes bubble hard to break. With the increasing initial bubble–droplet radius ratio, the bubble growth rate increases, the bubble breakup radius decreases, and the bubble breakup time becomes shorter.展开更多
The lean blowout experiments of the combustion stability device A (multi-vortexes-dome model combustor) have been carried out at atmospheric pressure. Compared with the device B (single-vortex-dome model combustor), t...The lean blowout experiments of the combustion stability device A (multi-vortexes-dome model combustor) have been carried out at atmospheric pressure. Compared with the device B (single-vortex-dome model combustor), the experimental results show that the device A has a superior lean blowout performance when the combustor reference velocity is within the range from 3.50m/s to 5.59m/s ( while the liner reference velocity is between 3.84 and 6.13m/s), and this superiority will remain stable after the inlet air flow rate reaches a certain value. In order to analyze the phenomena and experimental results, the numerical simulation method is used, and the strain rate and the cold reflux impact are employed to further explain the reason that causes the difference between the two devices' lean blowout characteristics.展开更多
基金supported by the National Natural Science Foundation of China(51008277)the Natural Science Foundation of Zhejiang Province(LY14E080001)the Key Project of Zhejiang Provincial Science and Technology Program(2012C03003-4)~~
文摘Cu–Mn bimetal catalysts were prepared to remove nitrogen oxides(NOx)from diesel engine exhaust at low temperatures.At a Cu/Mn ratio of 3:2,the NOx conversions at 200°C reached 65%and 90%on Cu–Mn/ZSM‐5 and Cu–Mn/SAPO‐34,respectively.After a hydrothermal treatment and reaction in the presence of C3H6,the activity of Cu–Mn/SAPO‐34 was more stable than that of Cu–Mn/ZSM‐5.No obvious variations in the crystal structure or dealumination were observed,whereas the physical structure was best maintained in Cu–Mn/SAPO‐34.The atomic concentration of Cu on the surface of Cu–Mn/SAPO‐34 was quite stable,and the consumption of octahedrally coordinated Cu2+could be recovered.Conversely,the proportion of octahedrally coordinated Cu2+on the surface of Cu–Mn/ZSM‐5 significantly decreased.Therefore,besides the structure,the redox cycle between Cu+and octahedrally coordinated Cu2+played an important role in the stability of the catalysts.
基金Supported by the National Natural Science Foundation of China(51276011)the National High Technology Research and Development Program of China(2013AA065303)+1 种基金Beijing Municipal Natural Science Foundation of China(3132016)the Opening Foundation of State Key Laboratory of Engines(K2013-3)
文摘A modified mathematical model is used to study the effects of various forces on the stability of cavitation bubbles within a diesel droplet. The principal finding of the work is that viscous forces of fluids stabilize the cavitation bubble, while inertial force destabilizes the cavitation bubble. The droplet viscosity plays a dominant role on the stability of cavitation bubbles compared with that of air and bubble. Bubble–droplet radius ratio is a key factor to control the bubble stability, especially in the high radius ratio range. Internal hydrodynamic and surface tension forces are found to stabilize the cavitation bubble, while bubble stability has little relationship with the external hydrodynamic force. Inertia makes bubble breakup easily, however, the breakup time is only slightly changed when bubble growth speed reaches a certain value(50 m·s-1). In contrast, viscous force makes bubble hard to break. With the increasing initial bubble–droplet radius ratio, the bubble growth rate increases, the bubble breakup radius decreases, and the bubble breakup time becomes shorter.
基金supported by the National Natural Science Foundation of China (No. 50876104)the Major State Basic Research Development Scheme of China (No. 2012CB720406)
文摘The lean blowout experiments of the combustion stability device A (multi-vortexes-dome model combustor) have been carried out at atmospheric pressure. Compared with the device B (single-vortex-dome model combustor), the experimental results show that the device A has a superior lean blowout performance when the combustor reference velocity is within the range from 3.50m/s to 5.59m/s ( while the liner reference velocity is between 3.84 and 6.13m/s), and this superiority will remain stable after the inlet air flow rate reaches a certain value. In order to analyze the phenomena and experimental results, the numerical simulation method is used, and the strain rate and the cold reflux impact are employed to further explain the reason that causes the difference between the two devices' lean blowout characteristics.
