A new silica sol binder was obtained by mixing the acid-modified aluminium sulfate and water glass. The effect of SiO2 concentration in sodium silicate, pH value and polymerization was investigated. The new silica sol...A new silica sol binder was obtained by mixing the acid-modified aluminium sulfate and water glass. The effect of SiO2 concentration in sodium silicate, pH value and polymerization was investigated. The new silica sol binder, which possessed abundant pore volume and suitable acid amount, was an ideal component for preparing cracking catalyst. As a result, the corresponding catalyst comprising the new binder showed excellent performance. Compared with the reference sample, the liquefied petroleum gas(LPG) and propylene yield obtained over this catalyst increased by 3.49 and 1.20 percentage points, respectively. The perfect pore structure and suitable Lewis acid amount of new silica sol were the possible reason leading to its outstanding performance.展开更多
Nine targets which stand both for the static characteristic of produced formations and the dynamic parameter of wells including the average permeability,variation coefficient of permeability,moving capability,remainin...Nine targets which stand both for the static characteristic of produced formations and the dynamic parameter of wells including the average permeability,variation coefficient of permeability,moving capability,remaining recoverable reserves,coefficient of flooding,daily oil production,increasing rate of water cut,cumulative liquid production per unit meter and efficiency index of oil production are selected as the evaluation indexes,a novel model to evaluate the porous formations in long-term waterflooding sand reservoir was established by using the support vector machine and clustering analysis. Data of 57 wells from Shentuo 21 block Shengli oilfield was analyzed by using the model. Four kinds of formation groups were gained. According to the analysis result,different adjustment solutions were put forward to develop the relevant formations. The Monthly oil production increased 7.6 % and the water cut decreased 8.9 % after the adjusted solutions. Good results indicate that the learning from this method gained will be valuable adding to other long-term waterflooding sand reservoirs in Shengli oilfield and other similar reservoirs worldwide.展开更多
The pore structure of the tight limestone in the Daanzhai Member of the Ziliujing Formation, Jurassic System, in central Sichuan Basin, China, is complex but essential to the exploration and development of tight oil. ...The pore structure of the tight limestone in the Daanzhai Member of the Ziliujing Formation, Jurassic System, in central Sichuan Basin, China, is complex but essential to the exploration and development of tight oil. The pore structure of the tight limestone is studied by using scanning electron microscopy （SEM）, nitrogen adsorption, high-pressure mercury intrusion, and nuclear magnetic resonance （NMR）. The experimental results suggest that the pores are mainly slit pores and mesopores and macropores contribute to the pore volume and specific surface. The displacement pressure, average pore size, and homogeneity coefficient correlate with porosity and permeability and can be used to evaluate the pore structure. The full pore-size distribution was obtained by combining nitrogen adsorption and high-pressure mercury intrusion. We find that the limestone mainly contains mesopores with diameter of 2-50 nm. The T2 distribution was converted into pore-size distribution, well matching the full pore-size distribution. The relation between T2 and pore size obeys a power law and the geometric mean of T2 correlates with the pore structure and can be used in the pore structure evaluation.展开更多
The accurate prediction of fracturing pressure for pay zone is the very important guidance to hydraulic fracturing design and operation. The pore pressure around the wellbore happens to change variously as the fractur...The accurate prediction of fracturing pressure for pay zone is the very important guidance to hydraulic fracturing design and operation. The pore pressure around the wellbore happens to change variously as the fracturing fluid entering the pay zone. The change of pore pressure affects the stress-state and the fracturing pressure around the wellbore. In this paper, a new concept of the effective membrane pressure coefficient is presented according to the wall building capacity of the fracturing fluid, then the change of pore pressure around the wellbore is studied, and it is proven that the prediction model for fracturing pressure is improved.展开更多
基金the Department of Science and Technology Management of PetroChina for providing financial support
文摘A new silica sol binder was obtained by mixing the acid-modified aluminium sulfate and water glass. The effect of SiO2 concentration in sodium silicate, pH value and polymerization was investigated. The new silica sol binder, which possessed abundant pore volume and suitable acid amount, was an ideal component for preparing cracking catalyst. As a result, the corresponding catalyst comprising the new binder showed excellent performance. Compared with the reference sample, the liquefied petroleum gas(LPG) and propylene yield obtained over this catalyst increased by 3.49 and 1.20 percentage points, respectively. The perfect pore structure and suitable Lewis acid amount of new silica sol were the possible reason leading to its outstanding performance.
基金supported by funds from the Key Pro-ject of Chinese National Programs for Fundamental Research and Development (863 Program) under thenumber 2007AA090701the Young and Mid-dle-aged Researchers Innovation and Technology Foun-dation of CNPC under the number 04E7029
文摘Nine targets which stand both for the static characteristic of produced formations and the dynamic parameter of wells including the average permeability,variation coefficient of permeability,moving capability,remaining recoverable reserves,coefficient of flooding,daily oil production,increasing rate of water cut,cumulative liquid production per unit meter and efficiency index of oil production are selected as the evaluation indexes,a novel model to evaluate the porous formations in long-term waterflooding sand reservoir was established by using the support vector machine and clustering analysis. Data of 57 wells from Shentuo 21 block Shengli oilfield was analyzed by using the model. Four kinds of formation groups were gained. According to the analysis result,different adjustment solutions were put forward to develop the relevant formations. The Monthly oil production increased 7.6 % and the water cut decreased 8.9 % after the adjusted solutions. Good results indicate that the learning from this method gained will be valuable adding to other long-term waterflooding sand reservoirs in Shengli oilfield and other similar reservoirs worldwide.
基金The work was supported by the National Natural Science Foundation of China （No. 41374144）, the National Key Basic Research Program of China （973 Program） （No. 2014CB239201）, and SINOPEC Key Laboratory of Geophysics.
文摘The pore structure of the tight limestone in the Daanzhai Member of the Ziliujing Formation, Jurassic System, in central Sichuan Basin, China, is complex but essential to the exploration and development of tight oil. The pore structure of the tight limestone is studied by using scanning electron microscopy （SEM）, nitrogen adsorption, high-pressure mercury intrusion, and nuclear magnetic resonance （NMR）. The experimental results suggest that the pores are mainly slit pores and mesopores and macropores contribute to the pore volume and specific surface. The displacement pressure, average pore size, and homogeneity coefficient correlate with porosity and permeability and can be used to evaluate the pore structure. The full pore-size distribution was obtained by combining nitrogen adsorption and high-pressure mercury intrusion. We find that the limestone mainly contains mesopores with diameter of 2-50 nm. The T2 distribution was converted into pore-size distribution, well matching the full pore-size distribution. The relation between T2 and pore size obeys a power law and the geometric mean of T2 correlates with the pore structure and can be used in the pore structure evaluation.
文摘The accurate prediction of fracturing pressure for pay zone is the very important guidance to hydraulic fracturing design and operation. The pore pressure around the wellbore happens to change variously as the fracturing fluid entering the pay zone. The change of pore pressure affects the stress-state and the fracturing pressure around the wellbore. In this paper, a new concept of the effective membrane pressure coefficient is presented according to the wall building capacity of the fracturing fluid, then the change of pore pressure around the wellbore is studied, and it is proven that the prediction model for fracturing pressure is improved.
