Radioactive markers are useful in dating lead （Pb） deposition patterns from industrialization in sedimentary archives. As a well-known natural reserve in the world, Yancheng coastal wetland in Jiangsu Province is on...Radioactive markers are useful in dating lead （Pb） deposition patterns from industrialization in sedimentary archives. As a well-known natural reserve in the world, Yancheng coastal wetland in Jiangsu Province is one of areas most sensitive to global sea level change and is located in the most developed and polluted region of China. Two cores were collected in Yancheng wetland in October 2013 and dated using 210pb and 137Cs radiometric techniques. Sediments in both cores were sectioned into depth bands and examined systematically for dry bulk density, water content, magnetic susceptibility and grain-size. Multiple elements including Pb were also measured using inductively coupled plasma systems. Unsupported 21~Pb activities decreased with depth in both of the two cores, and 21~pb chronologies were established （covering 150 years） using the constant rate of supply （CRS） model. The measured Pb contents ranged from 14.97 mg/kg to 29.40 mg/kg with average values of 17.17-22.79 mg/kg, and the Pb fluxes ranged from 41.70 mg/（m2·yr） to 172.70 mg/（m2·yr） with averages of 95.59-123.41 mg/（m2·yr）. Temporal variations of Pb flux, enrichment factors and Pb isotopes show a gradual and continuous increase over time and clearly reflect increased emissions from anthropogenic activities in the region. The Pb isotopic compositions show that most of Pb deposition in Yancheng wetland is input from natural sources by water flows and has the same levels of Pb as in the surface sediment of the Yangtze River and the Pacific mineral aerosol. We also stress the anthropogenic Pb contribution in Yangcheng wetland sediment and the reason of our Pb isotopes not showing anthropogenic signature is likely the insta- bility of anthropogenic Pb in high Fe/Mn oxide conditions. Therefore, more attention should be paid to current local pollution problems, and society should take action to seek a balance between economic development and environmental protection.展开更多
To investigate the spatio-temporal and compositional variation of selected water quality parameters and understand the puri- fying effects of wetland in Fujin National Wetland Park （FNWP）, China, the trophic level i...To investigate the spatio-temporal and compositional variation of selected water quality parameters and understand the puri- fying effects of wetland in Fujin National Wetland Park （FNWP）, China, the trophic level index （TLI）, paired samples t-test and correla- tion analysis were used for the statistical analysis of a set of 10 water quality parameters. The analyses were based on water samples collected from 22 stations in FNWP between 2014 and 2016. Results initially reveal that total nitrogen （TN） concentrations are above class V levels （2 mg/L）, total phosphorus （TP） concentrations are below class III levels （0.2 mg/L）, and that all other parameters fall within standard ranges. Highest values for TN, pH, and Chlorophyll-a were recorded in 2016, while the levels of chemical oxygen de- mand （CODMn） and biochemical oxygen demand （BODs） were lowest during this year. Similarly, TN values were highest between 2014 and 2016 while dissolved oxygen （DO） concentrations were lowest in the summer and TP concentrations were highest in the autumn. Significant variations were also found in Secchi depth （SD）, TN, CODMn （P 〈 0.01）, TP, and DO levels （P 〈 0.05） between the inlet and outlet of the park. High-to-low levels of TN, TP, and TDS were found in cattails, reeds, and open water （the opposite trend was seen in SD levels）. Tested wetland water had a light eutrophication status in most cases and TN and TP removal rates were between 7.54%-84.36% and 37.50%-70.83%, respectively. Data also show no significant annual changes in water quality within this wetland, although obvious affects from surrounding agricultural drainage were nevertheless recorded. Results reveal a high major nutrient removal efficiency （N and P）. The upper limits of these phenomena should be addressed in future research alongside a more efficient and scientific agricultural layout for the regions in and around the FNWP.展开更多
基金Natural Science Foundation of Jiangsu Province,China(No.BK20131058)NSFC-CNRS(National Natural Science Foundation of China-Centre National de la Recherche Scientifique(National Center for Scientific Research)) Joint Research Project(No.41611130163)+1 种基金National Natural Science Foundation of China(No.41301215)National Basic Research Program of China(No.2012CB956100)
文摘Radioactive markers are useful in dating lead （Pb） deposition patterns from industrialization in sedimentary archives. As a well-known natural reserve in the world, Yancheng coastal wetland in Jiangsu Province is one of areas most sensitive to global sea level change and is located in the most developed and polluted region of China. Two cores were collected in Yancheng wetland in October 2013 and dated using 210pb and 137Cs radiometric techniques. Sediments in both cores were sectioned into depth bands and examined systematically for dry bulk density, water content, magnetic susceptibility and grain-size. Multiple elements including Pb were also measured using inductively coupled plasma systems. Unsupported 21~Pb activities decreased with depth in both of the two cores, and 21~pb chronologies were established （covering 150 years） using the constant rate of supply （CRS） model. The measured Pb contents ranged from 14.97 mg/kg to 29.40 mg/kg with average values of 17.17-22.79 mg/kg, and the Pb fluxes ranged from 41.70 mg/（m2·yr） to 172.70 mg/（m2·yr） with averages of 95.59-123.41 mg/（m2·yr）. Temporal variations of Pb flux, enrichment factors and Pb isotopes show a gradual and continuous increase over time and clearly reflect increased emissions from anthropogenic activities in the region. The Pb isotopic compositions show that most of Pb deposition in Yancheng wetland is input from natural sources by water flows and has the same levels of Pb as in the surface sediment of the Yangtze River and the Pacific mineral aerosol. We also stress the anthropogenic Pb contribution in Yangcheng wetland sediment and the reason of our Pb isotopes not showing anthropogenic signature is likely the insta- bility of anthropogenic Pb in high Fe/Mn oxide conditions. Therefore, more attention should be paid to current local pollution problems, and society should take action to seek a balance between economic development and environmental protection.
基金Under the auspices of the National Natural Science Foundation of China(No.D41271106)the National Key Research and Development Program of China(No.2016YFA0602303)
文摘To investigate the spatio-temporal and compositional variation of selected water quality parameters and understand the puri- fying effects of wetland in Fujin National Wetland Park （FNWP）, China, the trophic level index （TLI）, paired samples t-test and correla- tion analysis were used for the statistical analysis of a set of 10 water quality parameters. The analyses were based on water samples collected from 22 stations in FNWP between 2014 and 2016. Results initially reveal that total nitrogen （TN） concentrations are above class V levels （2 mg/L）, total phosphorus （TP） concentrations are below class III levels （0.2 mg/L）, and that all other parameters fall within standard ranges. Highest values for TN, pH, and Chlorophyll-a were recorded in 2016, while the levels of chemical oxygen de- mand （CODMn） and biochemical oxygen demand （BODs） were lowest during this year. Similarly, TN values were highest between 2014 and 2016 while dissolved oxygen （DO） concentrations were lowest in the summer and TP concentrations were highest in the autumn. Significant variations were also found in Secchi depth （SD）, TN, CODMn （P 〈 0.01）, TP, and DO levels （P 〈 0.05） between the inlet and outlet of the park. High-to-low levels of TN, TP, and TDS were found in cattails, reeds, and open water （the opposite trend was seen in SD levels）. Tested wetland water had a light eutrophication status in most cases and TN and TP removal rates were between 7.54%-84.36% and 37.50%-70.83%, respectively. Data also show no significant annual changes in water quality within this wetland, although obvious affects from surrounding agricultural drainage were nevertheless recorded. Results reveal a high major nutrient removal efficiency （N and P）. The upper limits of these phenomena should be addressed in future research alongside a more efficient and scientific agricultural layout for the regions in and around the FNWP.
