Differential electrolytic potentiometry （DEP） was coupled with Flow injection analysis （FIA） technique for the determination of Procainamide in pharmaceutical preparations. Platinum electrodes were used as an indi...Differential electrolytic potentiometry （DEP） was coupled with Flow injection analysis （FIA） technique for the determination of Procainamide in pharmaceutical preparations. Platinum electrodes were used as an indicating system to follow the oxidation of Procainamide with cerium（IV）, and permanganate in an acidic medium. The oxidation reactions of Procainamide with Ce（IV） and/or permanganate are fast enough to permit its determination by flow injection in sulfuric acid media. The univariate method was employed to optimize the variables such as the current density, the flow rate, the oxidant concentration and the concentration of sulfuric acid. The proposed method was linear in the range 20-100 μg.mL^-1 , the DL and R2 values were 12 μg.mL^-1 and 0.995 respectively. The procedure was applied successfully to the determination of Procainamide in commercial tablets. The results of this study were favorably compared statistically with those obtained with official methods.展开更多
The conventional quality control method of core rocldill dam construction exhibit difficulty controlling compaction parameters accurately or ensuring construction quality. This is because it is easily influenced by hu...The conventional quality control method of core rocldill dam construction exhibit difficulty controlling compaction parameters accurately or ensuring construction quality. This is because it is easily influenced by human behavior or lack of adequate management. We therefore establish the timely monitoring indexes and control criteria of compaction processes by considering the characteristics and quality requirements of high core rockffll dam construction. Based on the established indexes and criteria, integrating GPS, GPRS and PDA technologies, a real-time compaction quality monitoring method is proposed. The relevant key techniques are proposed as well, including automatic collection of information and a graphic algorithm for rolling-process visualization. By the proposed method and techniques, a real-time monitoring system is provided to realize the precise automatic online entire-process monitoring of compaction parameters, including compaction pass, rolling trajectory, nmning speed of roller, vibration status and rolled pavement thickness. The application of the Nuozhadu project shows that the proposed system can control compaction parameters effectively and ensure better construction quality. Therefore, it might become a new way towards construction quality control of high core rockfill dam.展开更多
A nanopositioning system of both millimetric stroke and nanometric tracking accuracy is a key component for nanofabrication in many applications. In this paper, a novel bi-axial beam-flexure nano servo stage is propos...A nanopositioning system of both millimetric stroke and nanometric tracking accuracy is a key component for nanofabrication in many applications. In this paper, a novel bi-axial beam-flexure nano servo stage is proposed to support a direct writing system for femtosecond laser nanofabrication. The important features of the stage lie in: a mirror symmetric instead of rotational symmetric configuration is adopted to restrict cross axis coupling, and a novel Z-shaped guidance module is proposed to achieve relative large linear stiffness range, in addition a redundant constraints module is introduced to increase off-axis stiffness of the stage. Mechanical analysis and system identification are provided, with which a feedback control algorithm demonstrates the tracking capability for laser fabrication purposes. Based on the fabricated XY nano-stage, real time control and measurements are deployed, demonstrating the millimetric operating workspace and 77.8 nm(RMS) error of tracking a circular trajectory.展开更多
文摘Differential electrolytic potentiometry （DEP） was coupled with Flow injection analysis （FIA） technique for the determination of Procainamide in pharmaceutical preparations. Platinum electrodes were used as an indicating system to follow the oxidation of Procainamide with cerium（IV）, and permanganate in an acidic medium. The oxidation reactions of Procainamide with Ce（IV） and/or permanganate are fast enough to permit its determination by flow injection in sulfuric acid media. The univariate method was employed to optimize the variables such as the current density, the flow rate, the oxidant concentration and the concentration of sulfuric acid. The proposed method was linear in the range 20-100 μg.mL^-1 , the DL and R2 values were 12 μg.mL^-1 and 0.995 respectively. The procedure was applied successfully to the determination of Procainamide in commercial tablets. The results of this study were favorably compared statistically with those obtained with official methods.
基金supported by the National Natural Science Foundation of China (Grant Nos. 51021004, 51079096)the Program for New Century Excellent Talents in University (Grant No. NCET-08-0391)
文摘The conventional quality control method of core rocldill dam construction exhibit difficulty controlling compaction parameters accurately or ensuring construction quality. This is because it is easily influenced by human behavior or lack of adequate management. We therefore establish the timely monitoring indexes and control criteria of compaction processes by considering the characteristics and quality requirements of high core rockffll dam construction. Based on the established indexes and criteria, integrating GPS, GPRS and PDA technologies, a real-time compaction quality monitoring method is proposed. The relevant key techniques are proposed as well, including automatic collection of information and a graphic algorithm for rolling-process visualization. By the proposed method and techniques, a real-time monitoring system is provided to realize the precise automatic online entire-process monitoring of compaction parameters, including compaction pass, rolling trajectory, nmning speed of roller, vibration status and rolled pavement thickness. The application of the Nuozhadu project shows that the proposed system can control compaction parameters effectively and ensure better construction quality. Therefore, it might become a new way towards construction quality control of high core rockfill dam.
基金supported by Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry(Grant No.20121028120)the National Natural Science Foundation of China(Grant No.61327003)+4 种基金the Open Foundation of the State Key Laboratory of Fluid Power andMechatronic Systems(Grant No.GZKF-201413)the Fundamental Research Funds of Shandong University(Grant No.2015JC034)the National Key Basic Research Program of China(Grant No.2015CB059900)Beijing Natural Science Foundation(Grant No.3162019)the Fundamental Research Funds of Beihang University(Grant No.74003401)
文摘A nanopositioning system of both millimetric stroke and nanometric tracking accuracy is a key component for nanofabrication in many applications. In this paper, a novel bi-axial beam-flexure nano servo stage is proposed to support a direct writing system for femtosecond laser nanofabrication. The important features of the stage lie in: a mirror symmetric instead of rotational symmetric configuration is adopted to restrict cross axis coupling, and a novel Z-shaped guidance module is proposed to achieve relative large linear stiffness range, in addition a redundant constraints module is introduced to increase off-axis stiffness of the stage. Mechanical analysis and system identification are provided, with which a feedback control algorithm demonstrates the tracking capability for laser fabrication purposes. Based on the fabricated XY nano-stage, real time control and measurements are deployed, demonstrating the millimetric operating workspace and 77.8 nm(RMS) error of tracking a circular trajectory.
