The factors and mechanisms of oxidative degradation of three organophosphorus pesticides （dichlorvos, methamidophos and phoxim） were studied with sodium percarbonate （SPC） as a solid oxidant. The result showed tha...The factors and mechanisms of oxidative degradation of three organophosphorus pesticides （dichlorvos, methamidophos and phoxim） were studied with sodium percarbonate （SPC） as a solid oxidant. The result showed that SPC has highly activity in degrading these organophosphous pesticides. The most efficient degradation of pesticides occurred under basic conditions and the degradation rates increased with time extension and high temperature. The degradation of organophosphorus pesticides was expected to get even better results at lower initial concentration. Furthermore, we analyzed the intermediate products by NMP, spectrometry. On the basis of the analytical result, the oxidative degradation mechanism was proposed for each organophosphous pesticide. It is significant to understand the environment chemistry of organophosphorus pesticides in environmental system.展开更多
文摘The factors and mechanisms of oxidative degradation of three organophosphorus pesticides （dichlorvos, methamidophos and phoxim） were studied with sodium percarbonate （SPC） as a solid oxidant. The result showed that SPC has highly activity in degrading these organophosphous pesticides. The most efficient degradation of pesticides occurred under basic conditions and the degradation rates increased with time extension and high temperature. The degradation of organophosphorus pesticides was expected to get even better results at lower initial concentration. Furthermore, we analyzed the intermediate products by NMP, spectrometry. On the basis of the analytical result, the oxidative degradation mechanism was proposed for each organophosphous pesticide. It is significant to understand the environment chemistry of organophosphorus pesticides in environmental system.
