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AN/MAA共聚物泡沫塑料泡体结构研究 被引量:8
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作者 陈挺 张广成 +2 位作者 刘铁民 张翠 史学涛 《材料工程》 EI CAS CSCD 北大核心 2007年第6期15-19,54,共6页
通过烘箱自由发泡制备丙烯腈(AN)/甲基丙烯酸(MAA)共聚物泡沫塑料,讨论了该泡沫塑料泡孔平均孔径随泡沫塑料密度变化的规律,研究了成核剂和应力对泡沫塑料泡孔尺寸的影响,通过光学显微和电子扫描显微观察了该泡沫塑料的整体结构和微观... 通过烘箱自由发泡制备丙烯腈(AN)/甲基丙烯酸(MAA)共聚物泡沫塑料,讨论了该泡沫塑料泡孔平均孔径随泡沫塑料密度变化的规律,研究了成核剂和应力对泡沫塑料泡孔尺寸的影响,通过光学显微和电子扫描显微观察了该泡沫塑料的整体结构和微观结构。结果表明:AN/MAA共聚物泡沫塑料泡孔平均孔径随密度的增加而减小;碳酰胺能起到成核剂的作用,显著减小泡沫塑料泡孔尺寸;可发泡共聚物的应力发白现象能改善其发泡成核效果并使泡孔孔径大大减小;该共聚物泡沫塑料具有高闭孔率、各向同性的特征,其泡壁为三至七边形,泡棱由三个泡壁相交而成,泡壁体积分数随密度的增加而减小。 展开更多
关键词 丙烯腈 甲基丙烯酸 沫塑料 泡体结构
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高密度增强硬质聚氨酯泡沫塑料的复合泡体结构 被引量:7
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作者 王建华 芦艾 +5 位作者 周秋明 田春蓉 杨鸣波 李忠明 冯建民 黄锐 《中国塑料》 CAS CSCD 北大核心 2001年第4期28-31,共4页
通过对高密度玻璃纤维增强硬质聚氨酯泡沫塑料 (RRPUF)的断裂面形态观察 ,发现RRPUF含有多种形状的泡孔 ,是一种泡孔之间相互连结、贯穿的复合泡体结构。研究结果发现 ,密度分别为 0 .11、0 .3 1及 0 .5 1g/cm3 的RRPUF的泡体结构大致相... 通过对高密度玻璃纤维增强硬质聚氨酯泡沫塑料 (RRPUF)的断裂面形态观察 ,发现RRPUF含有多种形状的泡孔 ,是一种泡孔之间相互连结、贯穿的复合泡体结构。研究结果发现 ,密度分别为 0 .11、0 .3 1及 0 .5 1g/cm3 的RRPUF的泡体结构大致相同 ,都是复合泡体结构 ,但随密度增大 ,泡孔形状更趋于球体 ,泡孔尺寸分布范围变窄 ,平均尺寸减小。还计算了RRPUF的气体体积含量与密度及纤维之间的关系 ,发现其主要与泡体密度有关。此外 ,还初步探讨了复合泡体结构的形成机理 ,指出发泡剂和热分布不均是产生复合泡体结构的主要因素。 展开更多
关键词 高密度 玻璃纤维增强聚氨酯沫塑料 复合泡体结构 积含量
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建筑保温用聚氨酯泡体结构与性能的研究 被引量:5
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作者 吴蓁 孙揭阳 +2 位作者 郭青 于广豪 雍容 《新型建筑材料》 北大核心 2009年第8期54-57,共4页
研究了环保型发泡剂种类、特殊催化剂对建筑保温用聚氨酯泡体结构与性能的影响。研究结果表明,可通过改变催化剂有机锡用量协调凝胶速率与发泡速率的匹配以调节泡体结构及性能;不同类型的发泡剂所制得的聚氨酯泡体结构及性能均有所不同。
关键词 建筑保温 聚氨酯 泡体结构 性能 环保型发 催化剂
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不同原料组分对聚氨酯泡沫反应温度及泡沫密度、泡体结构、热稳定性的影响 被引量:1
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作者 张弛 聂士斌 《安徽理工大学学报(自然科学版)》 CAS 2016年第6期39-46,共8页
为进一步研究聚氨酯泡沫(PUF)的物理性能和热性能,以一步法制备聚氨酯泡沫,研究了黑料、发泡剂、锡类催化剂和泡沫稳定剂对PUF的影响。研究表明当物理发泡剂HCFC-141B的质量份数从8.33增加至50.0,反应温度从109℃下降到80.0℃,PUF密度从... 为进一步研究聚氨酯泡沫(PUF)的物理性能和热性能,以一步法制备聚氨酯泡沫,研究了黑料、发泡剂、锡类催化剂和泡沫稳定剂对PUF的影响。研究表明当物理发泡剂HCFC-141B的质量份数从8.33增加至50.0,反应温度从109℃下降到80.0℃,PUF密度从0.074 g/cm^3下降到0.044 g/cm^3,泡沫孔径明显增大,同时PUF800℃残炭量从25%下降到5%;当泡沫稳定剂硅油1086的质量份数从0增加到3.33,PUF反应温度从113℃下降到84.5℃,密度从0.222g/cm^3下降到0.047 g/cm^3,泡沫孔径明显减小,泡体变得致密规整,同时PUF800℃残炭量从16%上升到23%。实验表明,配方为44V20 167份,HCFC-141B 8.33份,C-101 0.083份,硅油1086 3.33份的泡沫具有较好的物理性能和热性能。 展开更多
关键词 聚氨酯 反应温度 密度 热稳定性 泡体结构
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硬质聚氨酯泡沫塑料结构及其性能的研究 被引量:21
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作者 吴蓁 郭青 +1 位作者 沈军 于广豪 《建筑材料学报》 EI CAS CSCD 北大核心 2009年第4期453-457,共5页
应用环保型发泡剂制备了硬质聚氨酯泡沫塑料,然后分别对影响其泡体结构和性能的因素(包括聚醚配合比、匀泡剂用量、催化剂用量等)进行了研究.结果表明:可通过改变催化剂有机锡用量来协调凝胶速率与发泡速率的匹配,从而调节泡体的结构及... 应用环保型发泡剂制备了硬质聚氨酯泡沫塑料,然后分别对影响其泡体结构和性能的因素(包括聚醚配合比、匀泡剂用量、催化剂用量等)进行了研究.结果表明:可通过改变催化剂有机锡用量来协调凝胶速率与发泡速率的匹配,从而调节泡体的结构及性能;聚醚配合比和匀泡剂用量等均对泡体结构及性能产生影响. 展开更多
关键词 硬质聚氨酯沫塑料 泡体结构 力学性能 玻璃化转变温度
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增强硬质聚氨酯泡沫塑料的压缩破坏行为 被引量:12
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作者 朱海静 杨伟 +5 位作者 杨鸣波 王建华 芦艾 田春蓉 周秋明 罗陈雷 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2003年第4期133-135,143,共4页
研究了玻纤、玻璃微珠增强材料增强的硬质聚氨酯泡沫塑料在静态压缩下泡孔结构的变化。实验结果表明 ,两种增强材料其压缩强度和模量都有不同程度的提高 ,但是其破坏方式则完全不同 :玻纤增强的泡沫塑料的破坏方式为泡孔的塌陷和纤维的... 研究了玻纤、玻璃微珠增强材料增强的硬质聚氨酯泡沫塑料在静态压缩下泡孔结构的变化。实验结果表明 ,两种增强材料其压缩强度和模量都有不同程度的提高 ,但是其破坏方式则完全不同 :玻纤增强的泡沫塑料的破坏方式为泡孔的塌陷和纤维的脱粘 。 展开更多
关键词 玻璃纤维 玻璃微珠增强材料 硬质聚氨酯沫塑料 压缩破坏 泡体结构
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大型模胎用硬质聚氨酯泡沫塑料的制备研究 被引量:3
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作者 礼嵩明 张广成 米星宇 《应用化工》 CAS CSCD 2010年第11期1703-1706,1712,共5页
研究了大型模胎用硬质聚氨酯泡沫塑料的制备方法,考察了催化剂用量、匀泡剂用量、物理发泡剂用量、化学发泡剂、模具压力、后处理温度等对硬质聚氨酯泡沫塑料泡体结构和性能的影响。结果表明,可以通过控制催化剂三乙醇胺和有机锡的用量... 研究了大型模胎用硬质聚氨酯泡沫塑料的制备方法,考察了催化剂用量、匀泡剂用量、物理发泡剂用量、化学发泡剂、模具压力、后处理温度等对硬质聚氨酯泡沫塑料泡体结构和性能的影响。结果表明,可以通过控制催化剂三乙醇胺和有机锡的用量配比来调节发泡和凝胶速率,匀泡剂用量、物理发泡剂用量、化学发泡剂、模具压力、后处理温度等均能对泡体结构和性能产生影响。 展开更多
关键词 大型模胎 硬质聚氨酯沫塑料 泡体结构 密度 压缩强度
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新型环保型发泡剂在聚氨酯硬泡中的应用研究 被引量:4
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作者 吴蓁 郭青 《新型建筑材料》 北大核心 2008年第1期42-47,共6页
通过组合聚醚与聚氨酯硬泡的制备,对发泡剂HFC-365mfc、HFC-365/227和水的发泡效果、泡体结构、与组合聚醚的互溶性及泡体力学性能等进行了研究,并与HCFC-141b进行了比较。研究结果表明,HFC-365mfc、HFC-365/227与组合聚醚均有较好的溶... 通过组合聚醚与聚氨酯硬泡的制备,对发泡剂HFC-365mfc、HFC-365/227和水的发泡效果、泡体结构、与组合聚醚的互溶性及泡体力学性能等进行了研究,并与HCFC-141b进行了比较。研究结果表明,HFC-365mfc、HFC-365/227与组合聚醚均有较好的溶解性与配伍性;在等质量下,两者在聚氨酯中的发泡效果稍差于HCFC-141b;而在等摩尔加入量时,HFC-365/227的泡孔结构较均匀,平均孔径较小,且所制备泡体的拉伸强度较高,断裂伸长率较大;全水发泡所制得的泡体密度较大。 展开更多
关键词 环保型发 聚氨酯硬 保温材料 效果 泡体结构 力学性能
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环保型发泡剂HFC-365mfc在硬质聚氨酯泡沫塑料中的应用研究 被引量:5
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作者 孙揭阳 《上海应用技术学院学报(自然科学版)》 2009年第4期295-299,共5页
对HFC-365m fc发泡剂在硬质聚氨酯泡沫塑料中的应用作了较为系统研究,研究结果表明HFC-365m fc作为环保型的发泡剂其泡体的综合力学性能与HCFC-141b比较接近,泡体的力学性能达到了国家"喷涂聚氨酯泡体保温材料"标准(JC/T998-2... 对HFC-365m fc发泡剂在硬质聚氨酯泡沫塑料中的应用作了较为系统研究,研究结果表明HFC-365m fc作为环保型的发泡剂其泡体的综合力学性能与HCFC-141b比较接近,泡体的力学性能达到了国家"喷涂聚氨酯泡体保温材料"标准(JC/T998-2006)标准,可作为HCFC-141b发泡剂的替代品用于市场。 展开更多
关键词 环保型发 聚氨酯硬 力学性能 泡体结构
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新型环保型发泡剂在聚氨酯硬泡中的应用研究
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作者 吴蓁 郭青 《保温材料与节能技术》 2008年第2期6-11,共6页
通过组合聚醚与聚氨酯硬泡的制备,对发泡剂HFC-365mfc、HFC-365/227和水的发泡效果、泡体结构、与组合聚醚的互溶性及泡体力学性能等进行了研究,并与HCFC-141b进行了比较。研究结果表明,HFC-365mfc、HFC-365/227与组合聚醚均有较... 通过组合聚醚与聚氨酯硬泡的制备,对发泡剂HFC-365mfc、HFC-365/227和水的发泡效果、泡体结构、与组合聚醚的互溶性及泡体力学性能等进行了研究,并与HCFC-141b进行了比较。研究结果表明,HFC-365mfc、HFC-365/227与组合聚醚均有较好的溶解性与配伍性;在等质量下,两者在聚氨酯中的发泡效果稍差于HCFC-141b;而在等摩尔加入量时,HFC-365/227的泡孔结构较均匀,平均孔径较小,且所制备泡体的拉伸强度较高,断裂伸长率较大;全水发泡所制得的泡体密度较大。 展开更多
关键词 环保型发 聚氨酯硬 保温材料 效果 泡体结构 力学性能
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Debinding of stainless steel foam precursor with 3-D open-cell network structure 被引量:2
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作者 李昌林 王辉 +2 位作者 周向阳 李劼 刘宏专 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第12期2340-2344,共5页
The thermal debinding behavior of stainless steel foam precursor in vacuum was studied and compared with that in hydrogen.The formation cause of pore channel was analyzed.The experiment results show that the binder re... The thermal debinding behavior of stainless steel foam precursor in vacuum was studied and compared with that in hydrogen.The formation cause of pore channel was analyzed.The experiment results show that the binder removal rate in vacuum is higher than that in hydrogen.In vacuum,the organic compounds can be removed effectively without change of pore size and the pore morphology for the sample.After pre-sintering,some sintering necks form and the sample has certain intensity.The initial surface pore forms with the temperature increasing at first,and then the internal melting binder is aspirated to form initial pore because of the capillary force and the metal powders re-arrange with the migration of binder at the same time. 展开更多
关键词 PRECURSOR stainless steel foam VACUUM thermal debinding pore channel
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Influence of impeller diameter on overall gas dispersion properties in a sparged multi-impeller stirred tank 被引量:4
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作者 包雨云 王冰洁 +2 位作者 林明丽 高正明 杨杰 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第6期890-896,共7页
The impeller configuration with a six parabolic blade disk turbine below two down-pumping hydrofoil propellers, identified as PDT + 2CBY, was used in this study. The effect of the impeller diameter D, ranging from0.30... The impeller configuration with a six parabolic blade disk turbine below two down-pumping hydrofoil propellers, identified as PDT + 2CBY, was used in this study. The effect of the impeller diameter D, ranging from0.30 T to 0.40T(T as the tank diameter), on gas dispersion in a stirred tank of 0.48 m diameter was investigated by experimental and CFD simulation methods. Power consumption and total gas holdup were measured for the same impeller configuration PDT + 2CBY with four different D/T. Results show that with D/T increases from 0.30 to 0.40, the relative power demand(RPD) in a gas–liquid system decreases slightly. At low superficial gas velocity VSof 0.0078 m·s-1, the gas holdup increases evidently with the increase of D/T. However, at high superficial gas velocity, the system with D/T = 0.33 gets a good balance between the gas recirculation and liquid shearing rate, which resulted in the highest gas holdup among four different D/T. CFD simulation based on the two-fluid model along with the Population Balance Model(PBM) was used to investigate the effect of impeller diameter on the gas dispersion. The power consumption and total gas holdup predicted by CFD simulation were in reasonable agreement with the experimental data. 展开更多
关键词 Gas holdup MIXING Multiphase reactors Relative power demand CFD Multi-impeller stirred tank
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Damage and penetration behavior of aluminum foam at various impacts 被引量:6
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作者 CHO Hosun CHO Jaeung 《Journal of Central South University》 SCIE EI CAS 2014年第9期3442-3448,共7页
In this work, the damage and penetration behavior of aluminum foam at various types of impact were examined through experiments. The impact energy of a striker was applied on the fixed aluminum foam having a thickness... In this work, the damage and penetration behavior of aluminum foam at various types of impact were examined through experiments. The impact energy of a striker was applied on the fixed aluminum foam having a thickness of 25 mm while increasing its impact by 2 J at each strike from 6 J to 16 J. The results show that the impact energies from 6 J to 12 J could not penetrate aluminum foam. However, the aluminum foam applied with the impact energy of 12 J incurred severe damages on its lower part. Finally, the aluminum foam applied with the impact energy of 14 J was penetrated. The striker having the impact energy of 6 J could penetrate aluminum foam around 10 mm. At this moment, aluminum foam could absorb the impact energy of around 9 J. When the impact energy of 14 J was applied on the aluminum foam, the aluminum foam was penetrated and it absorbed the impact energy of around 17.2 J. It is possible to create the safer structure against impact using the results of this work. The simulation results for the verification of the experimental results imply that the results for all the experiments in this work are reliable. It is possible to predict the structural safety of the aluminum foam for an impact if the impact behavior of aluminum foam performed in this work is utilized. 展开更多
关键词 aluminum foam absorbed energy finite element analysis impact energy impact load
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A honeycomb-tube packing medium and its application to column flotation 被引量:1
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作者 ZHANG Min SHI Chang-sheng +1 位作者 LIU Jiong-tian ZHAI Ai-feng 《Mining Science and Technology》 EI CAS 2009年第6期775-778,共4页
We address problems in the development of large-scale flotation columns that use short cylinders. As a starting point, we investigated the packing medium to identify a highly efficient internal packing for the flotati... We address problems in the development of large-scale flotation columns that use short cylinders. As a starting point, we investigated the packing medium to identify a highly efficient internal packing for the flotation column. The chosen packing was a honeycomb structure with an aperture diameter of 80 mm, a web thickness of 0.80 mm, a film height of 1000 mm, packed into a 400 mm diameter space, which completely filled the vessel at optimal cost. The column consisted of a modular ring of single-hole hexagonal honeycomb tube packing made from atactic polyproplene (PP-R). The packing was tested in a cyclonic, static micro-bubble flotation column. Computational fluid dynamic modeling was used to analyze the flotation fluid in a honeycomb tube packed flotation column. Our results show that the fluid axial movement was maximized and that the transverse fluid velocities were zero in the vicinity of axial flow. Using the honeycomb tube packing for copper sulfide flotation we observed that the average concentration in the product was increased to 25.41%, from an average feed concentration of 0.729%, with an average recovery of 92.92%. The demands of on-site industrial production were met. 展开更多
关键词 FILLING column flotation mineral processing
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Numerical simulation of unsteady cavitating flows around a transient pitching hydrofoil 被引量:7
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作者 HUANG Biao WU Qin WANG GuoYu 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第1期101-116,共16页
The objective of this paper is to improve the understanding of the influence of multiphase flow on the turbulent closure model, the interplay between vorticity fields and cavity dynamics around a pitching hydrofoil. T... The objective of this paper is to improve the understanding of the influence of multiphase flow on the turbulent closure model, the interplay between vorticity fields and cavity dynamics around a pitching hydrofoil. The effects of pitching rate on the sub- cavitating and cavitating response of the pitching hydrofoil are also investigated. In particular, we focus on the interactions between cavity inception, growth, and shedding and the vortex flow structures, and their impacts on the hydrofoil performance. The calculations are 2-D and performed by solving the incompressible, multiphase Unsteady Reynolds Averaged Navier Stokes (URANS) equations via the commercial CFD code CFX. The k-co SST (Shear Stress Transport) turbulence model is used along with the transport equation-based cavitation models. The density correction function is considered to reduce the eddy viscosity according to the computed local fluid mixture density. The calculation results are validated with experiments conducted by Ducoin et al. (see Computational and experimental investigation of flow over a transient pitching hydrofoil, Eur J Mech/B Fluids, 2009, 28:728-743 and An experimental analysis of fluid structure interaction of a flexible hydrofoil in vari- ous flow regimes including cavitating flow, Eur J Mech B/fluids, 2012, 36: 63-74). Results are shown for a NACA66 hydro- foil subject to slow (quasi static, t2=6~/s, &* =0.18) and fast (dynamic, &=63~/s, dr" =1.89) pitching motions from a =0~ to a =15~. Both subcavitaing (or =8.0) and cavitating (cr=3.0) flows are considered. For subcavitating flow (or=8.0), low frequency fluctuations have been observed when the leading edge vortex shedding occurs during stall, and delay of stall is ob- served with increasing pitching velocity. For cavitating flow (tr=3.0), small leading edge cavities are observed with the slow pitching case, which significantly modified the vortex dynamics at high angles of attack, leading to high frequency fluctuations of the hydrodynamic coefficients and different stall behaviors compared to the subcavitating flow at the same pitching rate. On the other hand, for the fast pitching case at or=3.0, large-scale sheet/cloud cavitation is observed, the cavity behavior is un- steady and has a strong impact on the hydrodynamic response, which leads to high amplitude fluctuations of the hydrodynamic coefficients, as well as significant changes in the stall and post-stall behavior. The numerical results also show that the local density modification helps to reduce turbulent eddy viscosity in the cavitating region, which significantly modifies the cavity lengths and shedding frequencies, particularly for the fast pitching case. In general, compared with the experimental visualiza- tions, the numerical results with local density correction have been found to agree well with experimental measurements and observations for both slow and fast transient pitching cases. 展开更多
关键词 unsteady cavitating flow pitching hydrofoil turbulence model
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