Influence of silicon oxide(SiO_2) and aluminum oxide(Al_2O_3) nanoparticles on the stability of nanoparticles and sodium dodecyl sulfate(SDS) mixed solution foams was studied at bulk and bubble-scale. Foam apparent vi...Influence of silicon oxide(SiO_2) and aluminum oxide(Al_2O_3) nanoparticles on the stability of nanoparticles and sodium dodecyl sulfate(SDS) mixed solution foams was studied at bulk and bubble-scale. Foam apparent viscosity was also determined in Hele-Shaw cell In order to investigate the foam performance at static and dynamic conditions. Results show that the maximum adsorption of surfactant on the nanoparticles occurs at 3 wt% surfactant concentration. Foam stability increases while the foamability decreases with the increasing nanoparticle concentration. However, optimum nanoparticle concentration corresponding to maximum foam stability was obtained at 1.0 wt% nanoparticle concentration for the hydrophilic SiO_2/SDS and Al_2O_3/SDS foams. Foam performance was enhanced with increasing nanoparticles hydrophobicity. Air-foams were generally more stable than CO_2 foams.Foam apparent viscosity increased in the presence of nanoparticles from 20.34 mPa·s to 84.84 mPa·s while the film thickness increased from 27.5 μm to 136 μm. This study suggests that the static and dynamic stability of conventional foams could be improved with addition of appropriate concentration of nanoparticles into the surfactant solution. The nanoparticles improve foam stability by their adsorption and aggregation at the foam lamellae to increase film thickness and dilational viscoelasticity. This prevents liquid drainage and film thinning and improves foam stability both at the bulk and bubble scale.展开更多
Density functional theory (DFT) simulation was performed to investigate the adsorption mechanisms between frothers and gas–liquid interface. In water phase, the polar head group of the frother molecule was connected ...Density functional theory (DFT) simulation was performed to investigate the adsorption mechanisms between frothers and gas–liquid interface. In water phase, the polar head group of the frother molecule was connected with water molecules by hydrogen bonding, while the non-polar group showed that hydrophobic property and water molecules around it were repelled away. The adsorption of water molecules on single frother molecule suggests that the complexes of α-terpineol-7H2O, MIBC-7H2O and DF200-13H2O reach their stable structure. The hydration shell affects both the polar head group and the non-polar group. The liquid film drainage rate of DF200 is the lowest, while α-terpineol and MIBC are almost the same. The adsorption layer of frother molecules adsorbed at the gas-liquid interface reveals that the α-terpineol molecules are more neatly arranged and better distributed. The DF200 molecules are arranged much more loosely than MIBC molecules. These results suggest that the α-terpineol molecule layer could better block the diffusion of gas through the liquid film than DF200 and MIBC. The simulation results indicate that the foam stability of α-terpineol is the best, followed by DF200 and MIBC.展开更多
In order to extract froth morphological feature,a bubble image adaptive segmentation method was proposed.Considering the image's low contrast and weak froth edges,froth image was coarsely segmented by using fuzzy ...In order to extract froth morphological feature,a bubble image adaptive segmentation method was proposed.Considering the image's low contrast and weak froth edges,froth image was coarsely segmented by using fuzzy c means(FCM) algorithm. Through the attributes of size and shape pattern spectrum,the optimal morphological structuring element was determined.According to the optimal parameters,some image noises were removed with an improved area opening and closing by reconstruction operation,which consist of image regional markers,and the bubbles were finely separated from each other by watershed transform.The experimental results show that the structural element can be determined adaptively by shape and size pattern spectrum,and the froth image is segmented accurately.Compared with other froth image segmentation method,the proposed method achieves much high accuracy,based on which,the bubble size and shape features are extracted effectively.展开更多
Features of the motion of gel particles in a three-phase bubble column with non-foaming and foaming gas–liquid systems,determined by using experiments of radioactive particle tracking(RPT),have been compared.The trac...Features of the motion of gel particles in a three-phase bubble column with non-foaming and foaming gas–liquid systems,determined by using experiments of radioactive particle tracking(RPT),have been compared.The tracer used is a gel particle which resembles typical immobilized biocatalyst.The tracer trajectory is analyzed to extract relevant information for design purposes.The solid velocity field,turbulence parameters,dispersion coefficients,mixing times and flow transitions are determined and compared.The presence of foam significantly affects many quantified parameters,especially within the heterogeneous flow regime.The hydrodynamic stresses are reduced in the presence of foam,especially close to the disengagement.The dispersion coefficients also decrease,and the solid mixing time is only slightly affected by the presence of foam.Gas holdup,inferred both from RPT experiments and from gamma ray scanning,is higher for foaming systems and leads to a shift in the transition gas velocity towards higher values.展开更多
In this paper we demonstrate that price-to-income ratio （PIR） is the most precise indicator of measuring bubble levels in China＇s urban hoasing market under current conditions. We have built a model to measure the ...In this paper we demonstrate that price-to-income ratio （PIR） is the most precise indicator of measuring bubble levels in China＇s urban hoasing market under current conditions. We have built a model to measure the reasonable PIR ceiling. Based on current mortgage rates, loan terms and down payment ratios, we conclude that the reasonable PIR for China ＇s urban residents should lie between 4.38-6.78 and should not exceed 7. 7hen, using statistical data, we calculate current PIR in China ＇s major cities. With reference to proper PIR, we conclude the existence of bubbles in China ＇s urban housing market; in particular, bubbles hace grown enormously large in some first-tier cities, which pose a huge financial risk. Based on the above analysis, we propose some policy suggestions to carefully deflate the bubbles in these housing markets.展开更多
基金the Ministry of Higher Education(Vot no.Q.J130000.2542.08H61)Universiti Teknologi(UTM)Malaysia,for supporting this research through research management grant
文摘Influence of silicon oxide(SiO_2) and aluminum oxide(Al_2O_3) nanoparticles on the stability of nanoparticles and sodium dodecyl sulfate(SDS) mixed solution foams was studied at bulk and bubble-scale. Foam apparent viscosity was also determined in Hele-Shaw cell In order to investigate the foam performance at static and dynamic conditions. Results show that the maximum adsorption of surfactant on the nanoparticles occurs at 3 wt% surfactant concentration. Foam stability increases while the foamability decreases with the increasing nanoparticle concentration. However, optimum nanoparticle concentration corresponding to maximum foam stability was obtained at 1.0 wt% nanoparticle concentration for the hydrophilic SiO_2/SDS and Al_2O_3/SDS foams. Foam performance was enhanced with increasing nanoparticles hydrophobicity. Air-foams were generally more stable than CO_2 foams.Foam apparent viscosity increased in the presence of nanoparticles from 20.34 mPa·s to 84.84 mPa·s while the film thickness increased from 27.5 μm to 136 μm. This study suggests that the static and dynamic stability of conventional foams could be improved with addition of appropriate concentration of nanoparticles into the surfactant solution. The nanoparticles improve foam stability by their adsorption and aggregation at the foam lamellae to increase film thickness and dilational viscoelasticity. This prevents liquid drainage and film thinning and improves foam stability both at the bulk and bubble scale.
基金Projects(51574092,51874106)supported by the National Natural Science Foundation,ChinaProject supported by Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund(the second phase),China
文摘Density functional theory (DFT) simulation was performed to investigate the adsorption mechanisms between frothers and gas–liquid interface. In water phase, the polar head group of the frother molecule was connected with water molecules by hydrogen bonding, while the non-polar group showed that hydrophobic property and water molecules around it were repelled away. The adsorption of water molecules on single frother molecule suggests that the complexes of α-terpineol-7H2O, MIBC-7H2O and DF200-13H2O reach their stable structure. The hydration shell affects both the polar head group and the non-polar group. The liquid film drainage rate of DF200 is the lowest, while α-terpineol and MIBC are almost the same. The adsorption layer of frother molecules adsorbed at the gas-liquid interface reveals that the α-terpineol molecules are more neatly arranged and better distributed. The DF200 molecules are arranged much more loosely than MIBC molecules. These results suggest that the α-terpineol molecule layer could better block the diffusion of gas through the liquid film than DF200 and MIBC. The simulation results indicate that the foam stability of α-terpineol is the best, followed by DF200 and MIBC.
基金Projects(60634020,60874069) supported by the National Natural Science Foundation of ChinaProject(2009AA04Z137) supported by the National High-Tech Research and Development Program of China
文摘In order to extract froth morphological feature,a bubble image adaptive segmentation method was proposed.Considering the image's low contrast and weak froth edges,froth image was coarsely segmented by using fuzzy c means(FCM) algorithm. Through the attributes of size and shape pattern spectrum,the optimal morphological structuring element was determined.According to the optimal parameters,some image noises were removed with an improved area opening and closing by reconstruction operation,which consist of image regional markers,and the bubbles were finely separated from each other by watershed transform.The experimental results show that the structural element can be determined adaptively by shape and size pattern spectrum,and the froth image is segmented accurately.Compared with other froth image segmentation method,the proposed method achieves much high accuracy,based on which,the bubble size and shape features are extracted effectively.
基金Supported by the FONCyT(PICT2014-0704)CONICET(PIP1122015-0100902CO)Universidad de Buenos Aires(UBACyT 20020130100544BA)
文摘Features of the motion of gel particles in a three-phase bubble column with non-foaming and foaming gas–liquid systems,determined by using experiments of radioactive particle tracking(RPT),have been compared.The tracer used is a gel particle which resembles typical immobilized biocatalyst.The tracer trajectory is analyzed to extract relevant information for design purposes.The solid velocity field,turbulence parameters,dispersion coefficients,mixing times and flow transitions are determined and compared.The presence of foam significantly affects many quantified parameters,especially within the heterogeneous flow regime.The hydrodynamic stresses are reduced in the presence of foam,especially close to the disengagement.The dispersion coefficients also decrease,and the solid mixing time is only slightly affected by the presence of foam.Gas holdup,inferred both from RPT experiments and from gamma ray scanning,is higher for foaming systems and leads to a shift in the transition gas velocity towards higher values.
文摘In this paper we demonstrate that price-to-income ratio （PIR） is the most precise indicator of measuring bubble levels in China＇s urban hoasing market under current conditions. We have built a model to measure the reasonable PIR ceiling. Based on current mortgage rates, loan terms and down payment ratios, we conclude that the reasonable PIR for China ＇s urban residents should lie between 4.38-6.78 and should not exceed 7. 7hen, using statistical data, we calculate current PIR in China ＇s major cities. With reference to proper PIR, we conclude the existence of bubbles in China ＇s urban housing market; in particular, bubbles hace grown enormously large in some first-tier cities, which pose a huge financial risk. Based on the above analysis, we propose some policy suggestions to carefully deflate the bubbles in these housing markets.
