A correlation equation between the UV absorption wavenumbers of 1,4-disubstituted benzenes and the excited-state substituent constant was obtained. For 80 sorts of 1,4- disubstituted benzenes, the correlation coeffici...A correlation equation between the UV absorption wavenumbers of 1,4-disubstituted benzenes and the excited-state substituent constant was obtained. For 80 sorts of 1,4- disubstituted benzenes, the correlation coefficient was 0.9805, and the standard deviation was only 672.27 cm^-1. The results imply that the excited-state substituent constant can be used productively for research on UV energy of 1,4-disubstituted benzenes. The present method provides a new avenue to study the UV absorption spectra of aromatic systems with the excited-state substituent constant, and it is helpful to understand the effect of substituent electrostatic effects on the chemical and physical properties of conjugated compounds with multiple substituents in excited state.展开更多
Taking into account moisture in virtue of general potential temperature,the author derive a three-dimensional(3D) pseudomomentum wave-activity relation for the moist atmosphere from the primitive equations in Cartesia...Taking into account moisture in virtue of general potential temperature,the author derive a three-dimensional(3D) pseudomomentum wave-activity relation for the moist atmosphere from the primitive equations in Cartesian coordinates using the Momentum-Casimir method.Since the wave-activity relation is constructed in an ageostrophic and non-hydrostatic dynamical framework,it may be applicable to diagnosing the evolution and propagation of mesoscale systems leading to heavy rainfall.The theoretical analysis shows that,besides the local change of wave-activity flux divergence and source or sink,the wave-activity relation includes two additional forcing terms.The first is the zonal gradient of difference between general potential temperature and potential temperature perturbations,and the second is the covariance of the solenoid and gradient of water vapor,denoting the direct influence of moisture on wave-activity density.The wave-activity density was applied to a heavy precipitation event occurring in the Jianghuai region of China.The calculation showed that the wave-activity density was consistent with 6-h accumulated precipitation observations,in terms of both spatial distribution and temporal tendency.This suggested that the disturbance represented by wave-activity density was closely related to the heavy precipitation.Although the wave-activity flux divergence and the covariance of the solenoid and gradient of water vapor made the primary contribution to the local change of wave-activity density,the covariance was more remarkable.The zonal gradient of difference between general potential temperature and potential temperature perturbations made a weaker contribution to the waveactivity density.展开更多
We study the field-aligned propagating magnetospheric chorus wave instability using a fully relativistic wave growth formula,the previously developed relativistic Kappa-type(KT) distribution and the regular Kappa dist...We study the field-aligned propagating magnetospheric chorus wave instability using a fully relativistic wave growth formula,the previously developed relativistic Kappa-type(KT) distribution and the regular Kappa distribution of energetic electrons.We demonstrate that the peak growth rate using the nonrelativistic Kappa simulation is higher than that using either the relativistic KT or the Kappa simulation at/above 100 keV, because the significant relativistic effect yields a reduction in the relativistic anisotropy. The relativistic anisotropy Arel basically decreases as the thermal parameter θ2 increases, allowing the peak growth by relativistic KT or Kappa distribution to stay at the lower frequency region. The growth rates tend to increase with the loss-cone parameter l because the overall anisotropy increases. Moreover, at high energy ~1.0 MeV, both the growth rate and the upper cutoff frequency become smaller as l increases for the relativistic KT calculation because the significant relativistic effect reduces both the resonant anisotropy and the number of the hot electrons, which is in contrast to the relativistic and nonrelativistic Kappa distribution calculations because the less relativistic or non-relativistic effect enhances the resonant anisotropy as l increases. The above results can be applied to the whistler-mode wave instability in the outer radiation belts of the Earth, the Jovian inner magnetosphere and other astrophysical plasmas where relativistic electrons often exist.展开更多
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.20772028 and No.20472019）, the Natural Science Foundation of Hunan Province （No.06JJ2002）, and the Scientific Research Fund of Hunan Provincial Education Commission.
文摘A correlation equation between the UV absorption wavenumbers of 1,4-disubstituted benzenes and the excited-state substituent constant was obtained. For 80 sorts of 1,4- disubstituted benzenes, the correlation coefficient was 0.9805, and the standard deviation was only 672.27 cm^-1. The results imply that the excited-state substituent constant can be used productively for research on UV energy of 1,4-disubstituted benzenes. The present method provides a new avenue to study the UV absorption spectra of aromatic systems with the excited-state substituent constant, and it is helpful to understand the effect of substituent electrostatic effects on the chemical and physical properties of conjugated compounds with multiple substituents in excited state.
基金supported by the National Basic Research Program of China (Grant No.2009CB421505)the Key Program of the Chinese Academy of Sciences (Grant No.KZZD-EW-05)+2 种基金the project of Chinese Academy of Meteorological Sciences (Grant No.2011LASW-B15)the Spectial Scientific Research Fund of Meteorological Public Welfare of the Ministry of Sciences and Technology (Grant No.GYHY200906004)and the National Natural Science Foundation of China (Grant Nos.41175060,41075098,and 41005005)
文摘Taking into account moisture in virtue of general potential temperature,the author derive a three-dimensional(3D) pseudomomentum wave-activity relation for the moist atmosphere from the primitive equations in Cartesian coordinates using the Momentum-Casimir method.Since the wave-activity relation is constructed in an ageostrophic and non-hydrostatic dynamical framework,it may be applicable to diagnosing the evolution and propagation of mesoscale systems leading to heavy rainfall.The theoretical analysis shows that,besides the local change of wave-activity flux divergence and source or sink,the wave-activity relation includes two additional forcing terms.The first is the zonal gradient of difference between general potential temperature and potential temperature perturbations,and the second is the covariance of the solenoid and gradient of water vapor,denoting the direct influence of moisture on wave-activity density.The wave-activity density was applied to a heavy precipitation event occurring in the Jianghuai region of China.The calculation showed that the wave-activity density was consistent with 6-h accumulated precipitation observations,in terms of both spatial distribution and temporal tendency.This suggested that the disturbance represented by wave-activity density was closely related to the heavy precipitation.Although the wave-activity flux divergence and the covariance of the solenoid and gradient of water vapor made the primary contribution to the local change of wave-activity density,the covariance was more remarkable.The zonal gradient of difference between general potential temperature and potential temperature perturbations made a weaker contribution to the waveactivity density.
基金supported by the National Natural Science Foundation of China(Grant Nos.41531072,41274165,41404130,41204114&41504125)
文摘We study the field-aligned propagating magnetospheric chorus wave instability using a fully relativistic wave growth formula,the previously developed relativistic Kappa-type(KT) distribution and the regular Kappa distribution of energetic electrons.We demonstrate that the peak growth rate using the nonrelativistic Kappa simulation is higher than that using either the relativistic KT or the Kappa simulation at/above 100 keV, because the significant relativistic effect yields a reduction in the relativistic anisotropy. The relativistic anisotropy Arel basically decreases as the thermal parameter θ2 increases, allowing the peak growth by relativistic KT or Kappa distribution to stay at the lower frequency region. The growth rates tend to increase with the loss-cone parameter l because the overall anisotropy increases. Moreover, at high energy ~1.0 MeV, both the growth rate and the upper cutoff frequency become smaller as l increases for the relativistic KT calculation because the significant relativistic effect reduces both the resonant anisotropy and the number of the hot electrons, which is in contrast to the relativistic and nonrelativistic Kappa distribution calculations because the less relativistic or non-relativistic effect enhances the resonant anisotropy as l increases. The above results can be applied to the whistler-mode wave instability in the outer radiation belts of the Earth, the Jovian inner magnetosphere and other astrophysical plasmas where relativistic electrons often exist.
