Leached Pt-Fe and Pt-Co catalysts were prepared by acid leaching the reduced catalysts in acid solution. Oxidation treatments of leached catalysts produced the structure o f metal oxides decorat-ing the surface of...Leached Pt-Fe and Pt-Co catalysts were prepared by acid leaching the reduced catalysts in acid solution. Oxidation treatments of leached catalysts produced the structure o f metal oxides decorat-ing the surface of nanoparticles. The fully oxidized Fe2O3 and Co3O4 species on Pt nanoparticle sur-faces result in the low performance of the CO complete oxidation （COOX） reaction. In contrast, un-saturated FeO and CoO surface species can be formed during exposure to the CO preferential oxida-tion （CO-PROX） reaction with an excess of H2, leading to a high O2 activation ability and enhancing the CO-PROX activity. The FeOx surface structures can be transformed between these two states by varying the reactive gas environments, exhibiting oscillating activity in these two reactions. Con-versely, the CoO surface structure formed in the H2 -rich atmosphere is stable when exposed to the COOX reaction and exhibits similar activity in these two reactions. It is hoped that this work may assist in understanding the important role of surface oxides in real reactions.展开更多
Electrochemical treatment of distillery .spentwash was carried out using different combinations of aluminum and iron electrodes in batch mode of operation. The spent wash was characterized for various parameters as pe...Electrochemical treatment of distillery .spentwash was carried out using different combinations of aluminum and iron electrodes in batch mode of operation. The spent wash was characterized for various parameters as per standard method of analysis and the treatment results were analyzed in terms of chemical oxygen demand （COD） removal efficiency o.f thespent.wash. The experiments were performed to s.tudy the effect of operating parameterssuch as current density, pH of the spent wash, agitation speed, electrolysis time and the distance between the elec- trodes on the COD removal efficiency of the spent wash. It was observed that aluminum electrodes were more suitable for treatment of distillery spent wash as compared to iron electrodes. The maximum COD removal effi- ciency of 81.3% was obtained with A1-A1 electrodes at the current density of 0.187 A.cm-2 and pH 3 for an elec-trolysis time of 2 h.展开更多
基金supported by the National Natural Science Foundation of China(21403004,21403003)~~
文摘Leached Pt-Fe and Pt-Co catalysts were prepared by acid leaching the reduced catalysts in acid solution. Oxidation treatments of leached catalysts produced the structure o f metal oxides decorat-ing the surface of nanoparticles. The fully oxidized Fe2O3 and Co3O4 species on Pt nanoparticle sur-faces result in the low performance of the CO complete oxidation （COOX） reaction. In contrast, un-saturated FeO and CoO surface species can be formed during exposure to the CO preferential oxida-tion （CO-PROX） reaction with an excess of H2, leading to a high O2 activation ability and enhancing the CO-PROX activity. The FeOx surface structures can be transformed between these two states by varying the reactive gas environments, exhibiting oscillating activity in these two reactions. Con-versely, the CoO surface structure formed in the H2 -rich atmosphere is stable when exposed to the COOX reaction and exhibits similar activity in these two reactions. It is hoped that this work may assist in understanding the important role of surface oxides in real reactions.
文摘Electrochemical treatment of distillery .spentwash was carried out using different combinations of aluminum and iron electrodes in batch mode of operation. The spent wash was characterized for various parameters as per standard method of analysis and the treatment results were analyzed in terms of chemical oxygen demand （COD） removal efficiency o.f thespent.wash. The experiments were performed to s.tudy the effect of operating parameterssuch as current density, pH of the spent wash, agitation speed, electrolysis time and the distance between the elec- trodes on the COD removal efficiency of the spent wash. It was observed that aluminum electrodes were more suitable for treatment of distillery spent wash as compared to iron electrodes. The maximum COD removal effi- ciency of 81.3% was obtained with A1-A1 electrodes at the current density of 0.187 A.cm-2 and pH 3 for an elec-trolysis time of 2 h.
