Aiming at evaluating the stability of a rock mass near a fault,a microseismic(MS) monitoring system was established in Hongtoushan copper mine.The distribution of displacement and log(/),the relationship between MS ac...Aiming at evaluating the stability of a rock mass near a fault,a microseismic(MS) monitoring system was established in Hongtoushan copper mine.The distribution of displacement and log(/),the relationship between MS activity and the exploitation process,and the stability of the rock mass controlled by a fault were studied.The results obtained from microseismic data showed that MS events were mainly concentrated al the footwall of the fault.When the distance to the fault exceeded 20 m,the rock mass reached a relatively stable state.MS activity is closely related to the mining process.Under the strong disturbance from blasting,the initiation and propagation of cracks is much faster.MS activity belongs in the category of aftershocks after large scale excavation.The displacement and log(C/) obtained from MS events can reflect the difference in physical and mechanical behavior of different areas within the rock mass,which is useful in judging the integrity and degradation of the rock mass.展开更多
We report here our results on the investigation of the chain dynamics of poly(acrylic acid) in aqueous solution. The concentration of poly(acrylic acid) was approximately 3.8×10^(-4) mol/L, two orders of magnitud...We report here our results on the investigation of the chain dynamics of poly(acrylic acid) in aqueous solution. The concentration of poly(acrylic acid) was approximately 3.8×10^(-4) mol/L, two orders of magnitude higher than that reported in the literature. The p H value of the solution was 3.9, and the hydrogen bonds between the intrinsic and ionized carboxylic acid groups formed dynamic networks, which captured aggregation-induced emission-active molecules(a tetra-quaternary ammonium modified tetraphenylethene derivative) inside the polymer coils and induced fluorescence emission. The hydrogen bonds can be classified as intra- or intermolecular; both can be probed based on the emission change of the tetra-quaternary ammonium modified tetraphenylethene probes. The effects of different external stimuli on the polymer chain dynamics were investigated using different metal cations(including Na^+, Li^+, Zn^(2+), Ni^(2+), Ca^(2+), and Co^(2+)), different cation concentrations(1×10^(-6) to 4×10^(-4) mol/L), different poly(acrylic acid) molecular weights(5, 240, and 450 k Da), and different copolymers. The experimental results indicate that the long poly(acrylic acid) chains(high molecular weight) tend to form dense globular coils and exclude the probe molecules outside, which are robust and unsusceptible to water-soluble metal cations. However, the shorter poly(acrylic acid) chains tend to form intermolecular hydrogen bonds, which are helpful in capturing more probe molecules inside the networks, thus inducing stronger emission. Because of the dual functions of forming hydrogen bonds with carboxylic groups and acting as an acceptor of protons from the carboxylic acid group to form cationic species, copolymerization with acrylate amide [poly(acrylic acid)-co-poly(acrylamide)] can greatly affect the chain dynamics of poly(acrylic acid) segments, which is reflected by the drastically decreased emission intensity from the fluorescent probes.展开更多
基金financially supported by Projects of the National Key Technology R&D Program of China(Nos.2013BAB02B01 and2013BAB02B03)the National Natural Science Foundation of China(Nos.51274055 and 51204030)+1 种基金the Fundamental Research Funds for the Central University of China(Nos.N130401006,N120801002 and N120701001)the Key Science&Technology Special Project of Third Five-Year Plan of MCC(No.0012012009)
文摘Aiming at evaluating the stability of a rock mass near a fault,a microseismic(MS) monitoring system was established in Hongtoushan copper mine.The distribution of displacement and log(/),the relationship between MS activity and the exploitation process,and the stability of the rock mass controlled by a fault were studied.The results obtained from microseismic data showed that MS events were mainly concentrated al the footwall of the fault.When the distance to the fault exceeded 20 m,the rock mass reached a relatively stable state.MS activity is closely related to the mining process.Under the strong disturbance from blasting,the initiation and propagation of cracks is much faster.MS activity belongs in the category of aftershocks after large scale excavation.The displacement and log(C/) obtained from MS events can reflect the difference in physical and mechanical behavior of different areas within the rock mass,which is useful in judging the integrity and degradation of the rock mass.
基金supported by the Natural Science Foundation of Zhejiang Province(2012C32007Z4110056)the National Basic Research Program of China(2013CB834704)
文摘We report here our results on the investigation of the chain dynamics of poly(acrylic acid) in aqueous solution. The concentration of poly(acrylic acid) was approximately 3.8×10^(-4) mol/L, two orders of magnitude higher than that reported in the literature. The p H value of the solution was 3.9, and the hydrogen bonds between the intrinsic and ionized carboxylic acid groups formed dynamic networks, which captured aggregation-induced emission-active molecules(a tetra-quaternary ammonium modified tetraphenylethene derivative) inside the polymer coils and induced fluorescence emission. The hydrogen bonds can be classified as intra- or intermolecular; both can be probed based on the emission change of the tetra-quaternary ammonium modified tetraphenylethene probes. The effects of different external stimuli on the polymer chain dynamics were investigated using different metal cations(including Na^+, Li^+, Zn^(2+), Ni^(2+), Ca^(2+), and Co^(2+)), different cation concentrations(1×10^(-6) to 4×10^(-4) mol/L), different poly(acrylic acid) molecular weights(5, 240, and 450 k Da), and different copolymers. The experimental results indicate that the long poly(acrylic acid) chains(high molecular weight) tend to form dense globular coils and exclude the probe molecules outside, which are robust and unsusceptible to water-soluble metal cations. However, the shorter poly(acrylic acid) chains tend to form intermolecular hydrogen bonds, which are helpful in capturing more probe molecules inside the networks, thus inducing stronger emission. Because of the dual functions of forming hydrogen bonds with carboxylic groups and acting as an acceptor of protons from the carboxylic acid group to form cationic species, copolymerization with acrylate amide [poly(acrylic acid)-co-poly(acrylamide)] can greatly affect the chain dynamics of poly(acrylic acid) segments, which is reflected by the drastically decreased emission intensity from the fluorescent probes.
