In the present study, the effects of operating conditions on biocatalytic activity and stability of Novozym 435 for repeated-batch biodiesel production from free fatty acid (FFA) were investigated. Thermal deactivat...In the present study, the effects of operating conditions on biocatalytic activity and stability of Novozym 435 for repeated-batch biodiesel production from free fatty acid (FFA) were investigated. Thermal deactivation caused by increased operating temperature from 45 to 50 ℃ could seriously affect the reusability of Novozym 435. The deactivation of Novozym 435 during the esterification of oleic acid with ethanol tended to be stronger than that in the system with methanol. Under the optimal conditions, considering both biocatalytic activity and stability of the enzyme, Novozym 435 could be reused for 13 cycles for biodiesel productions from oleic acid and absolute alcohols (methanol and ethanol) with FFA conversions of at least 90%. The presence of 4%-5% water in ethanol significantly affected the reusability of Novozym 435. Changes in the surface morphology of Novozym 435 during the esterification with various conditions were observed. It was revealed that the reduction in catalytic activity was related to the swelling degree of the catalyst surface, Additionally, biodiesel production from low cost renewable feedstocks, such as palm fatty acid distillate (PFAD) and 95% ethanol was examined, The esterification of PFAD with 95% ethanol catalyzed by Novozym 435 in 10-repeated batch operation showed the similar results in FFA conversion as compared to those using oleic acid. Novozym 435 remained active and could maintain 97.6% of its initial conversion after being used for 10 hatches.展开更多
This paper aims to analyze the Scientific Initiation (SI) as public policy of higher education in Brazil, from meanings and peculiarities of this device in the undergraduate academic's formation, created jointly wi...This paper aims to analyze the Scientific Initiation (SI) as public policy of higher education in Brazil, from meanings and peculiarities of this device in the undergraduate academic's formation, created jointly with the National Research Council in 1951 currently National Council for Scientific and Technological Development (CNPq). This corporation emerged from the recognition of the strategic importance of science and necessity of institutionalization of encouragement and fostering research. This is a theoretical bibliographical study and documentary that evidences the contributions and limits of SI while political science training should be part of academic activities to provide the development and support of investigative spirit. The concept of SI was established in universities as an activity to be developed in order to encourage the student to become familiar with scientific practices. The study concluded that SI is based on institutionalized norms within higher education to foster the development of science, and it is considered as an important strategy of expansion of graduate studies in Brazil.展开更多
E-commerce refers to a kind of business and trade activities, which are conducted under the situation that buyers and sellers do not meet each other by using a fast, easy and low-cost way. Along with the promotion and...E-commerce refers to a kind of business and trade activities, which are conducted under the situation that buyers and sellers do not meet each other by using a fast, easy and low-cost way. Along with the promotion and application of computer office automation, it is necessary for e-commerce module to develop towards automation, in which the core lies in making a good design for operation module. In this paper, the promotion of e-commerce in the information age is reviewed by the authors, the unique characteristics of e-commerce functional modules are analyzed, and also the most important point of the design of e-commerce automatic operation module is discussed. Hopefully, helps can be provided for relevant follow-up studies in the future.展开更多
Pd-only three-way catalyst (TWC), Pd supported on washcoating (the mixture of alumina and Ce-Zr solid solution)/cordierite, was prepared and its catalytic performance and the operation window (2-value) at 450 ℃...Pd-only three-way catalyst (TWC), Pd supported on washcoating (the mixture of alumina and Ce-Zr solid solution)/cordierite, was prepared and its catalytic performance and the operation window (2-value) at 450 ℃ were evaluated with the simulated automotive exhaust feed gas. Surfactants such as Tween-80 and Span-20 were added in the process of preparing the catalyst in order to improve the thermal stability and catalytic performance of Pd-only TWC. The fresh and aged catalysts at 1000 ℃ for 4 h were characterized by low-temperature N2 adsorption, XRD, XPS, and H2-TPR techniques. The results show that the presence of surfactants in the synthesis slurry could influence the physicochemical properties of the final Pd-only TWC. The FTS catalyst prepared with the mixed surfactant of Tween-80 and Span-20 exhibited excellent three-way catalytic performance. After being aged at 1000℃ for 4 h, the catalytic performances of Pd-only TWCs slightly decreased, but the FTS catalyst still demonstrated higher catalytic performance and better thermal stability compared with the Pd-only catalysts prepared with single surfactant or without any surfactant. And the FTS catalyst has a wider 2 value (operation window) than other catalysts, even after being aged at 1000℃.展开更多
基金the National Research Council of Thailand (NRCT) for financial supportthe 90th anniversary of Chulalongkorn University (Ratchadaphiseksomphot Endowment Fund)
文摘In the present study, the effects of operating conditions on biocatalytic activity and stability of Novozym 435 for repeated-batch biodiesel production from free fatty acid (FFA) were investigated. Thermal deactivation caused by increased operating temperature from 45 to 50 ℃ could seriously affect the reusability of Novozym 435. The deactivation of Novozym 435 during the esterification of oleic acid with ethanol tended to be stronger than that in the system with methanol. Under the optimal conditions, considering both biocatalytic activity and stability of the enzyme, Novozym 435 could be reused for 13 cycles for biodiesel productions from oleic acid and absolute alcohols (methanol and ethanol) with FFA conversions of at least 90%. The presence of 4%-5% water in ethanol significantly affected the reusability of Novozym 435. Changes in the surface morphology of Novozym 435 during the esterification with various conditions were observed. It was revealed that the reduction in catalytic activity was related to the swelling degree of the catalyst surface, Additionally, biodiesel production from low cost renewable feedstocks, such as palm fatty acid distillate (PFAD) and 95% ethanol was examined, The esterification of PFAD with 95% ethanol catalyzed by Novozym 435 in 10-repeated batch operation showed the similar results in FFA conversion as compared to those using oleic acid. Novozym 435 remained active and could maintain 97.6% of its initial conversion after being used for 10 hatches.
文摘This paper aims to analyze the Scientific Initiation (SI) as public policy of higher education in Brazil, from meanings and peculiarities of this device in the undergraduate academic's formation, created jointly with the National Research Council in 1951 currently National Council for Scientific and Technological Development (CNPq). This corporation emerged from the recognition of the strategic importance of science and necessity of institutionalization of encouragement and fostering research. This is a theoretical bibliographical study and documentary that evidences the contributions and limits of SI while political science training should be part of academic activities to provide the development and support of investigative spirit. The concept of SI was established in universities as an activity to be developed in order to encourage the student to become familiar with scientific practices. The study concluded that SI is based on institutionalized norms within higher education to foster the development of science, and it is considered as an important strategy of expansion of graduate studies in Brazil.
文摘E-commerce refers to a kind of business and trade activities, which are conducted under the situation that buyers and sellers do not meet each other by using a fast, easy and low-cost way. Along with the promotion and application of computer office automation, it is necessary for e-commerce module to develop towards automation, in which the core lies in making a good design for operation module. In this paper, the promotion of e-commerce in the information age is reviewed by the authors, the unique characteristics of e-commerce functional modules are analyzed, and also the most important point of the design of e-commerce automatic operation module is discussed. Hopefully, helps can be provided for relevant follow-up studies in the future.
基金financially supported by the National Basic Research Program of China(2010CB732300)the National Natural Science Foundation of China(21273150)the National High Technology Research and Development Program of China(2011AA03A406)
文摘Pd-only three-way catalyst (TWC), Pd supported on washcoating (the mixture of alumina and Ce-Zr solid solution)/cordierite, was prepared and its catalytic performance and the operation window (2-value) at 450 ℃ were evaluated with the simulated automotive exhaust feed gas. Surfactants such as Tween-80 and Span-20 were added in the process of preparing the catalyst in order to improve the thermal stability and catalytic performance of Pd-only TWC. The fresh and aged catalysts at 1000 ℃ for 4 h were characterized by low-temperature N2 adsorption, XRD, XPS, and H2-TPR techniques. The results show that the presence of surfactants in the synthesis slurry could influence the physicochemical properties of the final Pd-only TWC. The FTS catalyst prepared with the mixed surfactant of Tween-80 and Span-20 exhibited excellent three-way catalytic performance. After being aged at 1000℃ for 4 h, the catalytic performances of Pd-only TWCs slightly decreased, but the FTS catalyst still demonstrated higher catalytic performance and better thermal stability compared with the Pd-only catalysts prepared with single surfactant or without any surfactant. And the FTS catalyst has a wider 2 value (operation window) than other catalysts, even after being aged at 1000℃.