The relatedness between catalytic effect of activated carbon and passivation phenomenon during chalcopyrite bioleachingby mixed thermophilic Archaea culture(Acidianus brierleyi,Metallosphaera sedula,Acidianus manzaens...The relatedness between catalytic effect of activated carbon and passivation phenomenon during chalcopyrite bioleachingby mixed thermophilic Archaea culture(Acidianus brierleyi,Metallosphaera sedula,Acidianus manzaensis and Sulfolobusmetallicus)at65°C was studied.Leaching experiments showed that the addition of activated carbon could significantly promote thedissolution of chalcopyrite for both bioleaching and chemical leaching.The results of synchrotron-based X-ray diffraction,ironL-edge and sulfur K-edge X-ray absorption near edge structure spectroscopy indicated that activated carbon could change thetransition path of electrons through galvanic interactions to form more readily dissolved secondary mineral chalcocite at a low redoxpotential(?400mV)and then enhanced the copper dissolution.Jarosite accumulated immediately in the initial stage of bioleachingwith activated carbon but copper dissolution was not hindered.However,much jarosite precipitated on the surface of chalcopyrite inthe late stage of bioleaching,which might account for the decrease of copper dissolution rate.More elemental sulfur(S0)was alsodetected with additional activated carbon but the mixed thermophilic Archaea culture had a great sulfur oxidation activity,thus S0waseliminated and seemed to have no significant influence on the dissolution of chalcopyrite.展开更多
The characteristic of coal spontaneous combustion includes oxidative property and exothermic capacity. It can really simulate the process of coal spontaneous combustion to use the large scale experimental unit loading...The characteristic of coal spontaneous combustion includes oxidative property and exothermic capacity. It can really simulate the process of coal spontaneous combustion to use the large scale experimental unit loading coal 1 000 kg. According to the field change of gas concentration and coal temperature determined through experiment of coal self ignite at low temperature stage, and on the basis of hydromechanics and heat transfer theory, some parameters can be calculated at different low temperature stage, such as, oxygen consumption rate, heat liberation intensity. It offers a theoretic criterion for quantitatively analyzing characteristic of coal self ignite and forecasting coal spontaneous combustion. According to coal exothermic capability and its thermal storage surroundings, thermal equilibrium is applied to deduce the computational method of limit parameter of coal self ignite. It offers a quantitative theoretic criterion for coal self ignite forecasting and preventing. According to the measurement and test of spontaneous combustion of Haibei coal, some token parameter of Haibei coal spontaneous combustion is quantitatively analyzed, such as, spontaneous combustion period of coal, critical temperature, oxygen consumption rate, heat liberation intensity, and limit parameter of coal self ignite.展开更多
基金Project(51274257) supported by the National Natural Science Foundation of ChinaProject(U1232103) supported by the Joint Funds of National Natural Science Foundation of China and Large Scientific Facility Foundation of Chinese Academy of Sciences+1 种基金Project(VR-12419) supported by the Beijing Synchrotron Radiation Facility Public User Program,ChinaProject(15ssrf00924) supported by the Shanghai Institute of Applied Physics Open Fund of Shanghai Synchrotron Radiation Facility,China
文摘The relatedness between catalytic effect of activated carbon and passivation phenomenon during chalcopyrite bioleachingby mixed thermophilic Archaea culture(Acidianus brierleyi,Metallosphaera sedula,Acidianus manzaensis and Sulfolobusmetallicus)at65°C was studied.Leaching experiments showed that the addition of activated carbon could significantly promote thedissolution of chalcopyrite for both bioleaching and chemical leaching.The results of synchrotron-based X-ray diffraction,ironL-edge and sulfur K-edge X-ray absorption near edge structure spectroscopy indicated that activated carbon could change thetransition path of electrons through galvanic interactions to form more readily dissolved secondary mineral chalcocite at a low redoxpotential(?400mV)and then enhanced the copper dissolution.Jarosite accumulated immediately in the initial stage of bioleachingwith activated carbon but copper dissolution was not hindered.However,much jarosite precipitated on the surface of chalcopyrite inthe late stage of bioleaching,which might account for the decrease of copper dissolution rate.More elemental sulfur(S0)was alsodetected with additional activated carbon but the mixed thermophilic Archaea culture had a great sulfur oxidation activity,thus S0waseliminated and seemed to have no significant influence on the dissolution of chalcopyrite.
基金ThearticlesupportedfinanciallybyNationalNaturalScienceFoundationofChina (No .5 99740 2 0 )andSpecialFoundationofShaanxiEdu cationCommittee (No .99Jk2 2 0 )
文摘The characteristic of coal spontaneous combustion includes oxidative property and exothermic capacity. It can really simulate the process of coal spontaneous combustion to use the large scale experimental unit loading coal 1 000 kg. According to the field change of gas concentration and coal temperature determined through experiment of coal self ignite at low temperature stage, and on the basis of hydromechanics and heat transfer theory, some parameters can be calculated at different low temperature stage, such as, oxygen consumption rate, heat liberation intensity. It offers a theoretic criterion for quantitatively analyzing characteristic of coal self ignite and forecasting coal spontaneous combustion. According to coal exothermic capability and its thermal storage surroundings, thermal equilibrium is applied to deduce the computational method of limit parameter of coal self ignite. It offers a quantitative theoretic criterion for coal self ignite forecasting and preventing. According to the measurement and test of spontaneous combustion of Haibei coal, some token parameter of Haibei coal spontaneous combustion is quantitatively analyzed, such as, spontaneous combustion period of coal, critical temperature, oxygen consumption rate, heat liberation intensity, and limit parameter of coal self ignite.
