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萘氧化制苯酐催化剂活性微区模型的探讨 被引量:2
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作者 段世铎 林强 +1 位作者 杨晓军 刘慧英 《宁夏大学学报(自然科学版)》 CAS 1996年第3期74-75,87,共3页
萘氧化制苯酐催化剂活性微区模型的探讨*段世铎林强杨晓军刘慧英(天津大学化学系,300072,天津)(宁夏大学化学系,750021,宁夏银川)关键词萘制苯酐;催化剂;活性微区萘氧化制取邻苯二甲酸酐是典型的选择性多相催化... 萘氧化制苯酐催化剂活性微区模型的探讨*段世铎林强杨晓军刘慧英(天津大学化学系,300072,天津)(宁夏大学化学系,750021,宁夏银川)关键词萘制苯酐;催化剂;活性微区萘氧化制取邻苯二甲酸酐是典型的选择性多相催化氧化反应,历史上研究甚早.以往有关... 展开更多
关键词 苯酐 催化剂 活性微区 氧化 邻苯二甲酸酐
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钒系催化剂表面活性微区结构的量子化学计算
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作者 冯霞 段世铎 耿志刚 《天津大学学报》 EI CAS CSCD 1998年第3期373-375,共3页
采用经过修改的MOAB从头计算程序在微机上完成了样本-萘氧化制苯酐钒系催化剂的表面活性微区基本结构的量子化学计算.确定了基本单元的形式及可见结构,同时得到了体系的波函数.
关键词 从头计算法 钒系催化剂 表面结构 活性微区
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钒系催化剂表面结构及活性微区模型的研究
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作者 段世铎 冯霞 韩顺路 《宁夏大学学报(自然科学版)》 CAS 1997年第3期248-251,270,共5页
运用XPS,IR和LRS等手段,对萘氧化制苯酐钒系催化剂的表面组成和结构的联合分析结果表明:催化剂表面各元素以VKSO=12210的比例存在;催化剂以V2O5为基本骨架,形成了VO(SO4)2-及S2O72-的配位形式。
关键词 钒系催化剂 表面结构 活性微区 XPS IR LRS
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Soil vanadium pollution and microbial response characteristics from stone coal smelting district 被引量:8
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作者 肖细元 杨淼 +3 位作者 郭朝晖 姜智超 刘亚男 曹霞 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第4期1271-1278,共8页
A field investigation was performed to study the content, speciation and mobility of vanadium, as well as microbial response in soil from a stone coal smelting district in Hunan province of China. The results showed t... A field investigation was performed to study the content, speciation and mobility of vanadium, as well as microbial response in soil from a stone coal smelting district in Hunan province of China. The results showed that the contents of soil V ranged from 168 to 1538 mg/kg, which exceeded the maximum permissible value of Canadian soil quality for V. The mean soil V content from wasteland area reached 1421 mg/kg, and those from the areas related with slag heap, ore pile and smelting center were 380, 260 and 225 mg/kg, respectively. Based on the results of the modified BCR sequential extraction procedure, V contents in the mobile fractions varied from 19.2 to 637 mg/kg accounting for 7.4%-42.3% of total V, and those of V(+5) species were between 21.9 and 534.0 mg/kg. Soil enzyme activity and microbial basal respiration were adversely affected by high level of soil V. More attention should be paid to soil V pollution and potential hazardous surrounding the stone coal smelting district. 展开更多
关键词 VANADIUM soil pollution MOBILITY microbial response stone coal smelting district
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Effects of Different Land Use Patterns on Soil Microbial Quantity and Activity in Hongta District,Yuxi City 被引量:1
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作者 陈艳 刘家忠 何倩倩 《Agricultural Science & Technology》 CAS 2016年第11期2535-2538,共4页
[Objective] This study aimed to investigate the effects of different land use patterns on soil ecological environment. [Method] Total three representative land use patterns (corn field, cherry tree land, wood land) ... [Objective] This study aimed to investigate the effects of different land use patterns on soil ecological environment. [Method] Total three representative land use patterns (corn field, cherry tree land, wood land) were selected from Hongta District, Yuxi City, and under these three patterns, soil microbial quantity and activity were studied. [Result] Under the three land use patterns, soil microorganisms were domi- nated by bacteria; soil microbial quantity ranked as wood land's〉cheery tree land's〉 corn field's; and total microbial activity, catalase activity and urease activity all ranked as cherry tree land's〉wood land's〉corn field's. [Conclusion] Soil microbial activity and functions are related to farmland management measures, as well as land use pattern and soil nutrients. 展开更多
关键词 Land use pattern Total quantity of microorganisms Microbial activity Hongta District of Yuxi City
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Effects of Different Vegetable Planting Modes on Soil Microbial Flora and Enzyme Activity 被引量:1
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作者 孟平红 肖厚军 +4 位作者 郭惊涛 蔡霞 潘德怀 付纪勇 李桂莲 《Agricultural Science & Technology》 CAS 2015年第10期2265-2268,2272,共5页
To investigate the effects of different vegetable growing regions and planting modes on soil quality,soils in high,medium and low altitude areas of Guizhou were respectively sampled under different vegetable efficient... To investigate the effects of different vegetable growing regions and planting modes on soil quality,soils in high,medium and low altitude areas of Guizhou were respectively sampled under different vegetable efficient planting modes,and the variations of soil microbial flora and enzyme activities were analyzed. The soil microbial count and total bacteria of the vegetable efficient cultivation mode were significantly higher than that of the control (traditional planting mode) in each planting area,and the microbial diversity index was also improved to varying de- grees.The soil phosphatase,catalase and urease activities of the vegetable efficient planting mode were higher than that of the control.The soil catalase and urease activities were higher than that of the control by 1.37-1.44 and 1.51-2.80 times. Application of vegetable efficient planting mode in different regions will help to im- prove the soil quality in a given period. 展开更多
关键词 VEGETABLE Efficient planting mode Growing region Soil microbial flora Soil enzyme activity Biodiversity index
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