The diblock copolymers of methyl acrylate and perfluoroalkyl ethyl acrylate(FAEA) were synthesized by atom transfer radical polymerization (ATRP).GPC, 1H-NMR and fluorine-elementary analysis (F-EA) were used to study ...The diblock copolymers of methyl acrylate and perfluoroalkyl ethyl acrylate(FAEA) were synthesized by atom transfer radical polymerization (ATRP).GPC, 1H-NMR and fluorine-elementary analysis (F-EA) were used to study the structure of the block copolymers.To combine GPC with NMR and to combine GPC with F-EA were used to calculate the block length.It was found interestingly that the results of 1H-NMR showed a “temperature-dependent" feature.It means the relative ratios of MA block to FAEA block calculated from NMR were changed with measuring temperature.It might be caused by the formation of molecular association.Temperature and solvents can affect the degree of association.Therefore, 1H-NMR and GPC can’t be used in quantitative analysis of the fluorinated diblock copolymer.To combine GPC with F-EA is suitable for the characterization of fluorinated diblock copolymers.展开更多
文摘The diblock copolymers of methyl acrylate and perfluoroalkyl ethyl acrylate(FAEA) were synthesized by atom transfer radical polymerization (ATRP).GPC, 1H-NMR and fluorine-elementary analysis (F-EA) were used to study the structure of the block copolymers.To combine GPC with NMR and to combine GPC with F-EA were used to calculate the block length.It was found interestingly that the results of 1H-NMR showed a “temperature-dependent" feature.It means the relative ratios of MA block to FAEA block calculated from NMR were changed with measuring temperature.It might be caused by the formation of molecular association.Temperature and solvents can affect the degree of association.Therefore, 1H-NMR and GPC can’t be used in quantitative analysis of the fluorinated diblock copolymer.To combine GPC with F-EA is suitable for the characterization of fluorinated diblock copolymers.
文摘以α 溴代丙酸乙酯为小分子引发剂、氯化亚铜和联二吡啶组成的混合体系为催化剂,引发苯乙烯单体聚合,得到端基为卤原子的单分散PS X预聚体。并以此为大分子引发剂、氯化亚铜和N,N,N′,N″,N 五甲基二亚乙基三胺/联二吡啶组成的混合体系为催化剂,引发聚合甲基丙烯酸叔丁酯,得到相对分子质量可控、分子质量分布狭窄的聚苯乙烯 b 聚甲基丙烯酸叔丁酯嵌段共聚物.最后使该共聚物在酸性条件下水解,从而得到了两亲性的嵌段共聚物聚苯乙烯 b 聚甲基丙烯酸.用红外光谱仪、核磁共振仪、凝胶色谱仪等对产物的结构与性能进行了表征.
