A modified Swift type flow stress—strain relation was presented in order to describe the uniaxial tension test curve reasonably. The FLD-strain （forming limit diagram made up of limit strain） of 5754O aluminum allo...A modified Swift type flow stress—strain relation was presented in order to describe the uniaxial tension test curve reasonably. The FLD-strain （forming limit diagram made up of limit strain） of 5754O aluminum alloy sheet was calculated based on the two flow stress—strain relations using Yld2000-2d yield function. By comparing the theoretical and experimental results, it is found that the calculated FLD-strain based on the modified Swift flow stress—strain relation can reasonably describe the experimental results. However, though the common Voce flow stress—strain relation can describe the deformation behavior during homogenous deformation phase accurately, the FLD-strain calculated based on it is obviously lower than the experimental result. It is concluded that the higher the hardening rate of sheet metal is, the higher the forming limit is. A method for determining the reasonable flow stress—strain relation is recommended for describing the material behavior during inhomogenous phase and the forming limit of sheet metal.展开更多
Rotating disk electrode systems are widely used to study the kinetics of electrocatalytic reactions that may suffer from insufficient mass transfer of the reactants.Kinetic current density at certain overpotential cal...Rotating disk electrode systems are widely used to study the kinetics of electrocatalytic reactions that may suffer from insufficient mass transfer of the reactants.Kinetic current density at certain overpotential calculated by the Koutecky-Levich equation is commonly used as the metrics to evaluate the activity of electrocatalysts.However,it is frequently found that the diffusion limiting current density is not correctly identified in the literatures.Instead of kinetic current density,the measured current density normalized by diffusion limiting current density(j/jL)has also been frequently under circumstance where its validity is not justified.By taking oxygen reduction reaction/hydrogen oxidation reaction/hydrogen evolution reaction as examples,we demonstrate that identifying the actual diffusion limiting current density for the same reaction under otherwise identical conditions from the experimental data is essential to accurately deduce kinetic current density.Our analysis reveals that j/jLis a rough activity metric which can only be used to qualitatively compare the activity trend under conditions that the mass transfer conditions and the roughness factor of the electrode are exactly the same.In addition,if one wants to use j/jLto compare the intrinsic activity,the concentration overpotential should be eliminated.展开更多
Based on 3D, steady N-S equations and k-e turbulence model, Fluent was employed to do numerical simulation for lateral aerodynamic performance of 6-axis X2K double-deck container trains with two different loading form...Based on 3D, steady N-S equations and k-e turbulence model, Fluent was employed to do numerical simulation for lateral aerodynamic performance of 6-axis X2K double-deck container trains with two different loading forms, and speed limits of the freight trains were studied. The result indicates that under wind environment： 1） As for vehicles without and with cross-loaded structure, aero-pressure on the former is bigger, but air velocity around the latter is larger; 2） When sideslip angle θ=0°, the airflow is symmetry about train vertical axis; when θ〉0°, the airflow is detached at the top of vehicles, and the air velocity increases above the separated line but decreases below it; 3） With θ increasing, the lateral force on the mid vehicle firstly increases but decreases as θ=75°; 4） When the 6-axis X2K fiat car loads empty boxes of a 40 ft and a 48 ft at 120 km/h, the overturning wind speed is 25.19 m/s, and the train should be stopped under the 12th grade wind speed.展开更多
In the paper we consider a wide class of slow-fast second order systems and give sufficient conditions for the existence of a singular limit cycle related to a homoclinic orbit.
The Fleming-Viot process with parent-independent mutation process is one particular neutral pop- ulation genetic model. As time goes by, some initial species are replaced by mutated ones gradually. Once the population...The Fleming-Viot process with parent-independent mutation process is one particular neutral pop- ulation genetic model. As time goes by, some initial species are replaced by mutated ones gradually. Once the population mutation rate is high, mutated species will elbow out all the initial species very quickly. Small-time behavior in thls case seems to be the key to understand this fast transition. The small-time asymptotic results related to time scale t and a（O）t, where lim0→∞θ θa（θ） = O, are obtained by Dawson and Shni （1998, 2001）, Shui and Xiong （2002）, and Xiang and Zhang （2005）, respectively. Only the behavior under the scale t（θ）, where limθ→∞θt（θ） = 0 and limθ→∞（O） =∞ was left untouched. In this paper, the weak limits under various small-time scales are obtained. Of particular interest is the large deviations for the small-time transient sam- pling distributions, which reveal interesting phase transition. Interestingly, such a phase transition is uniquely determined by some species diversity indices.展开更多
基金Project(51005010)supported by the National Natural Science Foundation of China
文摘A modified Swift type flow stress—strain relation was presented in order to describe the uniaxial tension test curve reasonably. The FLD-strain （forming limit diagram made up of limit strain） of 5754O aluminum alloy sheet was calculated based on the two flow stress—strain relations using Yld2000-2d yield function. By comparing the theoretical and experimental results, it is found that the calculated FLD-strain based on the modified Swift flow stress—strain relation can reasonably describe the experimental results. However, though the common Voce flow stress—strain relation can describe the deformation behavior during homogenous deformation phase accurately, the FLD-strain calculated based on it is obviously lower than the experimental result. It is concluded that the higher the hardening rate of sheet metal is, the higher the forming limit is. A method for determining the reasonable flow stress—strain relation is recommended for describing the material behavior during inhomogenous phase and the forming limit of sheet metal.
基金supported by the National Natural Science Foundation of China(No.91545124,No.21972131,and No.21832004)。
文摘Rotating disk electrode systems are widely used to study the kinetics of electrocatalytic reactions that may suffer from insufficient mass transfer of the reactants.Kinetic current density at certain overpotential calculated by the Koutecky-Levich equation is commonly used as the metrics to evaluate the activity of electrocatalysts.However,it is frequently found that the diffusion limiting current density is not correctly identified in the literatures.Instead of kinetic current density,the measured current density normalized by diffusion limiting current density(j/jL)has also been frequently under circumstance where its validity is not justified.By taking oxygen reduction reaction/hydrogen oxidation reaction/hydrogen evolution reaction as examples,we demonstrate that identifying the actual diffusion limiting current density for the same reaction under otherwise identical conditions from the experimental data is essential to accurately deduce kinetic current density.Our analysis reveals that j/jLis a rough activity metric which can only be used to qualitatively compare the activity trend under conditions that the mass transfer conditions and the roughness factor of the electrode are exactly the same.In addition,if one wants to use j/jLto compare the intrinsic activity,the concentration overpotential should be eliminated.
基金Project supported by Scholarship Award for Excellent Doctoral Student granted by Ministry of Education,ChinaProject(2012QNZT029) supported by the Fundamental Research Funds for the Central Universities of China+1 种基金Project(CX2010B122) supported by Hunan Provincial Innovation Foundation for Postgraduate,ChinaProject(2010ybfz088) supported by the Foundation of Excellent Doctoral Dissertation of Central South University,China
文摘Based on 3D, steady N-S equations and k-e turbulence model, Fluent was employed to do numerical simulation for lateral aerodynamic performance of 6-axis X2K double-deck container trains with two different loading forms, and speed limits of the freight trains were studied. The result indicates that under wind environment： 1） As for vehicles without and with cross-loaded structure, aero-pressure on the former is bigger, but air velocity around the latter is larger; 2） When sideslip angle θ=0°, the airflow is symmetry about train vertical axis; when θ〉0°, the airflow is detached at the top of vehicles, and the air velocity increases above the separated line but decreases below it; 3） With θ increasing, the lateral force on the mid vehicle firstly increases but decreases as θ=75°; 4） When the 6-axis X2K fiat car loads empty boxes of a 40 ft and a 48 ft at 120 km/h, the overturning wind speed is 25.19 m/s, and the train should be stopped under the 12th grade wind speed.
基金Natural Science Foundation of Anhui Education Committee(2000J1008)
文摘In the paper we consider a wide class of slow-fast second order systems and give sufficient conditions for the existence of a singular limit cycle related to a homoclinic orbit.
基金supported by Fundamental Research Fund of Zhongnan University of Economics and Law (Grant No. 31541411208)
文摘The Fleming-Viot process with parent-independent mutation process is one particular neutral pop- ulation genetic model. As time goes by, some initial species are replaced by mutated ones gradually. Once the population mutation rate is high, mutated species will elbow out all the initial species very quickly. Small-time behavior in thls case seems to be the key to understand this fast transition. The small-time asymptotic results related to time scale t and a（O）t, where lim0→∞θ θa（θ） = O, are obtained by Dawson and Shni （1998, 2001）, Shui and Xiong （2002）, and Xiang and Zhang （2005）, respectively. Only the behavior under the scale t（θ）, where limθ→∞θt（θ） = 0 and limθ→∞（O） =∞ was left untouched. In this paper, the weak limits under various small-time scales are obtained. Of particular interest is the large deviations for the small-time transient sam- pling distributions, which reveal interesting phase transition. Interestingly, such a phase transition is uniquely determined by some species diversity indices.
