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二元流动相液相色谱体系中一个新的三参数溶质保留方程(英文)
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作者 边六交 杨晓燕 《西北大学学报(自然科学版)》 CAS CSCD 北大核心 2004年第5期577-582,共6页
目的 建立一个新的描述溶质在二元流动相液相色谱体系中保留的三参数方程并以实验进行验证。方法 通过研究液相色谱体系中溶质分子和溶剂或稀释剂分子的相互作用 ,得到一个溶质在液相色谱体系中保留的三参数方程 ,并用不同极性的溶质... 目的 建立一个新的描述溶质在二元流动相液相色谱体系中保留的三参数方程并以实验进行验证。方法 通过研究液相色谱体系中溶质分子和溶剂或稀释剂分子的相互作用 ,得到一个溶质在液相色谱体系中保留的三参数方程 ,并用不同极性的溶质分子的甲醇 水、乙腈 水和四氢呋喃 水反相色谱体系和极低流动相浓度下的正相色谱体系对此方程进行了验证。结果 在全浓度流动相范围内 ,实验数据均能用此方程良好描述 ,且保留方程中的 3个参数与所研究的色谱体系的特征紧密相关。 展开更多
关键词 保留方程 二元流动相体系 色谱
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反相离子抑制色谱法分离对位酯 被引量:5
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作者 郑伟 闵长春 谭春伟 《化工科技》 CAS 2002年第4期34-36,共3页
采用UV VISSepetrophotometric检测器 ,用RP -C18反相柱对合成对位酯各步反应产物进行了分离。选择不同的流动相体系 ,通过实验确定了最佳的色谱分离测试条件。
关键词 分离 对位酯 离子抑制色谱 流动相体系 对氨基苯基-β-羟乙基砜硫酸酯 染料中间
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Study on the Phase Equilibria of Hard Core Asakura-Oosawa Fluids with Renormalization-group Theory
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作者 付东 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2004年第4期463-469,共7页
An analytical equation of state (EOS) for hard core Asakura-Oosawa (AO) fluid is established by combining the AO potential, the first-order perturbation theory and the radial distribution function (RDF) for the hard s... An analytical equation of state (EOS) for hard core Asakura-Oosawa (AO) fluid is established by combining the AO potential, the first-order perturbation theory and the radial distribution function (RDF) for the hard sphere fluid.The phase equilibria are studied by using the renormalization-group (RG) theory. The obtained results agree well with the simulation data. Investigation shows that the attractive range parameter plays an important role in the phase equilibria for AO fluid. 展开更多
关键词 Asakura-Oosawa fluid equation of state phase equilibria renormalization-group theory
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CFD aided investigation of single droplet coalescence 被引量:2
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作者 Felix Gebauer Mark W.Hlawitschka Hans-Jorg Bart 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2016年第2期249-252,共4页
This article describes the development of a coalescence model using various CFD work packages,and is validated using as toluene water model system.Numerical studies were performed to describe droplet interactions in l... This article describes the development of a coalescence model using various CFD work packages,and is validated using as toluene water model system.Numerical studies were performed to describe droplet interactions in liquid–liquid test systems.Current models use adjustable parameters to describe these phenomena.The research in the past decades led to different correlations to model coalescence and breakage depending on the chemical system and the apparatus geometry.Especially the complexity of droplet coalescence requires a detailed investigation of local phenomena during the droplet interaction.Computational fluid dynamics(CFD) studies of single droplet interactions were performed and validated with experimental results to improve the understanding of the local hydrodynamics and film drainage during coalescence.The CFD simulations were performed for the interaction of two differently sized droplets at industrial relevant impact velocities.The experimental verification and validation of the numerical results were done with standardized high-speed imaging studies by using a special test cell with a pendant and a free rising droplet.An experimental based algorithm was implemented in the open source code OpenF OAM to account for the contact time and the dimple formation.The standard European Federation of Chemical Engineering(EFCE) test system toluene/water was used for the numerical studies and the experimental investigations as well.The results of the CFD simulations are in good accordance with the observed coalescence behavior in the experimental studies.In addition,a detailed description of local phenomena,like film rupture,velocity gradients,pressures and micro-droplet entrainment could be obtained. 展开更多
关键词 CFD Parameter estimation COALESCENCE Film drainage
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Corona-Support for the Entirety of High Energetic Disk
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作者 Krasimira Dimitrova Yankova 《Journal of Earth Science and Engineering》 2012年第7期395-400,共6页
Based on results obtained from the study for MHD (magneto-hydrodynamics) of advective accretion disk, which are applied to real source showing typical values for CBS (close binary star-system), it will investigate... Based on results obtained from the study for MHD (magneto-hydrodynamics) of advective accretion disk, which are applied to real source showing typical values for CBS (close binary star-system), it will investigate on self-structuring in the disk under the impact of the distribution of leading parameters (density, velocity ...). The paper is considering the problem of development of the corona and will analyze the process of interaction of the plasma with the magnetic field in connection to support for the instabilities. 展开更多
关键词 Accretion disk advection MHD (magneto-hydrodynamics) instabilities.
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