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聚丙烯酸十八酯-乙酸乙烯酯梳状二元共聚物降凝剂对含蜡原油结晶特性与流变性的影响 被引量:11
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作者 杨飞 肖作曲 +3 位作者 姚博 李传宪 孙广宇 阎孔尧 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2016年第7期1395-1401,共7页
在合成聚丙烯酸十八酯(POA)梳状均聚物和聚丙烯酸十八酯-乙酸乙烯酯(POA-VA)系列梳状二元共聚物的基础上,通过凝点测量、流变实验、差示扫描量热(DSC)分析及偏光显微镜观察等手段研究了POA与POA-VA对长庆含蜡原油结晶特性与流变性的影响... 在合成聚丙烯酸十八酯(POA)梳状均聚物和聚丙烯酸十八酯-乙酸乙烯酯(POA-VA)系列梳状二元共聚物的基础上,通过凝点测量、流变实验、差示扫描量热(DSC)分析及偏光显微镜观察等手段研究了POA与POA-VA对长庆含蜡原油结晶特性与流变性的影响.实验结果表明VA基团的引入调控了POA降凝剂对含蜡原油的作用效果.当OA与VA单体摩尔比为3∶1时,POA-VA对含蜡原油的流变改善效果最好,在降凝剂400 mg/kg剂量下可以降低凝点22℃,平均降黏率为51.45%;而单体摩尔比升高或降低均会使POA-VA对含蜡原油的流变改善效果变差.另外,从POA-VA分子的结晶放热特性和蜡晶微观形貌分析角度,探讨了VA含量对POA-VA作用性能的影响规律和机理. 展开更多
关键词 含蜡原油 降凝剂 流变性测量 梳状聚合物 极性基团
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低密度聚乙烯熔体挤出胀大的实验和数值模拟预测 被引量:4
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作者 黄树新 江体乾 +1 位作者 鲁传敬 黄进 《上海交通大学学报》 EI CAS CSCD 北大核心 2003年第4期535-540,共6页
对一种国产低密度聚乙烯 ( LDPE)进行了经过长毛细管的挤出胀大流动实验测量 ,得到了挤出胀大比和流动曲线 .测定了材料的线性和非线性粘弹性 ,并用 PSM模型进行了表征 ,同时数值模拟了 LDPE熔体的挤出胀大流动 .预测结果与实验基本吻... 对一种国产低密度聚乙烯 ( LDPE)进行了经过长毛细管的挤出胀大流动实验测量 ,得到了挤出胀大比和流动曲线 .测定了材料的线性和非线性粘弹性 ,并用 PSM模型进行了表征 ,同时数值模拟了 LDPE熔体的挤出胀大流动 .预测结果与实验基本吻合 ,但在较高剪切速率下两者间还存在一定的偏差 。 展开更多
关键词 低密度聚乙烯 挤出胀大实验 流变性测量实验 PSM模型 数值模拟
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Study on the rheology of coal-oil slurries during heating at high pressure 被引量:4
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作者 Bingfeng Yan 《International Journal of Coal Science & Technology》 EI 2017年第3期274-280,共7页
Using the self-developed viscosity measuring device, the viscosity variations of coal-oil slurries with temperature increasing during coal-oil co-processing were studied. The results show that the viscosity of coal-oi... Using the self-developed viscosity measuring device, the viscosity variations of coal-oil slurries with temperature increasing during coal-oil co-processing were studied. The results show that the viscosity of coal-oil slurries prepared by different kinds of oil varies differently during heating. The viscosity of the coal-oil slurry prepared by the catalytic cracking slurry (FCC) generally decreases during heating. However, the viscosity of the coal-oil slurry prepared by the high-temperature coal tar (CT) will peak at 338 ℃ during heating. The differences in viscosity variations of coal-oil slurries are analyzed. In addition to the temperature, the properties of the solvents and coal are the main influencing factors. Because the used coal contains a large number of polar functional groups, the swelling behavior of the coal in polar solvent (CT) is stronger than that in non-polar solvent (FCC). The swelling effect of the coal can result in the appearance of the viscosity peak. Therefore, before 100 ~C, the solvent molecules entering into the coal pores is the main influencing factor of coal-oil slurries viscosity variations. After 100 ℃, the increasing of particle size of coal particles is the main influencing factor of coal-oil slurries viscosity variations. 展开更多
关键词 Coal-oil slurry · Rheology· Swelling · High temperature and pressure
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MEASUREMENT OF REGIONAL BONE BLOOD FLOW IN THE CANINE MANDIBULAR RAMUS USING RADIOLABELLED TOAD RED BLOOD CELLS 被引量:1
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作者 毛驰 王翰章 《Chinese Medical Sciences Journal》 CAS CSCD 1994年第2期87-90,共4页
Toad red blood cells were used to measure regional bone blood flow in the canine mandibular ramus. The blood cells were labelled with sodium pertechnetate and fixed in 1 0%formalin; they were 22 × 15 μm in size ... Toad red blood cells were used to measure regional bone blood flow in the canine mandibular ramus. The blood cells were labelled with sodium pertechnetate and fixed in 1 0%formalin; they were 22 × 15 μm in size and had a specific gravity close to that of dog red blood cells. These cells had no discernible effect on systemic hemodynamics after injection, did not agglutinate, were well mixed and evenly distributed throughout the body, and were completely extracted in one circulation through the mandible. The mandibular ramus was divided into six regions. and the blood flow rates in each were found to be similar to those reported in previous studies with radiolabelled carbonized, microspheres. Furthermore, the blood flow distribution pattern of the mandibular ramus determined in this study was identical to that of our previous study using the bone-seeking radionuclide method. We suggest that radiolabelled toad red blood cells are an ideal marker for measuring regional blood flow in the canine mandible. 展开更多
关键词 MANDIBLE blood flow RADIONUCLIDE
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Effect of Particle Phase Volume, Shape and Liquid Phase Concentrations on Rheological Properties of Large Particulate-Liquid Model Food Systems by Using Ball Measuring System
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作者 Chlharu Inoue Peter Versluis Pablo Coronel Johanna Maria Martina Elberse 《Journal of Chemistry and Chemical Engineering》 2013年第7期643-652,共10页
Rheological properties of large particulate-liquid model food systems were studied by using the BMS (ball measuring system). The model food systems were composed of alginate gel particles (-10mm) and a gelatinised... Rheological properties of large particulate-liquid model food systems were studied by using the BMS (ball measuring system). The model food systems were composed of alginate gel particles (-10mm) and a gelatinised starch solution with 1% w/w sodium chloride as a liquid phase. The effects of particle phase volume (Ф, 0-0.60), particle shapes (cube, sphere, rod and disc) and starch concentrations (3% and 5% w/w starch) were investigated. The power law model was successfully applied to characterize the flow properties of each system and the consistency K and power law index n were obtained. The K increased and n decreased with increasing # for samples at all particle shapes at 3% w/w starch in the liquid phase. The particle effect on the viscosity is further analysed by means of the Krieger-Dougherty model and the maximum packing fraction #,, and the intrinsic viscosity [η] were obtained in each system. The Фm, depended on the particle shape, as expected. The [7] value depended on particle shape and was largely in the order of 4.04 (cube), 3.28 (disc), 2.56 (sphere) and 2.32 (rod) at 3% w/w starch. The [η] also depended on starch concentration and was 1.1 at 5%,6 w/w starch in the liquid phase with spherical particles. The present results show successful application of BMS to study the rheological properties of large particulate liquid food systems at relatively small scale experiment (-0.5 L) and also that existing models for suspension rheology are applicable for such food systems to a great extend. 展开更多
关键词 Large particulate-liquid model food flow property ball measuring system power law model krieger-dougherty model.
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Thick Domain Walls in Lyra Geometry with Bulk Viscosity
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作者 Anirudh Pradhan 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第2期378-384,共7页
In this paper, we evaluate the general solutions for plane-symmetric thick domain walls in Lyra geometry in presence of bulk viscous fluid. Expressions for the energy density and pressure of domain walls are derived i... In this paper, we evaluate the general solutions for plane-symmetric thick domain walls in Lyra geometry in presence of bulk viscous fluid. Expressions for the energy density and pressure of domain walls are derived in both cases of uniform and time varying displacement field β. Some physical consequences of the models are also given. Finally, the geodesic equations and acceleration of the test particle are discussed. 展开更多
关键词 COSMOLOGY plane symmetric domain walls bulk viscous model Lyra geometry
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