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阴极过量系数与流场布置对风冷燃料电池性能影响的数值模拟
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作者 彭明 夏强峰 +2 位作者 蒋理想 陈黎 陶文铨 《化工学报》 EI CSCD 北大核心 2023年第10期4267-4276,共10页
风冷燃料电池性能较差仍然是限制其商业化应用的关键问题。采用数值模拟研究了阴极氧气过量系数以及氢/空布置方式对风冷燃料单电池性能的影响。结果表明,阴极过量系数过低时,风冷燃料电池无法满足散热需求,提高过量系数有利于风冷燃料... 风冷燃料电池性能较差仍然是限制其商业化应用的关键问题。采用数值模拟研究了阴极氧气过量系数以及氢/空布置方式对风冷燃料单电池性能的影响。结果表明,阴极过量系数过低时,风冷燃料电池无法满足散热需求,提高过量系数有利于风冷燃料电池热管理,提升膜电极中膜态水含量和电池性能,为了保证风冷燃料电池运行安全,需尽量维持风冷燃料电池运行在中高过量系数。与氢/空顺流布置相比,氢/空逆流布置策略受阳极入口干氢气影响膜电极呈现局部脱水状态,导致性能略微降低。 展开更多
关键词 燃料电池 数值模拟 过量系数 流场布置 水热管理
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Evaluation of flow behavior in copper electro-refining cell with different inlet arrangements 被引量:4
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作者 Ping ZHOU Hai-bo MA +2 位作者 Zi-wei XIE Hong-jie YAN Chenn Q. ZHOU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第10期2282-2290,共9页
The arrangement of electrolyte inlet in the copper electro-refining(ER)cell has a great influence on the local flow field,which affects the distribution of electrical current density in consequence.In order to underst... The arrangement of electrolyte inlet in the copper electro-refining(ER)cell has a great influence on the local flow field,which affects the distribution of electrical current density in consequence.In order to understand the complicated phenomena ofelectrolyte flow behavior in vertical counter electrodes in full-scale copper ER cell,the three-dimensional computational fluiddynamics(CFD)models with four different arrangements of electrolyte inlets,i.e.,single inlet(SI),central bottom inlets(CBI),topside interlaced inlets(TII),and bottom side interlaced inlets(BII),were established to simulate the flow behavior.Simulation resultshave revealed that the parallel injection devices help to improve the electrolyte velocity between electrodes,and while the relativerange of electrolyte velocity in CBI exceeds that of TII and BII,which is more than4times,indicating its severer unequal flowdistribution.Meanwhile,the average velocity of electrolyte in BII is4times larger than that of SI due to its higher turbulenceintensity.Generally,one of the efficient ways to supply fresh copper solution rapidly and uniformly into the inter-electrode space is toadapt the arrangement of BII.By utilizing such an arrangement,the electro-refining under high electrical current density is possible,and the productivity can be increased in sequence. 展开更多
关键词 copper electro-refining electrolyte inlet arrangement flow uniformity computational fluid dynamics
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