Gully erosion has caused soil degradation and even reduced soil productivity. However, only few studies on the effects of gully erosion and artificial controlling measures on soil degradation in the Black Soil Region ...Gully erosion has caused soil degradation and even reduced soil productivity. However, only few studies on the effects of gully erosion and artificial controlling measures on soil degradation in the Black Soil Region of Northeast China are available. Thus, this study explores the relationships between gully erosion, gully filling and soil parameters. Two sets of soil samples were collected in the field at： （1） 72 sample points in the gully erosion study area, 60 sample points in the ephemeral and classical gully erosion area （3,518 m2）, 12 sample points in the deposition zone （443 m2）, （2）1o reference points along a slope unaffected by gully erosion representing the original situation before the gully was formed. All soil samples were analyzed for gravel content （GC）, soil organic matter （SOM）, total nitrogen （TN）, available nitrogen （AN）, available phosphorus （AP）, and available potassium （AK）. The soil property values on unaffected slope were fitted by the polynomial curves as the reference values in no gully erosion area. The interpolated soil property values in gully eroded study area were compared with these polynomial curves, respectively, and then, changes of soil property values were analyzed. Gully erosion caused an increase in GC and a decrease in SOM, TN, AN, AP and AK. The change of GC, SOM, TN, AN, AP, AK was 8.8%, -9.04 g kg-1, -0.92 g kg-1, -62.28 mg kg-1, -29.61 mg kg% -79.68 mg kg-1. The soil property values in the study area were below optimal values. Thus, we concluded that gully erosion and gully filling caused both on-site and off-site soil degradation. Soil degradation area was 0.65 % of the cultivated land. In addition, it was proved that gully filling were an improper soil and water conservation measure, which seems to exacerbate the problem. Thus, it is suggested that soil where soil is deep is moved to fill the gully, and then the area around the filled gullies should be covered by grass for preventing the formation and development of the gully.展开更多
The paper reports the effects of surface fractal structures on the rheological behavior and combustion kinetics of raw brown coal and three modified coal water slurries （CWSs）. The results show that the fractal stru...The paper reports the effects of surface fractal structures on the rheological behavior and combustion kinetics of raw brown coal and three modified coal water slurries （CWSs）. The results show that the fractal structures and physicochemical properties of samples are dependent on various modification processes. The apparent viscosities of the coal water slurries increase with increasing surface fractal dimensions （D）, especially with decreasing shear rates. Fur- thermore, it has been proved that the ignition temperatures and apparent activation energies of modified CWSs are lower than that of raw coal water slurry. Compared with the traditional qualitative analysis of the effect of pore structures on CWSs properties, D can more efficiently indicate the quantificational effect of pore structures on the rheological behavior and combustion kinetics of CWSs.展开更多
The Brazilian repository is being planned to be a near-surface one. In Brazil, the low and intermediate level radioactive wastes are immobilized using cement and bitumen for nuclear plant Angra 1 and Angra 2, respecti...The Brazilian repository is being planned to be a near-surface one. In Brazil, the low and intermediate level radioactive wastes are immobilized using cement and bitumen for nuclear plant Angra 1 and Angra 2, respectively. The major problems due to the disposal of bituminized wastes in repositories are swelling of the waste products and their degrad^ttion in the long term. To accommodate the swelling of the bituminized wastes, the drums are filled up to 70-90% of their volume, which reduces the structural the repository stability and the disposal availability. Countries, which use bitumen in the solidification of NPP＇s radioactive waste and have near-surface repositories, need to immobilize this bituminized waste within other drums containing cement pastes or mortars to disposal them. This study aims to evaluate the properties of bitumen, cement pastes and mortars to be used in the encapsulation of bituminized wastes. The formulations of two pastes and two mortars were selected for the pilot scale tests. The laboratory and pilot scales results were very similar, indicating that any of these formulations could be used. However, the better formulation will be chosen after the leaching test results, because it is an essential parameter in the long-term repository performance.展开更多
Invading track of chloride ions and chloride ion distribution rule in cement-based materials were investigated by partially soaking in 3.5% （mass fraction） NaCl solution and fully immerging in 3.5% and 5.0% （mass f...Invading track of chloride ions and chloride ion distribution rule in cement-based materials were investigated by partially soaking in 3.5% （mass fraction） NaCl solution and fully immerging in 3.5% and 5.0% （mass fraction） NaC1 solution, respectively, and relevant invading mechanisms were discussed. Results indicate that under full immerging condition, the invading track of chloride ions in cement mortar is similar to beeline that is vertical to chloride ion invading direction, and chloride ion content decreases rapidly with the increase of chloride ion invading depth. Under partial soaking condition, the invading track of chloride ion in cement mortar is similar to the shape of concave parabola, and chloride ion content decreases slowly along the lengthway direction of cement mortar samples in the distance of 20-80 mm from the bottom. Lots of chloride ions accumulate in cement mortar surface layer under the effect of capillary rise and evaporation and then invade cement mortar by diffusion effect. Under partial soaking condition, cement mortar is distinguished by four areas, i.e., immerging area, wet area, crystallization area and dry area.展开更多
A laboratory-scale reaction-crystallization process of struvite synthesis from diluted water solution of Mg^2＋, NH^＋ 4 and PO3- ions was studied. The research covered the tests of two original constructions of conti...A laboratory-scale reaction-crystallization process of struvite synthesis from diluted water solution of Mg^2＋, NH^＋ 4 and PO3- ions was studied. The research covered the tests of two original constructions of continuous jet-pump Draft Tube Magma （DTM）-type crystallizers with internal circulation of suspension （upward/downward）. Interactions between constructional, hydrodynamic and kinetic factors were established and discussed. Nucleation and linear growth rates of struvite crystals were calculated on the basis of population density distribution. Kinetic model of idealized Mixed Suspension Mixed Product Removal （MSMPR） crystallizer considering the size-dependent growth mechanism was applied （Rojkowski hyperbolic equation）. For comparison purposes the kinetic data corre- sponded to a simpler, continuous draft tube-type crystallizer equipped with propeller agitator were analyzed. It was concluded that crystal product of larger size was withdrawn from the jet-pump DTM crystallizer of the descending flow of suspension in a mixing chamber.展开更多
This investigation was carried out to study the effect of aggregate roughness on ITZ （interfacial transition zone） at same water/cement ratio and the influence of silica fume on the bond strength. On the experimenta...This investigation was carried out to study the effect of aggregate roughness on ITZ （interfacial transition zone） at same water/cement ratio and the influence of silica fume on the bond strength. On the experimental side, two types of aggregates （limestone and granite） were used, which were prepared with broken surface. Cement （Type I） was used with same w/c ratio for all batches. In order to study the effect of silica fume on the bond, the same mixes were produced with 8% silica fume. Three different tests were performed： ＂pull a part＂, Brazilian test and compressive strength test. The specimens for Brazilian and compressive strength were tested after 28 days, while the ＂pull a part＂ specimens were tested after 29 days. The result showed that the bond strength is influenced by the surface roughness of aggregate. For the same mix, limestone recorded higher bond strength than granite. Moreover, the bond strength is increased by adding the silica fume.展开更多
基金supported by National Basic Research Program of China (973 Program) (Grant no. 2007CB407204)Innovation project of Changjiang River Scientific Research Institute (CKSF2012052/TB)basic scientific research project of Changjiang River Scientific Research Institute (CKSF2011008)
文摘Gully erosion has caused soil degradation and even reduced soil productivity. However, only few studies on the effects of gully erosion and artificial controlling measures on soil degradation in the Black Soil Region of Northeast China are available. Thus, this study explores the relationships between gully erosion, gully filling and soil parameters. Two sets of soil samples were collected in the field at： （1） 72 sample points in the gully erosion study area, 60 sample points in the ephemeral and classical gully erosion area （3,518 m2）, 12 sample points in the deposition zone （443 m2）, （2）1o reference points along a slope unaffected by gully erosion representing the original situation before the gully was formed. All soil samples were analyzed for gravel content （GC）, soil organic matter （SOM）, total nitrogen （TN）, available nitrogen （AN）, available phosphorus （AP）, and available potassium （AK）. The soil property values on unaffected slope were fitted by the polynomial curves as the reference values in no gully erosion area. The interpolated soil property values in gully eroded study area were compared with these polynomial curves, respectively, and then, changes of soil property values were analyzed. Gully erosion caused an increase in GC and a decrease in SOM, TN, AN, AP and AK. The change of GC, SOM, TN, AN, AP, AK was 8.8%, -9.04 g kg-1, -0.92 g kg-1, -62.28 mg kg-1, -29.61 mg kg% -79.68 mg kg-1. The soil property values in the study area were below optimal values. Thus, we concluded that gully erosion and gully filling caused both on-site and off-site soil degradation. Soil degradation area was 0.65 % of the cultivated land. In addition, it was proved that gully filling were an improper soil and water conservation measure, which seems to exacerbate the problem. Thus, it is suggested that soil where soil is deep is moved to fill the gully, and then the area around the filled gullies should be covered by grass for preventing the formation and development of the gully.
文摘The paper reports the effects of surface fractal structures on the rheological behavior and combustion kinetics of raw brown coal and three modified coal water slurries （CWSs）. The results show that the fractal structures and physicochemical properties of samples are dependent on various modification processes. The apparent viscosities of the coal water slurries increase with increasing surface fractal dimensions （D）, especially with decreasing shear rates. Fur- thermore, it has been proved that the ignition temperatures and apparent activation energies of modified CWSs are lower than that of raw coal water slurry. Compared with the traditional qualitative analysis of the effect of pore structures on CWSs properties, D can more efficiently indicate the quantificational effect of pore structures on the rheological behavior and combustion kinetics of CWSs.
文摘The Brazilian repository is being planned to be a near-surface one. In Brazil, the low and intermediate level radioactive wastes are immobilized using cement and bitumen for nuclear plant Angra 1 and Angra 2, respectively. The major problems due to the disposal of bituminized wastes in repositories are swelling of the waste products and their degrad^ttion in the long term. To accommodate the swelling of the bituminized wastes, the drums are filled up to 70-90% of their volume, which reduces the structural the repository stability and the disposal availability. Countries, which use bitumen in the solidification of NPP＇s radioactive waste and have near-surface repositories, need to immobilize this bituminized waste within other drums containing cement pastes or mortars to disposal them. This study aims to evaluate the properties of bitumen, cement pastes and mortars to be used in the encapsulation of bituminized wastes. The formulations of two pastes and two mortars were selected for the pilot scale tests. The laboratory and pilot scales results were very similar, indicating that any of these formulations could be used. However, the better formulation will be chosen after the leaching test results, because it is an essential parameter in the long-term repository performance.
基金Project(50678174) supported by the National Natural Science Foundation of China
文摘Invading track of chloride ions and chloride ion distribution rule in cement-based materials were investigated by partially soaking in 3.5% （mass fraction） NaCl solution and fully immerging in 3.5% and 5.0% （mass fraction） NaC1 solution, respectively, and relevant invading mechanisms were discussed. Results indicate that under full immerging condition, the invading track of chloride ions in cement mortar is similar to beeline that is vertical to chloride ion invading direction, and chloride ion content decreases rapidly with the increase of chloride ion invading depth. Under partial soaking condition, the invading track of chloride ion in cement mortar is similar to the shape of concave parabola, and chloride ion content decreases slowly along the lengthway direction of cement mortar samples in the distance of 20-80 mm from the bottom. Lots of chloride ions accumulate in cement mortar surface layer under the effect of capillary rise and evaporation and then invade cement mortar by diffusion effect. Under partial soaking condition, cement mortar is distinguished by four areas, i.e., immerging area, wet area, crystallization area and dry area.
文摘A laboratory-scale reaction-crystallization process of struvite synthesis from diluted water solution of Mg^2＋, NH^＋ 4 and PO3- ions was studied. The research covered the tests of two original constructions of continuous jet-pump Draft Tube Magma （DTM）-type crystallizers with internal circulation of suspension （upward/downward）. Interactions between constructional, hydrodynamic and kinetic factors were established and discussed. Nucleation and linear growth rates of struvite crystals were calculated on the basis of population density distribution. Kinetic model of idealized Mixed Suspension Mixed Product Removal （MSMPR） crystallizer considering the size-dependent growth mechanism was applied （Rojkowski hyperbolic equation）. For comparison purposes the kinetic data corre- sponded to a simpler, continuous draft tube-type crystallizer equipped with propeller agitator were analyzed. It was concluded that crystal product of larger size was withdrawn from the jet-pump DTM crystallizer of the descending flow of suspension in a mixing chamber.
文摘This investigation was carried out to study the effect of aggregate roughness on ITZ （interfacial transition zone） at same water/cement ratio and the influence of silica fume on the bond strength. On the experimental side, two types of aggregates （limestone and granite） were used, which were prepared with broken surface. Cement （Type I） was used with same w/c ratio for all batches. In order to study the effect of silica fume on the bond, the same mixes were produced with 8% silica fume. Three different tests were performed： ＂pull a part＂, Brazilian test and compressive strength test. The specimens for Brazilian and compressive strength were tested after 28 days, while the ＂pull a part＂ specimens were tested after 29 days. The result showed that the bond strength is influenced by the surface roughness of aggregate. For the same mix, limestone recorded higher bond strength than granite. Moreover, the bond strength is increased by adding the silica fume.
