Poly(p-phenylene terephthalamide)(PPTA)pulp was prepared by polycondensation of the p-phenylene diamine(PPDA)with terephthaloyl chloride(TPC)in the completely anhydrous solvent system of N-methyl pyrrolidone(NMP)havin...Poly(p-phenylene terephthalamide)(PPTA)pulp was prepared by polycondensation of the p-phenylene diamine(PPDA)with terephthaloyl chloride(TPC)in the completely anhydrous solvent system of N-methyl pyrrolidone(NMP)having calcium chloride,in the presence of poly(vinyl pyrrolidone)(PVP)having a viscosity average molecular weight lower than 40 000.It was confirmed that the polycondensation could be accelerated,the inherent viscosity of the polymer could be increased,and the polymers could be fibrillated more easily by the addition of the PVP.FTIR and X-ray spectra proved that PVP had not combined into molecular chains of the resultant PPTA pulps.The morphology of the resultant pulps,the effect of viscosity average molecular weight,amount and adding mode of PVP on inherent viscosity,specific surface area,and mean length of the resultant pulps were discussed in detail.And the friction and wear properties of the compound reinforced by the resultant pulps were simply investigated.展开更多
A numerical method for predicting fiber orientation is presented to explore the flow properties of turbulent fiber suspension flowing through a stock pump impeller. The Fokker-Planck equation is used to describe the d...A numerical method for predicting fiber orientation is presented to explore the flow properties of turbulent fiber suspension flowing through a stock pump impeller. The Fokker-Planck equation is used to describe the distribution of fiber orientation. The effect of flow-fiber coupling is considered by modifying the constitutive mode.The three-dimensional orientation distribution function is formulated and the corresponding equations are solved in terms of second-order and fourth-order orientation tensors. The evolution of fiber orientation, flow velocity and pressure, additional shear stress and normal stress difference are presented. The results show that the evolutions of fiber orientation are different along different streamlines. The velocity and its gradient are large in the concave wall region, while they are very small in the convex wall region. The additional shear stress and normal stress difference are large in the inlet and concave wall regions, and moderate in the mid-region, while they are almost zero in most downstream regions. The non-equilibrium fiber orientation distribution is dominant at the inlet and the concave wall regions. The flow will consume more energy to overcome the additional shearing losses due to fibers at the inlet and the concave wall regions. The change of flow rates has effect on the distribution of additional shear stress and normal stress difference. The flow structure in the inlet and concave wall regions is essential in the resultant rheological properties of the fiber suspension through the stock pump impeller, which will directly affect the flow efficiency of the fiber suspension through the impeller.展开更多
文摘Poly(p-phenylene terephthalamide)(PPTA)pulp was prepared by polycondensation of the p-phenylene diamine(PPDA)with terephthaloyl chloride(TPC)in the completely anhydrous solvent system of N-methyl pyrrolidone(NMP)having calcium chloride,in the presence of poly(vinyl pyrrolidone)(PVP)having a viscosity average molecular weight lower than 40 000.It was confirmed that the polycondensation could be accelerated,the inherent viscosity of the polymer could be increased,and the polymers could be fibrillated more easily by the addition of the PVP.FTIR and X-ray spectra proved that PVP had not combined into molecular chains of the resultant PPTA pulps.The morphology of the resultant pulps,the effect of viscosity average molecular weight,amount and adding mode of PVP on inherent viscosity,specific surface area,and mean length of the resultant pulps were discussed in detail.And the friction and wear properties of the compound reinforced by the resultant pulps were simply investigated.
基金Supported by the National Natural Science Foundation of China （51309118）, the National Key Technology R＆D Program of the Ministry of Science and Technology of China （2011BAF14B01）, the Postdoctoral Science Foundation of China （2013M531282） and the Doctorate Program of Higher Education of China （20120101110121）.
文摘A numerical method for predicting fiber orientation is presented to explore the flow properties of turbulent fiber suspension flowing through a stock pump impeller. The Fokker-Planck equation is used to describe the distribution of fiber orientation. The effect of flow-fiber coupling is considered by modifying the constitutive mode.The three-dimensional orientation distribution function is formulated and the corresponding equations are solved in terms of second-order and fourth-order orientation tensors. The evolution of fiber orientation, flow velocity and pressure, additional shear stress and normal stress difference are presented. The results show that the evolutions of fiber orientation are different along different streamlines. The velocity and its gradient are large in the concave wall region, while they are very small in the convex wall region. The additional shear stress and normal stress difference are large in the inlet and concave wall regions, and moderate in the mid-region, while they are almost zero in most downstream regions. The non-equilibrium fiber orientation distribution is dominant at the inlet and the concave wall regions. The flow will consume more energy to overcome the additional shearing losses due to fibers at the inlet and the concave wall regions. The change of flow rates has effect on the distribution of additional shear stress and normal stress difference. The flow structure in the inlet and concave wall regions is essential in the resultant rheological properties of the fiber suspension through the stock pump impeller, which will directly affect the flow efficiency of the fiber suspension through the impeller.
