TB853.1 98042595单镜头反光照相机测光范围与测光光学系统设计计算=Design of light measuring system range andoptical system of SLR camera[刊,中]/冯华君(浙江大学光学仪器国家重点实验室.浙江,杭州(310027))∥光学技术.—1998,(2).
A design for a fisheye optical system is modified in order to enable IR vision in addition to the visible and UV lighting. The proposed modification goes to replace the optical material of the movable lens by another ...A design for a fisheye optical system is modified in order to enable IR vision in addition to the visible and UV lighting. The proposed modification goes to replace the optical material of the movable lens by another with less thermal dispersion. The choice of appropriate materials lead to a good focus appeared on the retina for a wide spectral range includes UV, visible, and near IR lighting. Then, the performance of the modified design is verified through some optical measures for imaging quality determinations. These optical measures are determined with the aid of Zemax software, which also used for testing performance of the modified fisheye optical system. The analysis mainly focuses on the energy distribution in the light spot on the focal surface. The results show that the modified design of the fisheye is acceptable.展开更多
A new kinetic spectrophotometric method has been developed for the determination of trace Ni (Ⅱ in natural water. The method is based on the catalytic effect of Ni (Ⅱ) on the oxidation of weak acid brilliant blue...A new kinetic spectrophotometric method has been developed for the determination of trace Ni (Ⅱ in natural water. The method is based on the catalytic effect of Ni (Ⅱ) on the oxidation of weak acid brilliant blue dye (RAWL) by KIO4 in acid medium. The concentration of nickel (Ⅱ) can be determined spectrophotometrically by measuring the decrease of absorbance of RAWL at λ = 626 nm using the fix-time method. The influencing factors are investigated by the orthogonal experimental design. The obtained optimum analytical conditions are: pH = 2.00, CRAWL = 5.00×10^-5 mol·L^-1, c KlO4 = 2.00× 10^-5 mol·L^-1, the reaction time t= 10min and the temperature T = 25 ℃. Under the optimum conditions, the developed method allows the measurement of Ni (Ⅱ) in a range of 0 - 40.0ngmL1. The standard deviation of eleven independent measurements of blank reaction is S = 3.08× 10^-3 and the limit of detection is 2.20ng·mL^-1. The relative standard deviations (RSDs) in six replicate determinations of 5 ngmL-1 and 8 ngmL1 Ni (Ⅱ) are 2.87% and 1.11%, respectively. Moreover, the experiments show few cations and anions can interfere with the measurement of Ni (Ⅱ). The recovery efficiencies of this method are in a range of 97.0%-102.5% in freshwater samples. But there is a decreasing effect, which is about 0.2 times the added Ni (Ⅱ) in seawater medium. After reasonable calibration this processing method is used for the determination of Ni (Ⅱ) in seawater samples successfully. The results show this developed method has high accuracy and precision, high sensitivity, large range of linearity and high speed. The method can, therefore, be employed at room temperature.展开更多
An optical chemical sensor has been developed for the determination of iodine based on the reversible fluorescence quenching of 2, 2, 7, 7, 12, 12, 17, 17-octamethyl-21, 22, 23, 24-tetraoxaquaterene-Li (LiTOE) imm...An optical chemical sensor has been developed for the determination of iodine based on the reversible fluorescence quenching of 2, 2, 7, 7, 12, 12, 17, 17-octamethyl-21, 22, 23, 24-tetraoxaquaterene-Li (LiTOE) immobilized in a plasticized poly(vinyl chloride) (PVC) membrane. The optimum membrane of the sensor consists of 100 mg of PVC, 200 mg of bis (2-ethytbexyl) sebacate (BOS) and 3.0 mg of LiTOE. The maximum response of the optode membrane for iodine is obtained in Tris-HCl buffer solutlon (pH 8.0). With the optimum conditions described, the proposed sensor responds linearly in the measuring range of 3.90×10^-2 to 3.90×10^-4 mol/L, and has a detection limit of 6.0×10^-8 mol/L. The response time of the sensor is less than I rain. In addition to high reproducibility and reversibility of the fluorescence signal, the sensor also exhibits good selectivity. It is not interfered by some common anions and cations. It is applied for the determination of iodine in table salt samples. The results agree with those obtained by another method.展开更多
A new present weather identifier(PWI) based on occlusion and scattering techniques is presented in the study. The present weather parameters are detectable by the meteorological optical range(MOR) approximately up to ...A new present weather identifier(PWI) based on occlusion and scattering techniques is presented in the study. The present weather parameters are detectable by the meteorological optical range(MOR) approximately up to 50 km and by droplets with diameters ranging from 0.125 mm to 22 mm with velocities up to 16 m s-1. The MOR error is less than 8% for the MOR within 10 km and less than 15% for farther distances. Moreover, the size errors derived from various positions of the light sheet by the particles were checked within ± 0.1 mm ± 5%. The comparison shows that the MOR, in a sudden shower event, is surprisingly consistent with those of the sentry visibility sensors(SVS) with a correlation coefficient up to 98%. For the rain amounts derived from the size and velocity of the droplets, the daily sums by the PWI agree within 10% of those by the Total Rain Weighing Sensor(TRwS205) and the rain gauge. Combined with other sensors such as temperature, humidity, and wind, the PWI can serve as a present weather sensor to distinguish several weather types such as fog, haze, mist, rain, hail, and drizzle.展开更多
Filtration processes are worldwide used for sterilizing solutions and substrates. Filtration seems to induce the formation of aqueous nanostructures. The aim of this work was to verify the influence of filtration proc...Filtration processes are worldwide used for sterilizing solutions and substrates. Filtration seems to induce the formation of aqueous nanostructures. The aim of this work was to verify the influence of filtration processes on water structure detected by spectral variations in NIR region. Samples of ultrapure water (MilliQ-Millipore, Vimodrone, Milan, Italy) before and after iterated filtrations were analyzed. NIR spectra were collected in transmission mode in the whole NIR range, by using NIRFIex N500 spectrometer at constant temperature (40 ± 1 ℃). NIR data were processed using Unscrambler software v. 9.2 in evaluating qualitative differences between filtered and not filtered samples. The information related to possible solvent physical stresses were highlighted in the range 6500-7500 cm^-1. The shifts observed were ascribable to a different distribution of the number of water molecules involved in hydrogen bonds in filtered and not filtered water samples, at constant temperature. NIR spectroscopy, commonly used to study relationship between spectral changes and hydrogen bonds in water at increasing temperature values, was applied to evaluate effects of filtration processes on water structure. The obtained results are in agreement with literature data and allowed the improvement of the knowledge about pure water characteristics when some mechanical perturbations are applied.展开更多
Polyelectrolyte PTPEPyH, containing tetraphenylethene (TPE) and pyridinium, was synthesized. Its optical properties were investigated with spectroscopies and the results showed that there were two emission-enhanced st...Polyelectrolyte PTPEPyH, containing tetraphenylethene (TPE) and pyridinium, was synthesized. Its optical properties were investigated with spectroscopies and the results showed that there were two emission-enhanced stages in the interaction between positive-charged PTPEPyH and negative-charged biomacromolecule heparin. The mechanism was very different due to the reduced non-radiative energy loss and the change of surroundings. The polyelectrolyte PTPEPyH, compared with ChS and HA, also showed high selectivity for heparin in the buffer solution and could be used as a potential bio-probe for heparin quantification in the clinical full range.展开更多
A novel fiber Bragg grating(FBG)displacement sensor is proposed,which can achieve wide measuring range displacement detection with variable measurement precision due to its mechanical transfer structure of helical bev...A novel fiber Bragg grating(FBG)displacement sensor is proposed,which can achieve wide measuring range displacement detection with variable measurement precision due to its mechanical transfer structure of helical bevel gear.A prototype is designed and fabricated.The maximum detection displacement of this prototype is 1.751 m,and the precision grade changes from 0.2%to 6.7%.Through analyzing the experiment data which is obtained in the calibration experiment,the measuring range of this sensor is from 0 m to 1.532 m,and the wavelength shift errors between experiment data and theory calculation are all less than 5%.展开更多
Two-dimensional(2D) ternary materials have sprung up in a broad variety of optoelectronic applications due to their robust degree of freedom to design the physical properties of the materials through adjusting the sto...Two-dimensional(2D) ternary materials have sprung up in a broad variety of optoelectronic applications due to their robust degree of freedom to design the physical properties of the materials through adjusting the stoichiometric ratio. However, the controlled growth of high-quality 2D ternary materials with good chemical stoichiometry remains challenging, which severely impedes their further development and future device applications. Herein, we synthesize ternary Bi_(2)Te_(2)Se(BTS) flakes with a thickness down to 4 nm and a lateral dimension about 60 μm by an atmospheric-pressure solid source thermal evaporation method on a mica substrate. The phonon vibration and electrical transportation of 2D BTS are respectively investigated by temperature-dependent Raman spectrum and conductivity measurements. Furthermore, the photodetector based on 2D BTS exhibits excellent performance with a high light on/off ratio of 1300(365 nm), a wide spectral response range from 365 to 980 nm, and an ultra-fast response speed up to 2 μs. In addition, its electrical and photoelectric properties can be modulated by the gate voltage, offering an improved infrared responsivity to 2.74 A W^(-1) and an on/off ratio of 2266 under 980 nm. This work introduces an effective approach to obtain 2D BTS flakes and demonstrates their excellent prospects in optoelectronics.展开更多
The generation mechanism of the first arrivals in the cased boreholes for the poorly bonded conditions is investigated. Based on the analyses of the Riemann surface structure of the characteristic function, the disper...The generation mechanism of the first arrivals in the cased boreholes for the poorly bonded conditions is investigated. Based on the analyses of the Riemann surface structure of the characteristic function, the dispersion features, excitation spectra and contributions of modes excited in the cased boreholes with different cementing types are studied. The phase velocity dispersion studies of leaky modes show that high-order modes form "plateau" regions with one approximate velocity denoted by v separated by their cutoff frequencies, in which the phase velocity changes little with a considerable frequency range, while the group velocity keeps a relatively constant high value. Usually, the operation frequency range of a specific cementing evaluation acoustic logging tool is covered by such a "plateau" region. Mode excitation and contribution analyses show that the first arrivals in the cased boreholes for the poorly bonded conditions are the contributions from leaky modes, where the traveling velocity of the first arrivals processed by slowness time coherence(STC) method is equal to the approximated velocity v. Analyses on generation of leaky modes in the cased boreholes supplement the understanding of the generation mechanism of the first arrivals.展开更多
An accurate frequency response characterization method for photoreceivers with optical heterodyne technique is presented in this paper.The characterization is implemented with two single-mode tunable lasers operating ...An accurate frequency response characterization method for photoreceivers with optical heterodyne technique is presented in this paper.The characterization is implemented with two single-mode tunable lasers operating near the wavelength of 1.55 μm.The errors introduced by extra fixtures as well as laser output fluctuations are considered and calibrated simultaneously.Compared with previous works,the proposed calibration procedures are more complete.Experimental results indicate that the significant improvement in measurement precision has been achieved with the proposed method in the frequency range from 0 to 30 GHz,which proves the proposed frequency response characterization method to be feasible and reliable.展开更多
文摘TB853.1 98042595单镜头反光照相机测光范围与测光光学系统设计计算=Design of light measuring system range andoptical system of SLR camera[刊,中]/冯华君(浙江大学光学仪器国家重点实验室.浙江,杭州(310027))∥光学技术.—1998,(2).
文摘A design for a fisheye optical system is modified in order to enable IR vision in addition to the visible and UV lighting. The proposed modification goes to replace the optical material of the movable lens by another with less thermal dispersion. The choice of appropriate materials lead to a good focus appeared on the retina for a wide spectral range includes UV, visible, and near IR lighting. Then, the performance of the modified design is verified through some optical measures for imaging quality determinations. These optical measures are determined with the aid of Zemax software, which also used for testing performance of the modified fisheye optical system. The analysis mainly focuses on the energy distribution in the light spot on the focal surface. The results show that the modified design of the fisheye is acceptable.
文摘A new kinetic spectrophotometric method has been developed for the determination of trace Ni (Ⅱ in natural water. The method is based on the catalytic effect of Ni (Ⅱ) on the oxidation of weak acid brilliant blue dye (RAWL) by KIO4 in acid medium. The concentration of nickel (Ⅱ) can be determined spectrophotometrically by measuring the decrease of absorbance of RAWL at λ = 626 nm using the fix-time method. The influencing factors are investigated by the orthogonal experimental design. The obtained optimum analytical conditions are: pH = 2.00, CRAWL = 5.00×10^-5 mol·L^-1, c KlO4 = 2.00× 10^-5 mol·L^-1, the reaction time t= 10min and the temperature T = 25 ℃. Under the optimum conditions, the developed method allows the measurement of Ni (Ⅱ) in a range of 0 - 40.0ngmL1. The standard deviation of eleven independent measurements of blank reaction is S = 3.08× 10^-3 and the limit of detection is 2.20ng·mL^-1. The relative standard deviations (RSDs) in six replicate determinations of 5 ngmL-1 and 8 ngmL1 Ni (Ⅱ) are 2.87% and 1.11%, respectively. Moreover, the experiments show few cations and anions can interfere with the measurement of Ni (Ⅱ). The recovery efficiencies of this method are in a range of 97.0%-102.5% in freshwater samples. But there is a decreasing effect, which is about 0.2 times the added Ni (Ⅱ) in seawater medium. After reasonable calibration this processing method is used for the determination of Ni (Ⅱ) in seawater samples successfully. The results show this developed method has high accuracy and precision, high sensitivity, large range of linearity and high speed. The method can, therefore, be employed at room temperature.
文摘An optical chemical sensor has been developed for the determination of iodine based on the reversible fluorescence quenching of 2, 2, 7, 7, 12, 12, 17, 17-octamethyl-21, 22, 23, 24-tetraoxaquaterene-Li (LiTOE) immobilized in a plasticized poly(vinyl chloride) (PVC) membrane. The optimum membrane of the sensor consists of 100 mg of PVC, 200 mg of bis (2-ethytbexyl) sebacate (BOS) and 3.0 mg of LiTOE. The maximum response of the optode membrane for iodine is obtained in Tris-HCl buffer solutlon (pH 8.0). With the optimum conditions described, the proposed sensor responds linearly in the measuring range of 3.90×10^-2 to 3.90×10^-4 mol/L, and has a detection limit of 6.0×10^-8 mol/L. The response time of the sensor is less than I rain. In addition to high reproducibility and reversibility of the fluorescence signal, the sensor also exhibits good selectivity. It is not interfered by some common anions and cations. It is applied for the determination of iodine in table salt samples. The results agree with those obtained by another method.
基金supported by Automatic Observation System for Cloud, Visibility and Weather Phenomena (Grant No. GYHY200806031)Carbon Satellites Verification Systems and Comprehensive Observations (Grant Nos. GJHZ1207 and XDA05040302)
文摘A new present weather identifier(PWI) based on occlusion and scattering techniques is presented in the study. The present weather parameters are detectable by the meteorological optical range(MOR) approximately up to 50 km and by droplets with diameters ranging from 0.125 mm to 22 mm with velocities up to 16 m s-1. The MOR error is less than 8% for the MOR within 10 km and less than 15% for farther distances. Moreover, the size errors derived from various positions of the light sheet by the particles were checked within ± 0.1 mm ± 5%. The comparison shows that the MOR, in a sudden shower event, is surprisingly consistent with those of the sentry visibility sensors(SVS) with a correlation coefficient up to 98%. For the rain amounts derived from the size and velocity of the droplets, the daily sums by the PWI agree within 10% of those by the Total Rain Weighing Sensor(TRwS205) and the rain gauge. Combined with other sensors such as temperature, humidity, and wind, the PWI can serve as a present weather sensor to distinguish several weather types such as fog, haze, mist, rain, hail, and drizzle.
文摘Filtration processes are worldwide used for sterilizing solutions and substrates. Filtration seems to induce the formation of aqueous nanostructures. The aim of this work was to verify the influence of filtration processes on water structure detected by spectral variations in NIR region. Samples of ultrapure water (MilliQ-Millipore, Vimodrone, Milan, Italy) before and after iterated filtrations were analyzed. NIR spectra were collected in transmission mode in the whole NIR range, by using NIRFIex N500 spectrometer at constant temperature (40 ± 1 ℃). NIR data were processed using Unscrambler software v. 9.2 in evaluating qualitative differences between filtered and not filtered samples. The information related to possible solvent physical stresses were highlighted in the range 6500-7500 cm^-1. The shifts observed were ascribable to a different distribution of the number of water molecules involved in hydrogen bonds in filtered and not filtered water samples, at constant temperature. NIR spectroscopy, commonly used to study relationship between spectral changes and hydrogen bonds in water at increasing temperature values, was applied to evaluate effects of filtration processes on water structure. The obtained results are in agreement with literature data and allowed the improvement of the knowledge about pure water characteristics when some mechanical perturbations are applied.
基金the National Basic Research Pro- gram of China (973 Program 2013CB834704)+2 种基金the National Natural Scientific Foundation of China (21004004 and 51061160500)the Specialized Research Fund for the Doctoral Program of Higher Education of China (20101101120029 and 20091101110031)the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (20120932001)
文摘Polyelectrolyte PTPEPyH, containing tetraphenylethene (TPE) and pyridinium, was synthesized. Its optical properties were investigated with spectroscopies and the results showed that there were two emission-enhanced stages in the interaction between positive-charged PTPEPyH and negative-charged biomacromolecule heparin. The mechanism was very different due to the reduced non-radiative energy loss and the change of surroundings. The polyelectrolyte PTPEPyH, compared with ChS and HA, also showed high selectivity for heparin in the buffer solution and could be used as a potential bio-probe for heparin quantification in the clinical full range.
基金supported by the National Natural Science Foundation of China(Nos.61174018,41472260 and 41202206)
文摘A novel fiber Bragg grating(FBG)displacement sensor is proposed,which can achieve wide measuring range displacement detection with variable measurement precision due to its mechanical transfer structure of helical bevel gear.A prototype is designed and fabricated.The maximum detection displacement of this prototype is 1.751 m,and the precision grade changes from 0.2%to 6.7%.Through analyzing the experiment data which is obtained in the calibration experiment,the measuring range of this sensor is from 0 m to 1.532 m,and the wavelength shift errors between experiment data and theory calculation are all less than 5%.
基金supported by the National Natural Science Foundation of China (21825103)Hubei Provincial Natural Science Foundation of China (2019CFA002)the Fundamental Research Funds for the Central Universities (2019kfy XMBZ018)。
文摘Two-dimensional(2D) ternary materials have sprung up in a broad variety of optoelectronic applications due to their robust degree of freedom to design the physical properties of the materials through adjusting the stoichiometric ratio. However, the controlled growth of high-quality 2D ternary materials with good chemical stoichiometry remains challenging, which severely impedes their further development and future device applications. Herein, we synthesize ternary Bi_(2)Te_(2)Se(BTS) flakes with a thickness down to 4 nm and a lateral dimension about 60 μm by an atmospheric-pressure solid source thermal evaporation method on a mica substrate. The phonon vibration and electrical transportation of 2D BTS are respectively investigated by temperature-dependent Raman spectrum and conductivity measurements. Furthermore, the photodetector based on 2D BTS exhibits excellent performance with a high light on/off ratio of 1300(365 nm), a wide spectral response range from 365 to 980 nm, and an ultra-fast response speed up to 2 μs. In addition, its electrical and photoelectric properties can be modulated by the gate voltage, offering an improved infrared responsivity to 2.74 A W^(-1) and an on/off ratio of 2266 under 980 nm. This work introduces an effective approach to obtain 2D BTS flakes and demonstrates their excellent prospects in optoelectronics.
基金the National Natural Science Foundation of China(Grant Nos.11134011 and 41274134)
文摘The generation mechanism of the first arrivals in the cased boreholes for the poorly bonded conditions is investigated. Based on the analyses of the Riemann surface structure of the characteristic function, the dispersion features, excitation spectra and contributions of modes excited in the cased boreholes with different cementing types are studied. The phase velocity dispersion studies of leaky modes show that high-order modes form "plateau" regions with one approximate velocity denoted by v separated by their cutoff frequencies, in which the phase velocity changes little with a considerable frequency range, while the group velocity keeps a relatively constant high value. Usually, the operation frequency range of a specific cementing evaluation acoustic logging tool is covered by such a "plateau" region. Mode excitation and contribution analyses show that the first arrivals in the cased boreholes for the poorly bonded conditions are the contributions from leaky modes, where the traveling velocity of the first arrivals processed by slowness time coherence(STC) method is equal to the approximated velocity v. Analyses on generation of leaky modes in the cased boreholes supplement the understanding of the generation mechanism of the first arrivals.
文摘An accurate frequency response characterization method for photoreceivers with optical heterodyne technique is presented in this paper.The characterization is implemented with two single-mode tunable lasers operating near the wavelength of 1.55 μm.The errors introduced by extra fixtures as well as laser output fluctuations are considered and calibrated simultaneously.Compared with previous works,the proposed calibration procedures are more complete.Experimental results indicate that the significant improvement in measurement precision has been achieved with the proposed method in the frequency range from 0 to 30 GHz,which proves the proposed frequency response characterization method to be feasible and reliable.