Presented is a multiple model soft sensing method based on Affinity Propagation (AP), Gaussian process (GP) and Bayesian committee machine (BCM). AP clustering arithmetic is used to cluster training samples acco...Presented is a multiple model soft sensing method based on Affinity Propagation (AP), Gaussian process (GP) and Bayesian committee machine (BCM). AP clustering arithmetic is used to cluster training samples according to their operating points. Then, the sub-models are estimated by Gaussian Process Regression (GPR). Finally, in order to get a global probabilistic prediction, Bayesian committee mactnne is used to combine the outputs of the sub-estimators. The proposed method has been applied to predict the light naphtha end point in hydrocracker fractionators. Practical applications indicate that it is useful for the online prediction of quality monitoring in chemical processes.展开更多
To overcome the problem that soft sensor models cannot be updated with the process changes, a soft sensor modeling algorithm based on hybrid fuzzy c-means (FCM) algorithm and incremental support vector machines (I...To overcome the problem that soft sensor models cannot be updated with the process changes, a soft sensor modeling algorithm based on hybrid fuzzy c-means (FCM) algorithm and incremental support vector machines (ISVM) is proposed. This hybrid algorithm FCMISVM includes three parts: samples clustering based on FCM algorithm, learning algorithm based on ISVM, and heuristic sample displacement method. In the training process, the training samples are first clustered by the FCM algorithm, and then by training each clustering with the SVM algorithm, a sub-model is built to each clustering. In the predicting process, when an incremental sample that represents new operation information is introduced in the model, the fuzzy membership function of the sample to each clustering is first computed by the FCM algorithm. Then, a corresponding SVM sub-model of the clustering with the largest fuzzy membership function is used to predict and perform incremental learning so the model can be updated on-line. An old sample chosen by heuristic sample displacement method is then discarded from the sub-model to control the size of the working set. The proposed method is applied to predict the p-xylene (PX) purity in the adsorption separation process. Simulation results indicate that the proposed method actually increases the model's adaptive abilities to various operation conditions and improves its generalization capability.展开更多
Atmospheric sulfur deposition onto typical farmland in East China was investigated using both field measurements and numerical modeling. The field measurements were conducted at the Experiment Station of Red Soil Ecol...Atmospheric sulfur deposition onto typical farmland in East China was investigated using both field measurements and numerical modeling. The field measurements were conducted at the Experiment Station of Red Soil Ecology, Chinese Academy of Sciences, 10 km from Yingtan, Jiangxi Province, East China, between November 1998 and October 1999, and at the Changshu Ecological Experiment Station, Chinese Academy of Sciences, in a rapidly developing region of Jiangsu Province, East China, between April 2001 and Marc…展开更多
River Ghataprabha, during its course through Belgaum district in Karnataka state (India), receives untreated domestic waste from Gokak town and other neighboring villages situated on the bank of the river. The prese...River Ghataprabha, during its course through Belgaum district in Karnataka state (India), receives untreated domestic waste from Gokak town and other neighboring villages situated on the bank of the river. The present study involves the application of water quality model QUAL2K to predict the water quality of this polluted segment of the river. The model was calibrated and validated for biochemical oxygen demand (BOD), dissolved oxygen (DO) and total nitrogen (TN) in pre-monsoon season. Data for calibration and validation were obtained after the field and laboratory measurements. The performance of the model was evaluated using statistics based on standard errors (SE) and mean multiplicative errors (MME). The model represented the field data quite well with some exceptions. In spite of some differences between the measured and simulated data sets at some points, the calibration and validation results are acceptable especially for the developing countries where the financial resources are often limited for frequent monitoring campaigns and higher accuracy data analysis.展开更多
Aimed at the CMS laser scanning theory and characteristic, a combined actual situation of stope N4-5 of Fankou Lead-Zinc Mine and complementary monitoring of the stope were carried out by carefully choos- ing two meas...Aimed at the CMS laser scanning theory and characteristic, a combined actual situation of stope N4-5 of Fankou Lead-Zinc Mine and complementary monitoring of the stope were carried out by carefully choos- ing two measuring points. The cavity 3D visible model was created by large-scale mining industry soft- ware Surpac after changing the measured data. The stope mine design model, bottom structural model and backfill model of the south and north sides of the stope N4-5 were established according to the stope design data. On this basis, the stope block model was established, and then block attribute was estimated. The amount the ore remains, mullock, backfill and total mined ore were calculated through the solid model restrains. Finally, the stope mining dilution rate and loss rate reached 8.2% and 1.47%, respectively. The practice indicates that the mining index visible calculation method based on cavity 3D monitoring and stope block modeling can make up the deficiency of adopting the solid model to directly carry out the Boolean operation, The stope mining indexes obtained by this method are accurate and reliable, and can be used to guide the actual nroduction management and estimate the mining aualitv.展开更多
To ensure the safety of buildings surrounding foundation pits, a study was made on a settlement monitoring and trend prediction method. A statistical testing method for analyzing the stability of a settlement monitori...To ensure the safety of buildings surrounding foundation pits, a study was made on a settlement monitoring and trend prediction method. A statistical testing method for analyzing the stability of a settlement monitoring datum has been discussed. According to a comprehensive survey, data of 16 stages at operating control point, were verified by a standard t test to determine the stability of the operating control point. A stationary auto-regression model, AR(p), used for the observation point settlement prediction has been investigated. Given the 16 stages of the settlement data at an observation point, the applicability of this model was analyzed. Settlement of last four stages was predicted using the stationary auto-regression model AR (1); the maximum difference between predicted and measured values was 0.6 mm, indicating good prediction results of the model. Hence, this model can be applied to settlement predictions for buildings surrounding foundation pits.展开更多
In the Pearl River Delta (PRD), there is severe competition between container ports, particularly those in Hong Kong, Shenzhen, and Guangzhou, for collecting international maritime container cargo. In addition, the se...In the Pearl River Delta (PRD), there is severe competition between container ports, particularly those in Hong Kong, Shenzhen, and Guangzhou, for collecting international maritime container cargo. In addition, the second phase of the Nansha terminal in Guangzhou’s port and the first phase of the Da Chang Bay container terminal in Shenzhen opened last year. Under these circumstances, there is an increasing need to quantitatively measure the impact these infrastructure investments have on regional cargo flows. The analysis should include the effects of container terminal construction, berth deepening, and access road construction. The authors have been developing a model for international cargo simulation (MICS) which can simulate the movement of cargo. The volume of origin-destination (OD) container cargo in the East Asian region was used as an input, in order to evaluate the effects of international freight transportation policies. This paper focuses on the PRD area and, by incorporating a more detailed network, evaluates the impact of several infrastructure investment projects on freight movement.展开更多
The solubility of red palm oil (RPO) in supercritical carbon dioxide (scCO2) was determined using a dynamic method at 8.5-25 MPa and, 313.15-333.15 K and at a fixed scCO2 flow rate of 2.9 g. mn -1 using a full fac...The solubility of red palm oil (RPO) in supercritical carbon dioxide (scCO2) was determined using a dynamic method at 8.5-25 MPa and, 313.15-333.15 K and at a fixed scCO2 flow rate of 2.9 g. mn -1 using a full factorial design. The solubility was determined under low pressures and temperatures as a preliminary study for RPO par- ticle formation using scCO2. The solubility of RPO was 0.5-11.3 mg. (g CO2) -1 and was significantly affected by the pressure and temperature. RPO solubility increased with pressure and decreased with temperature. The Adachi-Lu model showed the best-fit for RPO solubility data with an average relative deviation of 14% with a high coefficient of determination, R2 of 0.9667, whereas the Peng-Robinson equation of state thermodynamic model recorded deviations of 17%-30%.展开更多
The processes of building dynamic and static relationships between secondary and primary variables are usually integrated in most of nonlinear dynamic soft sensor models. However, such integration limits the estimatio...The processes of building dynamic and static relationships between secondary and primary variables are usually integrated in most of nonlinear dynamic soft sensor models. However, such integration limits the estimation accuracy of soft sensor models. Wiener model effectively describes dynamic and static characteristics of a system with the structure of dynamic and static submodels in cascade. We propose a soft sensor model derived from Wiener model structure, which is an extension of Wiener model. Dynamic and static relationships between secondary and primary variables are built respectively to describe the dynamic and static characteristics of system. The feasibility of this model is verified. Then the expression of discrete model is derived for soft sensor system. Conjugate gradient algorithm is applied to identify the dynamic and static model parameters alternately. Corresponding update method for soft sensor system is also given. Case studies confirm the effectiveness of the proposed model, alternate identification algorithm, and update method.展开更多
Vapor-liquid equilibrium(VLE) data were measured for ternary system water + ethanol + 1-butyl-3methylimidazolium acetate([bmim][OAc]),in a relatively wide range of ionic liquid(IL) mass fractions up to 0.8.Six sets of...Vapor-liquid equilibrium(VLE) data were measured for ternary system water + ethanol + 1-butyl-3methylimidazolium acetate([bmim][OAc]),in a relatively wide range of ionic liquid(IL) mass fractions up to 0.8.Six sets of complete T-x-y data were obtained,in which the mole fraction of ethanol on IL-free basis was fixed separately at 0.1,0.2,0.4,0.6,0.8,and approximate 0.98.The non-random-two-liquid(NRTL) and electrolyte non-random-two-liquid(eNRTL) equations were used for correlation,showing similar deviations.The ternary VLE was also modeled with the correlation from two data sets,with the mole fractions of ethanol on IL-free basis being 0.1 and approximate 0.98.The VLE data were also reproduced satisfactorily.With the eNRTL model,the root-mean-square deviation for temperature is 0.79 K and that for vapor-phase mole fraction is 0.0094.The calculations are in good agreement with experimental data.The effect of the IL on the VLE behavior of the volatile components is also illustrated.展开更多
The Arizona Department of Transportation (ADOT) in the USA conducted a series of asphalt aging related research and special studies between the 1970s and 1990s. The studies covered over 157 test sections representin...The Arizona Department of Transportation (ADOT) in the USA conducted a series of asphalt aging related research and special studies between the 1970s and 1990s. The studies covered over 157 test sections representing both neat (virgin) asphalt and crumb rubber modified (asphalt-rubber) binders. The data comprised of a wide range of penetration, viscosity, and Performance Grade (PG) parameters, at original and aged conditions. In the late 1990s, asphalt PG complex shear modulus (G*), and phase angle (5) data were collected. The main purpose of this paper was to use the assembled database of the field core-aged asphalt test data and compare the test results to the American Association of State Highway and Transportation Officials approved Mechanistic-Empirical Pavement Design Guide (MEPDG) predictive modeled asphalt properties such as penetration and viscosity, G*, and 5. Furthermore, G* and laboratory measurements on neat and asphalt-rubber binders extracted from the field cores of the pavement sections aged ten or more years were compared to the pressure aging vessel PG G* and ~. values. It was observed that the MEPDG predicted asphalt binder properties were rational for originally (tank) sampled binders, but fairly correlated for the aged binders. Additionally, penetration and viscosity aging indices representing over 20 years of field aged sections were established for a wide variety of asphalt binder grades. Overall, the relationships for aging indices were meaningful and rational. Results of this research indicated the degree of difficulty in predicting asphalt binder properties for pavements with ten or more years of field aging. The findings from this research study are envisioned to be of substantial value in future asphalt binder aging studies.展开更多
The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H2S removal. The solubility of HzS in JM-T was measured at 298, 313,333,353, and 368 K with H2S partial pressures from 20 to 760 k...The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H2S removal. The solubility of HzS in JM-T was measured at 298, 313,333,353, and 368 K with H2S partial pressures from 20 to 760 kPa and HzS loading from 0.02 to 0.8 mol H2S per mol JM-T. Relevant physical properties, such as density, viscoslty and dielectric constant, ot the matenal were measured. 'The thermodynamlc model with two-suttlX Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore, the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.展开更多
Vapor-liquid equilibrium(VLE)data for water+2-propanol+1-butyl-3-methylimidazolium chloride([bmim]Cl)were measured.Six sets of complete T,x,y data are reported,in which the 2-propanol mole fraction on IL-free basis is...Vapor-liquid equilibrium(VLE)data for water+2-propanol+1-butyl-3-methylimidazolium chloride([bmim]Cl)were measured.Six sets of complete T,x,y data are reported,in which the 2-propanol mole fraction on IL-free basis is fixed separately at 0.1,0.2,0.4,0.6,0.8,and approximate 0.98,while the IL mass fraction is varied from 0.1 to 0.8,in an interval of 0.1.The non-random-two-liquid(NRTL)and electrolyte non-random-two-liquid(eNRTL)equations are used to correlate the experimental data with satisfactory results.The ternary VLE behavior is also modeled with the parameters obtained by correlating two data sets,in which the mole fraction of 2-propanol on IL-free basis is approximately 0.1 and 0.98.In this way,the six sets of data are reproduced satisfactorily.With the eNRTL model,the root-mean-square deviation for temperature is 0.82 K and that for vapor-phase mole fraction is 0.0078.The influences of IL on activity coefficients and relative volatility of the volatile components are also graphically illustrated.展开更多
In the field of underwater survey, there is a variety of methods which differ from each other in terms of the operating environment and the purpose that each method is used. Hence, some of the state-of-the-art methods...In the field of underwater survey, there is a variety of methods which differ from each other in terms of the operating environment and the purpose that each method is used. Hence, some of the state-of-the-art methods, that have many applications in the various scientific fields nowadays, are introduced in this paper. Additionally, the application of the procedures for an underwater survey in shallow depths is analyzed in accordance with the training standards of the PADI Underwater Survey Diver distinctive specialty. The main goal is to demonstrate not only the theoretical background of underwater surveys but also their operational issues, in order to facilitate the development of knowledge and skills during a training course. Finally, a case study for the recording and 3D modeling of the seabeds' morphology in shallow water is presented as it has been organized and accomplished by the participants of such a training course. By this way, it is expected that the reader will understand explicitly the application of the procedures prior, during and after the dive for an underwater survey in shallow depths.展开更多
In a teaching experiment, Japanese Grade 9 students investigated how to measure the height of an aerial balloon using different models involving angles and distances, and also to evaluate the models they developed. As...In a teaching experiment, Japanese Grade 9 students investigated how to measure the height of an aerial balloon using different models involving angles and distances, and also to evaluate the models they developed. As novices to mathematical modelling, they needed to decide which of several possible models were both valid and practicable, and the errors in measurement that are likely to arise. Opportunities to construct and use paper models, as scale reductions of the real situation, and discussing their results in small groups were effective in moving forward the thinking of many students on the dimensions mentioned above. While students were less able to identify different sources of errors, many came to appreciate the need to learn trigonometric techniques that are more suitable in dealing with problems of this kind.展开更多
Assessing large-scale patterns of gross primary production (GPP) in arid and semi-arid (ASA) areas is important for both scientific and practical purposes.Remote sensing-based models,which integrate satellite data wit...Assessing large-scale patterns of gross primary production (GPP) in arid and semi-arid (ASA) areas is important for both scientific and practical purposes.Remote sensing-based models,which integrate satellite data with input from ground-based meteorological measurements and vegetation characteristics,improve spatially extended estimates of vegetation productivity with high accuracy.In this study,the authors simulated GPP in ASA areas by integrating moderate resolution imaging spectral radiometer (MODIS) data with eddy covariance and meteorological measurements at the flux tower sites using the Vegetation Photosynthesis Model (VPM),which is a remote sensing-based model for analyzing the spatial pattern of GPP in different land cover types.The field data were collected by coordinating observations at nine stations in 2008.The results indicate that in the region during the growing season GPP was highest in cropland sites,second highest in woodland sites,and lowest in grassland sites.VPM captured the temporal and spatial characteristics of GPP for different land covers in ASA areas.Further,Enhanced Vegetation Index (EVI) had a strong liner relationship with GPP in densely vegetated areas,while the Normalized Difference Vegetation Index (NDVI) had a strong liner relationship with GPP over less dense vegetation.This study demonstrates the potential of satellite-driven models for scaling-up GPP,which is a key component for studying the carbon cycle at regional and global scales.展开更多
This work constitutes a contribution to the study of the physical-chemical performance of some heavy metals and micro-nutrients in the Argan trees. The samples are harvested from small Argan trees, three samples (soi...This work constitutes a contribution to the study of the physical-chemical performance of some heavy metals and micro-nutrients in the Argan trees. The samples are harvested from small Argan trees, three samples (soil, wood, leaves) per tree. The content of various heavy metals and micro-nutrient in aerial parts (leaves, wood and soil) were analyzed in the Argan tree by the method of ICP-ES. The results of analysis of data for the chemical variables were measured for several trees at different measurement times, do not affect the dispersion of the data. The use of chemometrics has allowed us to interpret the results obtained especially those related to the characterization of heavy metals and micro-nutrient after calibration by variable regression of these results in order to get an overall estimate of the optimal content, and to follow changes in the methods of treatment. The results of the characteristics of Argan trees have been treated using the statistical method of Principal Component Analysis (MFA), The MFA was used to analyze the three groups simultaneously. These groups are fairly similar.展开更多
3D reconstruction of terrain model based on digital line graphics (DLG) is discussed. An auto-coupling triangles algo-rithm based on triangle topological relationship is put forward, and the topological data model of ...3D reconstruction of terrain model based on digital line graphics (DLG) is discussed. An auto-coupling triangles algo-rithm based on triangle topological relationship is put forward, and the topological data model of complicated terrain is developed. Based on this data model, automatic 3D topological reconstruction of terrain is realized.展开更多
A model to describe the hysteresis damping characteristic of rubber material was presented.It consists of a parallel spring and damper,whose coefficients change with the vibration amplitude and frequency.In order to a...A model to describe the hysteresis damping characteristic of rubber material was presented.It consists of a parallel spring and damper,whose coefficients change with the vibration amplitude and frequency.In order to acquire these relations,force decomposition was carried out according to some sine vibration measurement data of nonlinear forces changing with the deformation of the rubber material.The nonlinear force is decomposed into a spring force and a damper force,which are represented by the amplitude-and frequency-dependent spring and damper coefficients,respectively.Repeating this step for different measurements gives different coefficients corresponding to different amplitudes and frequencies.Then,the application of a parameter identification method provides the requested approximation functions over amplitude and frequency.Using those formulae,as an example,the dynamic characteristic of a hollow shaft system supported by rubber rings was analyzed and the acceleration response curve in the centroid position was calculated.Comparisons with the sine vibration experiments of the real system show a maximal inaccuracy of 8.5%.Application of this model and procedure can simplify the modeling and analysis of mechanical systems including rubber materials.展开更多
基金Supported by the National High Technology Research and Development Program of China (2006AA040309)National BasicResearch Program of China (2007CB714000)
文摘Presented is a multiple model soft sensing method based on Affinity Propagation (AP), Gaussian process (GP) and Bayesian committee machine (BCM). AP clustering arithmetic is used to cluster training samples according to their operating points. Then, the sub-models are estimated by Gaussian Process Regression (GPR). Finally, in order to get a global probabilistic prediction, Bayesian committee mactnne is used to combine the outputs of the sub-estimators. The proposed method has been applied to predict the light naphtha end point in hydrocracker fractionators. Practical applications indicate that it is useful for the online prediction of quality monitoring in chemical processes.
基金Supported by the National Natural Science Foundation of China (60421002) and priority supported financially by "the New Century 151 Talent Project" of Zhejiang Province.
文摘To overcome the problem that soft sensor models cannot be updated with the process changes, a soft sensor modeling algorithm based on hybrid fuzzy c-means (FCM) algorithm and incremental support vector machines (ISVM) is proposed. This hybrid algorithm FCMISVM includes three parts: samples clustering based on FCM algorithm, learning algorithm based on ISVM, and heuristic sample displacement method. In the training process, the training samples are first clustered by the FCM algorithm, and then by training each clustering with the SVM algorithm, a sub-model is built to each clustering. In the predicting process, when an incremental sample that represents new operation information is introduced in the model, the fuzzy membership function of the sample to each clustering is first computed by the FCM algorithm. Then, a corresponding SVM sub-model of the clustering with the largest fuzzy membership function is used to predict and perform incremental learning so the model can be updated on-line. An old sample chosen by heuristic sample displacement method is then discarded from the sub-model to control the size of the working set. The proposed method is applied to predict the p-xylene (PX) purity in the adsorption separation process. Simulation results indicate that the proposed method actually increases the model's adaptive abilities to various operation conditions and improves its generalization capability.
文摘Atmospheric sulfur deposition onto typical farmland in East China was investigated using both field measurements and numerical modeling. The field measurements were conducted at the Experiment Station of Red Soil Ecology, Chinese Academy of Sciences, 10 km from Yingtan, Jiangxi Province, East China, between November 1998 and October 1999, and at the Changshu Ecological Experiment Station, Chinese Academy of Sciences, in a rapidly developing region of Jiangsu Province, East China, between April 2001 and Marc…
文摘River Ghataprabha, during its course through Belgaum district in Karnataka state (India), receives untreated domestic waste from Gokak town and other neighboring villages situated on the bank of the river. The present study involves the application of water quality model QUAL2K to predict the water quality of this polluted segment of the river. The model was calibrated and validated for biochemical oxygen demand (BOD), dissolved oxygen (DO) and total nitrogen (TN) in pre-monsoon season. Data for calibration and validation were obtained after the field and laboratory measurements. The performance of the model was evaluated using statistics based on standard errors (SE) and mean multiplicative errors (MME). The model represented the field data quite well with some exceptions. In spite of some differences between the measured and simulated data sets at some points, the calibration and validation results are acceptable especially for the developing countries where the financial resources are often limited for frequent monitoring campaigns and higher accuracy data analysis.
基金Financial support for this work was provided by the Frontier Research Plan Key Program of Central South University (No.2010QZZ001)the Open Projects of State Key Laboratory of CoalResources and Mine Safety, CUMT (No. 11KF02)
文摘Aimed at the CMS laser scanning theory and characteristic, a combined actual situation of stope N4-5 of Fankou Lead-Zinc Mine and complementary monitoring of the stope were carried out by carefully choos- ing two measuring points. The cavity 3D visible model was created by large-scale mining industry soft- ware Surpac after changing the measured data. The stope mine design model, bottom structural model and backfill model of the south and north sides of the stope N4-5 were established according to the stope design data. On this basis, the stope block model was established, and then block attribute was estimated. The amount the ore remains, mullock, backfill and total mined ore were calculated through the solid model restrains. Finally, the stope mining dilution rate and loss rate reached 8.2% and 1.47%, respectively. The practice indicates that the mining index visible calculation method based on cavity 3D monitoring and stope block modeling can make up the deficiency of adopting the solid model to directly carry out the Boolean operation, The stope mining indexes obtained by this method are accurate and reliable, and can be used to guide the actual nroduction management and estimate the mining aualitv.
基金Project 50279005 supported by the National Natural Science Foundation of China
文摘To ensure the safety of buildings surrounding foundation pits, a study was made on a settlement monitoring and trend prediction method. A statistical testing method for analyzing the stability of a settlement monitoring datum has been discussed. According to a comprehensive survey, data of 16 stages at operating control point, were verified by a standard t test to determine the stability of the operating control point. A stationary auto-regression model, AR(p), used for the observation point settlement prediction has been investigated. Given the 16 stages of the settlement data at an observation point, the applicability of this model was analyzed. Settlement of last four stages was predicted using the stationary auto-regression model AR (1); the maximum difference between predicted and measured values was 0.6 mm, indicating good prediction results of the model. Hence, this model can be applied to settlement predictions for buildings surrounding foundation pits.
文摘In the Pearl River Delta (PRD), there is severe competition between container ports, particularly those in Hong Kong, Shenzhen, and Guangzhou, for collecting international maritime container cargo. In addition, the second phase of the Nansha terminal in Guangzhou’s port and the first phase of the Da Chang Bay container terminal in Shenzhen opened last year. Under these circumstances, there is an increasing need to quantitatively measure the impact these infrastructure investments have on regional cargo flows. The analysis should include the effects of container terminal construction, berth deepening, and access road construction. The authors have been developing a model for international cargo simulation (MICS) which can simulate the movement of cargo. The volume of origin-destination (OD) container cargo in the East Asian region was used as an input, in order to evaluate the effects of international freight transportation policies. This paper focuses on the PRD area and, by incorporating a more detailed network, evaluates the impact of several infrastructure investment projects on freight movement.
基金supported by Geran Putra IPS(Vote No.:9469400),University Putra Malaysia
文摘The solubility of red palm oil (RPO) in supercritical carbon dioxide (scCO2) was determined using a dynamic method at 8.5-25 MPa and, 313.15-333.15 K and at a fixed scCO2 flow rate of 2.9 g. mn -1 using a full factorial design. The solubility was determined under low pressures and temperatures as a preliminary study for RPO par- ticle formation using scCO2. The solubility of RPO was 0.5-11.3 mg. (g CO2) -1 and was significantly affected by the pressure and temperature. RPO solubility increased with pressure and decreased with temperature. The Adachi-Lu model showed the best-fit for RPO solubility data with an average relative deviation of 14% with a high coefficient of determination, R2 of 0.9667, whereas the Peng-Robinson equation of state thermodynamic model recorded deviations of 17%-30%.
基金Supported by the National Natural Science Foundation of China(61104218,21006127)the National Basic Research Program of China(2012CB720500)the Science Foundation of China University of Petroleum(YJRC-2013-12)
文摘The processes of building dynamic and static relationships between secondary and primary variables are usually integrated in most of nonlinear dynamic soft sensor models. However, such integration limits the estimation accuracy of soft sensor models. Wiener model effectively describes dynamic and static characteristics of a system with the structure of dynamic and static submodels in cascade. We propose a soft sensor model derived from Wiener model structure, which is an extension of Wiener model. Dynamic and static relationships between secondary and primary variables are built respectively to describe the dynamic and static characteristics of system. The feasibility of this model is verified. Then the expression of discrete model is derived for soft sensor system. Conjugate gradient algorithm is applied to identify the dynamic and static model parameters alternately. Corresponding update method for soft sensor system is also given. Case studies confirm the effectiveness of the proposed model, alternate identification algorithm, and update method.
基金Supported by the National Natural Science Foundation of China (20776132)
文摘Vapor-liquid equilibrium(VLE) data were measured for ternary system water + ethanol + 1-butyl-3methylimidazolium acetate([bmim][OAc]),in a relatively wide range of ionic liquid(IL) mass fractions up to 0.8.Six sets of complete T-x-y data were obtained,in which the mole fraction of ethanol on IL-free basis was fixed separately at 0.1,0.2,0.4,0.6,0.8,and approximate 0.98.The non-random-two-liquid(NRTL) and electrolyte non-random-two-liquid(eNRTL) equations were used for correlation,showing similar deviations.The ternary VLE was also modeled with the correlation from two data sets,with the mole fractions of ethanol on IL-free basis being 0.1 and approximate 0.98.The VLE data were also reproduced satisfactorily.With the eNRTL model,the root-mean-square deviation for temperature is 0.79 K and that for vapor-phase mole fraction is 0.0094.The calculations are in good agreement with experimental data.The effect of the IL on the VLE behavior of the volatile components is also illustrated.
文摘The Arizona Department of Transportation (ADOT) in the USA conducted a series of asphalt aging related research and special studies between the 1970s and 1990s. The studies covered over 157 test sections representing both neat (virgin) asphalt and crumb rubber modified (asphalt-rubber) binders. The data comprised of a wide range of penetration, viscosity, and Performance Grade (PG) parameters, at original and aged conditions. In the late 1990s, asphalt PG complex shear modulus (G*), and phase angle (5) data were collected. The main purpose of this paper was to use the assembled database of the field core-aged asphalt test data and compare the test results to the American Association of State Highway and Transportation Officials approved Mechanistic-Empirical Pavement Design Guide (MEPDG) predictive modeled asphalt properties such as penetration and viscosity, G*, and 5. Furthermore, G* and laboratory measurements on neat and asphalt-rubber binders extracted from the field cores of the pavement sections aged ten or more years were compared to the pressure aging vessel PG G* and ~. values. It was observed that the MEPDG predicted asphalt binder properties were rational for originally (tank) sampled binders, but fairly correlated for the aged binders. Additionally, penetration and viscosity aging indices representing over 20 years of field aged sections were established for a wide variety of asphalt binder grades. Overall, the relationships for aging indices were meaningful and rational. Results of this research indicated the degree of difficulty in predicting asphalt binder properties for pavements with ten or more years of field aging. The findings from this research study are envisioned to be of substantial value in future asphalt binder aging studies.
基金Supported by the National Natural Science Foundation of China(51178446,21206168)
文摘The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H2S removal. The solubility of HzS in JM-T was measured at 298, 313,333,353, and 368 K with H2S partial pressures from 20 to 760 kPa and HzS loading from 0.02 to 0.8 mol H2S per mol JM-T. Relevant physical properties, such as density, viscoslty and dielectric constant, ot the matenal were measured. 'The thermodynamlc model with two-suttlX Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore, the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.
基金Supported by the National Natural Science Foundation of China(20776132)the Natural Science Foundation of Zhejiang Province(Y4100699)
文摘Vapor-liquid equilibrium(VLE)data for water+2-propanol+1-butyl-3-methylimidazolium chloride([bmim]Cl)were measured.Six sets of complete T,x,y data are reported,in which the 2-propanol mole fraction on IL-free basis is fixed separately at 0.1,0.2,0.4,0.6,0.8,and approximate 0.98,while the IL mass fraction is varied from 0.1 to 0.8,in an interval of 0.1.The non-random-two-liquid(NRTL)and electrolyte non-random-two-liquid(eNRTL)equations are used to correlate the experimental data with satisfactory results.The ternary VLE behavior is also modeled with the parameters obtained by correlating two data sets,in which the mole fraction of 2-propanol on IL-free basis is approximately 0.1 and 0.98.In this way,the six sets of data are reproduced satisfactorily.With the eNRTL model,the root-mean-square deviation for temperature is 0.82 K and that for vapor-phase mole fraction is 0.0078.The influences of IL on activity coefficients and relative volatility of the volatile components are also graphically illustrated.
文摘In the field of underwater survey, there is a variety of methods which differ from each other in terms of the operating environment and the purpose that each method is used. Hence, some of the state-of-the-art methods, that have many applications in the various scientific fields nowadays, are introduced in this paper. Additionally, the application of the procedures for an underwater survey in shallow depths is analyzed in accordance with the training standards of the PADI Underwater Survey Diver distinctive specialty. The main goal is to demonstrate not only the theoretical background of underwater surveys but also their operational issues, in order to facilitate the development of knowledge and skills during a training course. Finally, a case study for the recording and 3D modeling of the seabeds' morphology in shallow water is presented as it has been organized and accomplished by the participants of such a training course. By this way, it is expected that the reader will understand explicitly the application of the procedures prior, during and after the dive for an underwater survey in shallow depths.
文摘In a teaching experiment, Japanese Grade 9 students investigated how to measure the height of an aerial balloon using different models involving angles and distances, and also to evaluate the models they developed. As novices to mathematical modelling, they needed to decide which of several possible models were both valid and practicable, and the errors in measurement that are likely to arise. Opportunities to construct and use paper models, as scale reductions of the real situation, and discussing their results in small groups were effective in moving forward the thinking of many students on the dimensions mentioned above. While students were less able to identify different sources of errors, many came to appreciate the need to learn trigonometric techniques that are more suitable in dealing with problems of this kind.
基金supported by the National Basic Research Program of China (Grant Nos. 2009CB723904 and 2006CB400500)
文摘Assessing large-scale patterns of gross primary production (GPP) in arid and semi-arid (ASA) areas is important for both scientific and practical purposes.Remote sensing-based models,which integrate satellite data with input from ground-based meteorological measurements and vegetation characteristics,improve spatially extended estimates of vegetation productivity with high accuracy.In this study,the authors simulated GPP in ASA areas by integrating moderate resolution imaging spectral radiometer (MODIS) data with eddy covariance and meteorological measurements at the flux tower sites using the Vegetation Photosynthesis Model (VPM),which is a remote sensing-based model for analyzing the spatial pattern of GPP in different land cover types.The field data were collected by coordinating observations at nine stations in 2008.The results indicate that in the region during the growing season GPP was highest in cropland sites,second highest in woodland sites,and lowest in grassland sites.VPM captured the temporal and spatial characteristics of GPP for different land covers in ASA areas.Further,Enhanced Vegetation Index (EVI) had a strong liner relationship with GPP in densely vegetated areas,while the Normalized Difference Vegetation Index (NDVI) had a strong liner relationship with GPP over less dense vegetation.This study demonstrates the potential of satellite-driven models for scaling-up GPP,which is a key component for studying the carbon cycle at regional and global scales.
文摘This work constitutes a contribution to the study of the physical-chemical performance of some heavy metals and micro-nutrients in the Argan trees. The samples are harvested from small Argan trees, three samples (soil, wood, leaves) per tree. The content of various heavy metals and micro-nutrient in aerial parts (leaves, wood and soil) were analyzed in the Argan tree by the method of ICP-ES. The results of analysis of data for the chemical variables were measured for several trees at different measurement times, do not affect the dispersion of the data. The use of chemometrics has allowed us to interpret the results obtained especially those related to the characterization of heavy metals and micro-nutrient after calibration by variable regression of these results in order to get an overall estimate of the optimal content, and to follow changes in the methods of treatment. The results of the characteristics of Argan trees have been treated using the statistical method of Principal Component Analysis (MFA), The MFA was used to analyze the three groups simultaneously. These groups are fairly similar.
文摘3D reconstruction of terrain model based on digital line graphics (DLG) is discussed. An auto-coupling triangles algo-rithm based on triangle topological relationship is put forward, and the topological data model of complicated terrain is developed. Based on this data model, automatic 3D topological reconstruction of terrain is realized.
基金Project(50675042) supported by the National Natural Science Foundation of China
文摘A model to describe the hysteresis damping characteristic of rubber material was presented.It consists of a parallel spring and damper,whose coefficients change with the vibration amplitude and frequency.In order to acquire these relations,force decomposition was carried out according to some sine vibration measurement data of nonlinear forces changing with the deformation of the rubber material.The nonlinear force is decomposed into a spring force and a damper force,which are represented by the amplitude-and frequency-dependent spring and damper coefficients,respectively.Repeating this step for different measurements gives different coefficients corresponding to different amplitudes and frequencies.Then,the application of a parameter identification method provides the requested approximation functions over amplitude and frequency.Using those formulae,as an example,the dynamic characteristic of a hollow shaft system supported by rubber rings was analyzed and the acceleration response curve in the centroid position was calculated.Comparisons with the sine vibration experiments of the real system show a maximal inaccuracy of 8.5%.Application of this model and procedure can simplify the modeling and analysis of mechanical systems including rubber materials.