基于污泥浓度分区技术的理论研究

提出采用筛网(Mesh)过滤组件进行污泥浓度分区(A区和B区)的技术,解决单独MBR系统零剩余污泥排放条件下污泥浓度过高的问题。对此技术进行物料衡算,并从理论上分析A区、B区VSS(XA、XB)的变化规律。结果表明,XA随着HRTA值的增大而降低;XB随着R值的增大而降低,且随着筛网出水VSS(XA,B)的升高而增大。当XB维持在固定值时,XA,B随着R的变大而升高;XA随着R的变大而缓慢降低,从理论上证明此技术的可行性。

小回流比条件下污泥浓度分区试验研究

用次毫米过滤(sub-milliFiltration,SMF)组件将生物处理系统内的污泥分为高浓度区和低浓度区,使高浓度区保持大量污泥,强化对有机物的去除,使低浓度区污泥浓度满足膜分离的要求.主要验证了小回流比(R为0.5、1.0、1.5、2.0)条件下污泥浓度分区的效果,考察了采用SMF组件后,系统对COD的去除效果,并将各小回流比条件下A、B两区污泥浓度的理论值和实测值做比较.结果表明,在小回流比条件下可实现污泥浓度分区,低浓度区的MLSS在9 g.L-1以下,高浓度区的MLSS在20 g.L-1以上;系统的COD平均去除率超过90%;A、B两区MLVSS的理论值与实测值具有相关性.

SMF-MBR工艺污泥浓度分区及除污性能研究

针对MBR在长污泥龄下运行时,由高污泥浓度引起的出水水质恶化问题,开发了SMF-MBR工艺进行污泥浓度分区,从而实现膜区在较低污泥浓度下运行,在保证出水水质的前提下,减缓膜污染。以中浓度生活污水(COD为500 mg/L)为处理对象的试验结果表明,SMF组件具有良好的污泥浓度分区效果,有效地减缓了污泥浓度对膜污染的影响。该工艺的除污效果良好,对COD、NH3-N、TN的平均去除率分别为95.9%、99.2%和73.7%,出水平均浓度分别为20.1、0.24和10.43 mg/L,达到了《城镇污水处理厂污染物排放标准》(GB 18918—2002)的一级A标准。

Correspondence of bubble size and frother partitioning in flotation

The size of bubbles created in the flotation process is of great importance to the efficiency of the mineral separation achieved.Meanwhile,it is believed that frother transport between phases is perhaps the most important reason for the interactive nature of the phenomena occurring in the bulk and froth phases in flotation,as frother adsorbed in the surface of rising bubbles is removed from the bulk phase and then released into the froth as a fraction of the bubbles burst.This causes the increased concentration in the froth compared to the bulk concentration,named as frother partitioning.Partitioning reflects the adsorption of frother on bubbles and how to influence bubble size is not known.There currently exists no such a topic aiming to link these two key parameters.To fill this vacancy,the correspondence between bubble size and frother partitioning was examined.Bubble size was measured by sampling-for-imaging(SFI)technique.Using total organic carbon(TOC)analysis to measure the frother partitioning between froth and bulk phases was determined.Measurements have shown,with no exceptions including four different frothers,higher frother concentration is in the bulk than in the froth.The results also show strong partitioning giving an increase in bubble size which implies there is a compelling relationship between these two,represented by CFroth/CBulk and D32.The CFroth/CBulkand D32 curves show similar exponential decay relationships as a function of added frother in the system,strongly suggesting that the frother concentration gradient between the bulk solution and the bubble interface is the driving force contributing to bubble size reduction.

MEASUREMENTS OF PARTICLE NUMBER SIZE DISTRIBUTIONS AND NEW PARTICLE FORMATION EVENTS DURING WINTER IN THE PEARL RIVER DELTA REGION,CHINA

Particle number size distribution(PNSD) between 10 nm and 20 μm were measured in the Pearl River Delta(PRD) region in winter 2011.The average particle number concentration of the nucleation mode(10-20 nm),Aitken mode(20-100 nm),accumulation mode(100 nm-1μm) and coarse mode(1-20 μm) particles were 1 552,7 470,4 012,and 19 cm-3,respectively.The volume concentration of accumulation mode particles with peak at 300 nm accounted for over 70% of the total volume concentration.Diurnal variations and dependencies on meteorological parameters of PNSD were investigated.The diurnal variation of nucleation mode particles was mainly influenced by new particle formation events,while the diurnal variation of Aitken mode particles correlated to the traffic emission and the growth process of nucleation mode particles.When the PRD region was controlled by a cold high pressure,conditions of low relative humidity,high wind speed and strong radiation are favorable for the occurrence of new particle formation(NPF) events.The frequency of occurrence of NPF events was 21.3% during the whole measurement period.Parameters describing NPF events,including growth rate(GR) and source rate of condensable vapor(Q),were slightly larger than those in previous literature.This suggests that intense photochemical and biological activities may be the source of condensable vapor for particle growth,even during winter in the PRD.

Sources and distribution of polycyclic aromatic hydrocarbons of different glaciers over the Tibetan Plateau

Twenty snow samples were collected from the Qiyi glacier in Qilian Mountains,the Yuzhufeng glacier in eastern Kunlun Mountains,the Xiaodongkemadi glacier in Tanggula Mountains,and the Gurenhekou glacier in Nyainqêntanglha Range over the Tibetan Plateau.The concentration and distribution features of sixteen priority Polycyclic Aromatic Hydrocarbons (PAHs) were determined by gas chromatography equipped with a mass spectrometry detector (GC-MS).The sources of these PAHs were explored as well.Our results indicated that the average concentrations of PAHs in snow were in the range of 20.45 60.57 ng/L.Maximum PAHs levels were found in the YZF glacier andminimum in the XDKMD glacier.However,no apparent regional distribution pattern of PAHs was found in the glaciers over the Tibetan Plateau.Moreover,the 2 4 ring low molecular weight PAHs predominated in snow samples and the concentrations of phenanthrene was the highest.Integrated factor analysis and isomer pair ratios suggested that PAHs of glaciers over the Tibetan Plateau were derived from low temperature combustion of coal and biomass,and partially from the exhaust gas of locomotives.Air mass back trajectory indicated that organic compounds detected in snowpit of these four glaciers,in the period of time they represented,mainly came from Central Asia and the arid area of Northwest China by westerly wind circulation.

Spatial distribution of marine chemicals along a transect from Zhongshan Station to the Grove Mountain area, Eastern Antarctica

This study investigates the regional distribution of marine aerosol originated species （Na＋, CI-, nss-SO42- and MSA） in the snow pits （or firn cores） collected along a transect between Zhongshan Station and the Grove Mountain area （450 km inland） on the eastern side of the Lambert Glacier Basin. Concentrations of Na＋ and Cl- decrease exponentially with distance from the coast to 100 km inland （i.e., 1500 m a.s.1.）. Statistical results demonstrate that distance from the coast inland and elevation af-fect the concentration of sea-salt originated ions in inland areas significantly. Increase of Cl-/Na＋ ratio and higher variability in its standard deviation suggest that there are other sources of ions in addition to sea-salt in inland areas of the Antarctic conti- nent. The concentrations of Na＋ and Cl- from nine sampling sites in the Grove Mountain area are relatively higher than those from sites along CHINARE transect, although all sites are at similar distance inland. This phenomenon indicates that the barri- er effect of the mountain may be the most important factor influencing ion deposition. In addition, nss-SO42- and MSA vary differently, with nss-SO42- decreasing with distance more significantly. This implies that sources and transporting pathways influence the deposition of the two sulfur compounds considerably, being supported by the spatial pattern of correlation coeffi- cients between the nss-SO42- and MSA.