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非线性化学动力学发展的新阶段——浓度场方程及浓度场理论 被引量:1
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作者 张少军 李松杰 +1 位作者 杜江 王成铎 《化工进展》 EI CAS CSCD 北大核心 2019年第1期1-13,共13页
在综述各种非线性化学动力学研究发展的基础上,重点介绍了最新研究成果浓度场理论的主要内容。该理论根据质量作用定律和广义相对性原理,构建了非线性复杂反应动力学方程即浓度场方程,并给出了扩散、结晶、吸附、传热及相变等9种基本动... 在综述各种非线性化学动力学研究发展的基础上,重点介绍了最新研究成果浓度场理论的主要内容。该理论根据质量作用定律和广义相对性原理,构建了非线性复杂反应动力学方程即浓度场方程,并给出了扩散、结晶、吸附、传热及相变等9种基本动力学类型的机理指数,解决了热分析动力学积分不收敛、理论基础不完善等问题,合理解释了分形子动力学所谓"记忆效应"和"分数级反应级数"问题,并在通过数学方程和图线全面、直观、定量表达并解释化学振荡、化学分岔、多重定态等各种非线性化学现象的同时,给出了"三级反应的双解性质,是产生各种非线性化学现象的根本原因"的重要结论。浓度场方程及浓度场理论具有很强的理论研究和实际应用价值。 展开更多
关键词 非线性动力学 热分析动力学 分形子动力学 浓度方程 浓度场理论
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Aggregation Behaviors of a Two-Species System with Lose-Lose Interactions
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作者 宋美霞 林振权 +1 位作者 李晓东 柯见洪 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第6期1190-1200,共11页
We propose an aggregation evolution model of two-species (A- and B-species) aggregates to study the prevalent aggregation phenomena in social and economic systems. In this model, A- and B-species aggregates perform ... We propose an aggregation evolution model of two-species (A- and B-species) aggregates to study the prevalent aggregation phenomena in social and economic systems. In this model, A- and B-species aggregates perform self-exchange-driven growths with the exchange rate kernels K(k, l) = Kkl and L(k, l) = Lkl, respectively, and the two species aggregates perform self-birth processes with the rate kernels J1(k) = J1 k and J2( k ) = J2k, and meanwhile the interaction between the aggregates of different species A and B causes a lose-lose scheme with the rate kernel H(k,l) = Hkl. Based on the mean-field theory, we investigated the evolution behaviors of the two species aggregates to study the competitions among above three aggregate evolution schemes on the distinct initial monomer concentrations A0 and B0 of the two species. The results show that the evolution behaviors of A- and B-species are crucially dominated by the competition between the two self-birth processes, and the initial monomer concentrations Ao and Bo play important roles, while the lose-lose scheme play important roles in some special cases. 展开更多
关键词 kinetic behavior lose-lose scheme scaling law rate equation
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