用激光拉曼频移测定乙醇水溶液的浓度

为了进一步探索用激光拉曼光谱测定乙醇水溶液中乙醇浓度的方法,研究了室温下C-H伸缩振动频移与溶液浓度的关系。室温下,在Renishaw 1000型激光拉曼光谱仪上测得了不同浓度乙醇水溶液在5004 000 cm^-1的拉曼光谱,发现溶液位于2 8003 050 cm^-1的3个C-H伸缩振动特征峰的峰值位置相对纯乙醇对应峰位的偏移量大致与乙醇浓度呈线性相关。对各峰峰值位置随浓度变化发生偏移的实验数据进行一元线性回归,然后利用回归结果进一步进行二元线性回归,得到乙醇浓度与C-H伸缩振动频率变化量的回归模型。实验结果表明,C-H对称伸缩振动峰（位于2 882cm^-1附近）对应的回归方程决定系数为0.962 2,-CH3非对称伸缩振动峰（位于2 977 cm-1附近）对应的回归方程决定系数为0.965 0,此二峰的频移量均与浓度呈现出较高的线性相关度,据此建立的二元回归方程决定系数达到0.98,可以用于常温下乙醇浓度的测定。实验研究表明,用激光拉曼光谱中乙醇分子的C-H伸缩振动频移测定室温下乙醇水溶液的浓度是可行的。

Prediction of oxygen concentration and temperature distribution in loose coal based on BP neural network

An effective method for preventing spontaneous combustion of coal stockpiles on the ground is to control the air-flow in loose coal. In order to determine and predict accurately oxygen concentrations and temperatures within coal stockpiles, it is vital to obtain information of self-heating conditions and tendencies of spontaneous coal combustion. For laboratory conditions, we designed our own experimental equipment composed of a control-heating system, a coal column and an oxygen concentration and temperature monitoring system, for simulation of spontaneous combustion of block coal （13-25 mm） covered with fine coal （0-3 mm）. A BP artificial neural network （ANN） with 150 training samples was gradually established over the course of our experiment. Heating time, relative position of measuring points, the ratio of fine coal thickness, artificial density, voidage and activation energy were selected as input variables and oxygen concentration and temperature of coal column as output variables. Then our trained network was applied to predict the trend on the untried experimental data. The results show that the oxygen concentration in the coal column could be reduced below the minimum still able to induce spontaneous combustion of coal - 6% by covering the coal pile with fine coal, which would meet the requirement to prevent spontaneous combustion of coal stockpiles. Based on the prediction of this ANN, the average errors of oxygen concentration and temperature were respectively 0.5% and 7 ℃, which meet actual tolerances. The implementation of the method would provide a practical guide in understanding the course of self-heating and spontaneous combustion of coal stockpiles.

Determining suspended sediment concentration and settling velocity from PC-ADP measurements in the Beibu Gulf, China

Modeling sediment transport depends on several parameters, such as suspended sediment concentration （SSC）, shear stress, and settling velocity. To assess the ability of Pulse-Coherent Acoustic Doppler Profiling （PC-ADP） to non-intrusively quantify spatial and temporal SSC and settling velocity at seabed, a field experiment was conducted in the Beibu Gulf （Tonkin Gulf）, in the South China Sea. The spatial profiles and temporal variations in SSC at 1 m above bottom were derived from PC-ADP acoustic backscatter intensity determinations after being calibrated with the optical backscatter sensor （OBS） measurements at the same elevation. The PC-ADP and OBS results agreed well. The temporal settling velocity obtained from Rouse profiles agreed well with the Soulsby formula based on size information by LISST （laser in situ scattering and transmissometry）. Tides and tidal currents are diurnal in the gulf. SSC increased with increasing ebb and flood flow, and it rapidly decreased with the increase of distance from the seabed. The maximum SSC at 0.16 m and 1.3 m above bottom reached 816 mg/L and 490 mg/L during spring tides, respectively. The sediments consisted of mineral particles 23-162 μm in diameter and 0.05-2.04 crn/s in settling velocity. Generally, both the SSC and settling velocity followed variations in the bottom friction. Results suggest that PC-ADP is able to provide reasonable SSC and settling velocity measurements of both profiles and time series for a long study period.

Solubility and metastable zone width measurement of 3,4-bis (3-nitrofurazan-4-yl) furoxan (DNTF) in ethanol + water

The solubility and supersolubility of 3,4-bis(3-nitrofurazan-4-yl)furoxan(DNTF) in ethanol + water at different operation were determined by laser monitoring system under atmospheric pressure to study the metastable zone width(MSZW). The modified Apelblat equation was adopted to correlate the experimental solubility data, and the correlation result showed perfect consistent with the experimental data. The standard dissolution enthalpy, standard dissolution entropy and Gibbs energy were calculated according to the experimental solubility data. The effect of the cooling rate, stirring rate, temperature and the concentration of ethanol + water on the MSZW was studied. It was found that the MSZW of DNTF increased with the increasing cooling rate, decreasing temperature, decreasing stirring rate and decreasing ratio of water. And the apparent nucleation order of DNTF in ethanol + water was calculated by the relationship between the cooling rate and the MSZW.

Gradient Step Method to Predict the Ozone Solubility in Water

In this work it presents a strategy to obtain the ozone solubility in water by gradient step method. In this methodology, the ozone in mixture with oxygen is bubbling in a reactor with distilled water at 21℃ and pH 7. The ozone concentration on gas phase is continually increased after the saturation is reached. The method proposed is faster than conventional method （isocratic method）. The solubility from the gradient method is compared with that values obtained from correlations founded in the literature.

Effect of Transport Times on Welfare of Pigs

The aim of the study was to investigate effect of transport times of up to 12 h on pigs＇ welfare. An observation box was located on the 3rd floor of the vehicle. Device to measure temperature, humidity and video camera to monitor pigs＇ behaviors were fitted in the box. Eighteen measurements were performed during two seasons for 4, 8, and 12 h of transport time with three replications. Meat samples were taken from longissimus dorsi （LD） and the carcases were chilled for 24 h at ＋4 ~C for pH determination. To determine cortisol, glucose, lactate, and creatine kinase concentration levels, blood samples were collected before and after transport from 90 pigs and from 20 controls that were not transported for control purposes. To evaluate behavioural alterations, frequency of events and durations were considered. Highest pH24 of 5.99 ＋ 0.29 occurred during summer at 12 h transport time. Cortisol concentrations elevated during short and decreased with an increase of transport time （P 〈 0.001）. Highest and lowest glucose concentrations for winter and summer were at 8 and 12 h transport time, respectively （P 〈 0.01）. Concentrations of lactate and creatine kinase positively correlated with transport time （P 〈 0.002）. Lying, sitting, rooting and vocalization behaviours correlated with transport time （P 〈 0.009）. Certain THI values during summer surpassed normal （〉 74） level during loading. The pH24 value correlated with transport time during summer. Lactate and creatine kinase concentrations increased with an increase in transport time but for Glucose, highest value was at 8 h transport time.

An all optical fiber gas sensor of NH3 and CO based on based on the spectral absorption and harmonic detection

An all optical fiber gas sensor is presented to detect the concentration of NH3 and CO. Based on the spectral absorption, The wideband light source is used to reflect two narrowband spectra by fiber grating of different duty. and piezoelectric ceramics to obtain narrowband output light. The high sensitivity detection can be measured from the second harmonic signal. The two narrowband spectra are corresponding to the absorption spectra of NH3 and CO. Concentration detection are realized by the detection of variety of light intensity. Sensitivity is proved and cost is reduced.

Research on the Drunk Driving Intelligent Test System Based onμC/OS- II

The article design the hardware system scheme using STM32F407 as the control core circuit, and designed the software structure of the system and application layer multi task and priority based on transplanted μ C/OS operating system. Aimed at that the traditional drunk driving detection system has low sensitivity and unable to distinguish diffuse alcohol sigmal interference. For accurate identification of pilot and crew alcohol concentration, the paper puts forward a driving intelligent identification wine system based on embedded μC/OS- II. The experimental results show that the detection sensitivity of the system has high accuracy rate, effectively prevent the purpose for the prevention of drunk driving, drunk driving has very good practical value.

Air Pollution Concentration Approach to Potential Area Selection of the Air Quality Monitoring Station in Nakhon Ratchasima Municipality, Thailand

The purpose of the study is to generate traffic air information system） to determine a proper zone of AQMS （air analyzed were carbon monoxide （CO）, and nitrogen oxides （NOx） pollution map using mathematical model and GIS （geographic quality monitoring station） in municipality area. The pollutants which can be harmful to people living in the area. The three steps of mapping process were performed under the GIS environment using the existing vehicle emission rates and pollutant dispersion model. First, traffic volume, road network, and the emission rates of road segments varying with types of vehicle were collected from existing data. Second, the pollutant concentrations were calculated by use of CALINE4, a tool with Gaussian dispersion model. The model parameters include emission rate, wind directions and speeds, ambient temperature and observed pollutant concentration, and atmospheric stability during all seasons from the January 1, 2010 to May 31,2011 with regardless the rainy season. This resulted in concentrations at many receptor points along links of the road network. Third, distributions of pollution concentrations were generated by means of the spatial interpolation of those from receptors. The results of pollution raster-based maps are used for determining frequency of violence and combined pollution map. The resulting frequency of violence and intensity concentration will be further integrated to determine a potential area of AQMS. Finally, achieving pollution potential area of AQMS can be located as helpful basic data for efficient traffic and transportation planning.

Development of 2D Temperature and Concentration Measurement Method Using Tunable Diode Laser Absorption Spectroscopy

Exhaust gas temperature is an important factor in NOx, THC and PM emissions of engines. Especially 2D temperature and concentration distribution plays an important role for the engine efficiency. A thermocouple is intrinsically a point temperature measurement method and noncontact 2D temperature distribution cannot be attained by thermocouples. Recently, as a measurement technique with high sensitivity and high response, laser diagnostics has been developed and applied to the actual engine combustions. With these engineering developments, transient phenomena such as start-ups and load changes in engines have been gradually elucidated in various conditions. In this study, the theoretical and experimental research has been conducted in order to develop the noncontact and fast response 2D temperature and concentration distribution measurement method. The method is based on a Computed Tomography （CT） method using absorption spectra of water vapor at 1388 nm. It has been demonstrated that the method has been successfully applied to engine exhausts to measure 2D temperature distributions.

Experimental assessment of a new salt aerosol generator for measuring efficiency of automotive air filters

Generation of polydisperse KCl aerosol with a new salt aerosol generator was investigated, Special attention was paid on particles with diameters between 3 and 10 μm. The main improvement consists of the different routes of KCl solution droplets. In traditional generators, the solution droplets travel through one cylinder; while in the case analyzed here, after spray atomization, the droplets travel through two cylinders in series. The first cylinder was fed with warm air and the second one with cold air. In such way, the complete evaporation of the water from the droplets can be ensured. The influencing factors of the generated aerosol size distribution were investigated. The data measured show that the concentration of generated aerosol becomes higher both increasing the flow rate of the KCI solution injected in the first cylinder and increasing the concentration in the solution. The temperature of solution influences mainly the generation of smaller KCI particles （0,3-3 μm）. The amount of hot air used in the generation process increases the concentration of larger KC1 particles （〉3 μm） while cold air does not have the same effect. The aerosol generator is able to generate KC1 aerosol stably. This instrument can be used effectively for testing air filters for automotive.

Evaluation of Metal Contamination of Mullet （Mullus surmuletus L., 1758） in the Bay of Oran

The present study focused on the evaluation of the contamination by three heavy metals （Cd, Cu and Zn） of a bony fish, Mullus surmuletus L., 1758, caught in the Bay of Oran. This reflects the quality of fish habitat as species common Algerian coastal waters and enjoyed by a large fish-eating population. Monthly sampling was spread over a period of six months （December 2011-May 2012）. Given their physiological importance in the body, muscle, liver and gonads were targeted. Metal concentrations were determined by atomic absorption spectrophotometry in flame depends on three parameters （sex, size and month）. It appears from this study that the target organs of rouget （M. surmuletus） accumulate three metal pollutants sought. The highest values are those of zinc, copper and cadmium are at concentrations at least important. The results, statistically treated, showed no significant difference between the concentrations of trace metals both sexes and at all three organs considered. The average dose of heavy metals found in the mullet compared to those provided by the literature relating to DMA （Maximum Allowable Doses）, are not worrisome. Concentration levels of toxic metals reflect a certain metal pollution in the Bay of Oran.

Investigating Mercury Existence in Some Stations in Tigris River in Iraq

Mercury concentration in water, sediments and two aquatic plants were measured in the Tigris River for the period in 2013 Hg concentrations in water between 0.18-0.74 μg/g, however, in sediments ranged between 0.66-0.73 lag/g. The concentrations of accumulated mercury in aquatic plants ranged in Ceratophyllum demersum and Phragmitus australis were 0.035-0.022, 0.028-0.023 μg/g, respectively. The concentration bioconcentration factor B.C.F range between 0.331-0.209 μg/g and B.S.F 0.043-0.011 μg/g. These results indicate the ability of the aquatic plants of Tigris River to accumulate elements in their tissues more than water consequently, mercury concentrations in the food chain path way could cause health problems on public health by transfer through aquatic organisms to human. The studied plants could be considered as bioindicator for elements flow to the river from natural and anthropogenic sources. The study showed there is an increase in the concentration of this element in the Tigris River and due to the low rate of discharge of river water, which leads to high concentrations of ions dissolved and effect divorced industrial waste and sewage and irrigation water, especially in the area of Zafaraniyah a result of the large number of events industrialized as well as the impact of the Diyala River on the River Tigris.

Comparison of the effects of carbamyl-β-methylcholine chloride ad ministered by intravenous,intramuscular and intra-acupuncture point injections

OBJECTIVE:To compare the effects of carbamylβ-methylcholine chloride(CMCC) administered by intra-acupuncture point injection(IAI),intramuscular injection(IMI),and intravenous injection(IVI),and to analyze the mechanisms.METHODS:In the IAI group,CMCC was injected into the Zusanli acupoint(ST 36) immediately after 30-min stimulation by electro-acupuncture(EA) at the acupoints,and into the femoral vein and skeletal muscle in IVI and IMI groups,respectively.Intra-gastric pressure was detected.The plasma concentration of CMCC was measured at various times.RESULTS:The gastric effect of CMCC in the IVI group was enhanced and attenuated more rapidly than in the other groups.In the IAI group,this effect was significantly stronger than that in the IMI group at 2 min and 15 min,but not significantly different between the two groups at 5 min and 30 min.Plasma concentration of CMCC in the IAI group was similar to that in the IVI group at 2 min,but higher than that in the IMI group.The concentration in the IAI group was higher than that in the IV group and similar to that in the IMI group at 5,15 and 30 min,indicating rapid increase and slower reduction of the plasma concentration of the drug in the IAI group.There was a positive correlation between the plasma concentration of CMCC and intragastric pressure in all groups.CONCLUSION:The effect of IAI with CMCC was stronger than that of IMI and longer-lasting than that of IVI,which correlated with the blood concentration of CMCC.

Transformation and source of nutrients in the Changjiang Estuary

The concentrations of phosphate （PO43 ）, ammonium, nitrite, nitrate, silicate, dissolved organic nitrogen （DON）, dissolved or- ganic phosphorus （DOP）, particulate phosphorus （PP） and particulate nitrogen （PN） along the salinity gradient were measured in the Changjiang Estuary in April 2007. The behavior of nutrient species along the continuum from the freshwater to the coastal zone is discussed. In the mixing zone between the riverine and marine waters, nitrate and phosphate behave non-conservatively, while silicate behaves conservatively. Nutrient import was quantified from the fiver load. Nutrient export to the sea was quantified from fiver discharge and from the salinity-nutrient gradient in the outer estuary. Using these data, a nitrogen and phosphorus budget was made. The internal estuarine fluxes played an important role in the nutrient estuarine fluxes, which accounted for approximately 41% of the nitrogen flux and 45% of the phosphorus flux. The mixing experiments in the laboratory generally reproduced well the inorganic process affecting nutrient dynamics in the Changjiang Estuary, indi- cating that the primary P and N transformation processes were phosphate and nitrate desorption along the salinity gradient.

Investigation of Detailed Kinetic Scheme Performance on Modelling of Turbulent Non-Premixed Sooting Flames

This paper presents the results of an application of a first-order conditional moment closure （CMC） approach coupled with a semi-empirical soot model to investigate the effect of various detailed combustion chemistry schemes on soot formation and destruction in turbulent non-premixed flames. A two-equation soot model repre- senting soot particle nucleation, growth, coagulation and oxidation, was incorporated into the CMC model. The turbulent flow-field of both flames is described using the Favre-averaged fluid-flow equations, applying a stan- dard k-c turbulence model. A number of five reaction kinetic mechanisms having 50 - 100 species and 200 - 1000 elementary reactions called ABF, Miller-Bowman, GRI-Mech3.0, Warnatz, and Qin were employed to study the effect of combustion chemistry schemes on soot predictions. The results showed that of various kinetic schemes being studied, each yields similar accuracy in temperature prediction when compared with experimental data. With respect to soot prediction, the kinetic scheme containing benzene elementary reactions tends to result in a better prediction on soot concentrations in comparison to those contain no benzene elementary reactions. Among five kinetic mechanisms being studied, the Qin combustion scheme mechanism turned to yield the best prediction on both flame temperature and soot levels.

Influence of ring-down cavity parameters on intensity transmission property in trace gas concentration measurement

In this paper, we describe the basic principles and system design of continuous wave cavity ring-down spectroscopy （CWCRDS）. We also particularly study the nature and the behavior of a novel method to detune a laser and apply it to a cavity ring-down spectroscopy experiment. Both simulations and experiments are completed on the relation between the transmission characteristic and different refiectivities, as well as scanning speed. Output electric field equation is deduced. It has been investigated that how photons are coupled to the cavity and how to accumulate the intensity and leak out of the cavity as a function of time. It is noted that both accumulation of intensity and decay times decrease, and the oscillation amplitude increases as the reflectivity increases. Relative intensity increases with decreasing scanning velocity. Additionally, the simulations show that a non-detuned cavity displays the transmitted signals which are highly dependent on the mirror reflectivity and piezoelectric translator （PZT） modulation speed. Simulations also display that the laser switching off is different from dettming.

Significant downward trend of SO_2 observed from 2005 to 2010 at a background station in the Yangtze Delta region,China

SO2 is an important gas in atmosphere with great environmental and climate implications.SO2 emission in China has been receiving great attention as the economy grows and the amount of coal consumption has increased in the past few decades.SO2 has been observed from July 2005 to June 2010 at Linan WMO GAW regional station(30.3 °N,119.73 °E,138 m a.s.l.) located in the Yangtze Delta region in eastern China.These observation data are analyzed to understand the trend of regional SO2 background concentration.Strict quality controls are conducted to ensure the temporal comparability of the data.Significant downward trend with ?2.4 ppb/yr(P < 0.0001) of surface SO2 is observed from 2005 to 2010,especially after 2008.The average concentration of SO2 from July 2005 to June 2008 is 14.2±3.1 ppb,which is slightly higher than the mean values of 13.5±5.1 ppb during 1999?2000 and is two folds of the average value(7.1±3.1 ppb) from July 2008 to June 2010.More than 50% of the SO2 has been cut down after 2008 in the Yangtze Delta region due to the implementation of stricter emission control measures.The peak SO2 concentration appears around 10 o'clock in the morning after 2009 while appears at night before 2009.These diurnal variations of SO2 might indicate that after 2009,more SO2 is from the vertical exchange process than from the local accumulation.