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聚乙烯基咪唑对2,6-二甲基苯酚氧化聚合中底物的浓缩效应
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作者 张文丽 王奂 +1 位作者 申屠宝卿 翁志学 《高校化学工程学报》 EI CAS CSCD 北大核心 2013年第4期610-614,共5页
制备了铜-聚乙烯基咪唑(Cu(Ⅱ)-PVI)络合物,用于催化水介质中2,6-二甲基苯酚(DMP)的氧化聚合,与传统催化剂Cu(Ⅱ)-EDTA络合物相比,其催化效率约提高十倍。为探究Cu(Ⅱ)-PVI络合物催化效率提高的原因,采用N,N’-亚甲撑-二(丙烯酰胺)作为... 制备了铜-聚乙烯基咪唑(Cu(Ⅱ)-PVI)络合物,用于催化水介质中2,6-二甲基苯酚(DMP)的氧化聚合,与传统催化剂Cu(Ⅱ)-EDTA络合物相比,其催化效率约提高十倍。为探究Cu(Ⅱ)-PVI络合物催化效率提高的原因,采用N,N’-亚甲撑-二(丙烯酰胺)作为交联剂与N-乙烯基咪唑共聚合制备了PVI水凝胶。采用紫外可见吸收光谱研究了PVI水凝胶对DMP的吸附量随时间的变化,发现水溶液中DMP的浓度先随时间延长而降低,而PVI水凝胶中DMP的浓度则随时间延长而增加,最后达到平衡,说明PVI对反应底物DMP有浓缩效应。认为Cu(Ⅱ)-PVI络合物催化水介质中DMP氧化聚合反应时,其催化效率的提高归结为PVI微团对催化剂和反应底物的浓缩效应。 展开更多
关键词 聚乙烯基咪唑 2 6-二甲基苯酚 氧化聚合 催化剂 浓缩效应
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高温水沸腾条件下模拟缺陷的浓缩效应
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作者 Ashm.,CB 张运 《云南电力技术》 1991年第2期59-72,共14页
关键词 高温水 模拟缺陷 浓缩效应
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微生物复合菌剂对污泥好氧堆肥过程的影响 被引量:17
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作者 欧阳建新 施周 +2 位作者 崔凯龙 钟华 梁运姗 《中国环境科学》 EI CAS CSCD 北大核心 2011年第2期253-258,共6页
研究了黄孢原毛平革菌与枯草芽孢杆菌复合菌剂在剩余污泥静态强制通风好氧堆肥中的作用.结果表明,根据堆肥过程中的温度(0~5d为中温阶段,6~12d为高温阶段,16~28d为腐熟阶段)变化,复合菌剂的变化导致堆体细菌数量明显高于空白堆体,且... 研究了黄孢原毛平革菌与枯草芽孢杆菌复合菌剂在剩余污泥静态强制通风好氧堆肥中的作用.结果表明,根据堆肥过程中的温度(0~5d为中温阶段,6~12d为高温阶段,16~28d为腐熟阶段)变化,复合菌剂的变化导致堆体细菌数量明显高于空白堆体,且堆体中的嗜热真菌在高温期显著增多,促进了有机物的降解,加速了堆体的腐熟.试验组萝卜种子发芽指数(GI)相对空白组提前3d达到了50%,表明复合菌剂的加入迅速地降低了堆体的生物毒性,但由于相对浓缩效应使得堆肥产品Cd含量略有增加。 展开更多
关键词 剩余污泥 复合菌剂 静态强制通风好氧堆肥 种子发芽指数 相对浓缩效应
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上海近郊五种农作物重金属含量的测定及分析 被引量:2
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作者 杨士军 张琳琳 《人民长江》 北大核心 2012年第S1期140-141,182,共3页
选用常食用的芋头、山药等根茎农作物作为研究对象,对上海近郊5种农作物的重金属污染状况进行调查,并通过实验对其含量进行测定,分析了土壤与农作物中重金属的污染水平,以及不同农作物品种重金属含量的差别。对不同污染水平的土壤对重... 选用常食用的芋头、山药等根茎农作物作为研究对象,对上海近郊5种农作物的重金属污染状况进行调查,并通过实验对其含量进行测定,分析了土壤与农作物中重金属的污染水平,以及不同农作物品种重金属含量的差别。对不同污染水平的土壤对重金属的浓缩效应进行了对比,并据此考察其健康安全风险。结果显示,上海近郊土壤和农作物已受到重金属污染,且某些元素含量已超过规定值,应引起足够重视。 展开更多
关键词 重金属 浓缩效应 测定 湿地农作物 上海近郊
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化工塔器设计若干问题的探讨 被引量:1
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作者 许开天 《化工装备技术》 CAS 2001年第2期7-14,共8页
就酒精初馏塔进料层的浓缩效应、入塔前的物料状态和条件。
关键词 化工塔器 塔板 蒸馏 酒精 浓缩效应
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Zonal disintegration phenomenon in rock mass surrounding deep tunnels 被引量:9
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作者 WU Hao FANG Qin GUO Zhi-kun 《Journal of China University of Mining and Technology》 EI 2008年第2期187-193,共7页
Zonal disintegration is a typical static phenomenon of deep rock masses. It has been defined as alternating regions of fractured and relatively intact rock mass that appear around or in front of the working stope duri... Zonal disintegration is a typical static phenomenon of deep rock masses. It has been defined as alternating regions of fractured and relatively intact rock mass that appear around or in front of the working stope during excavation of a deep tunnel. Zonal disintegration phenomenon was successfully demonstrated in the laboratory with 3D tests on analogous gypsum models, two circular cracked zones were observed in the test. The linear Mohr-Coulomb yield criterion was used with a constitutive model that showed linear softening and ideal residual plastic to analyze the elasto-plastic field of the enclosing rock mass around a deep tunnel. The results show that tunneling causes a maximum stress zone to appear between an elastic and plastic zone in the surrounding rock. The zonal disintegration phenomenon is analyzed by considering the stress-strain state of the rock mass in the vicinity of the maximum stress zone. Creep instability failure of the rock due to the development of the plastic zone, and transfer of the maximum stress zone into the rock mass, are the cause of zonal disintegration. An analytical criterion for the critical depth at which zonal disintegration can occur is derived. This depth depends mainly on the character and stress concentration coefficient of the rock mass. 展开更多
关键词 block-hierarchical structure zonal disintegration phenomenon enclosing rock mass around deep tunnel equivalent material stress concentration coefficient
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Maltose Concentration by Ultrafiltration
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作者 WANG Hong-bo 《Chinese Food Science》 2012年第1期23-24,30,共3页
[Objective] The aim was to study on effect of maltose concentration by ultrafiltration.[Method] 40% and 15% maltose syrups were concentrated using ultrafiltration membranes at molecular weight of 6 000 Da in order to ... [Objective] The aim was to study on effect of maltose concentration by ultrafiltration.[Method] 40% and 15% maltose syrups were concentrated using ultrafiltration membranes at molecular weight of 6 000 Da in order to study on concentration effect of maltose and restoration effect of membranes property through backflushing.[Result] When 40% maltose was concentrated with the membrane,membrane flux weakened rapidly and pores blocked.In contrast,when 15% maltose was concentrated with the same membrane,the membrane flux was high and weakened very slowly.Dextrose equivalent(DE) and luminousness changed from 43% and 91%T before filtration to 50% and 98%T after filtration,respectively.[Conclusion] The research provides a practical method to improve transparency of maltose products and extend quality guarantee period. 展开更多
关键词 ULTRAFILTRATION CONCENTRATION MALTOSE China
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