1260m^3高炉探尺控制系统的改进

“七五”期间,国内自行设计的4座高炉中(含唐钢)首次采用探尺可控硅直流调速系统;由于初次设计,又没有较全面的结合生产工艺过程合理的选择控制方式,使唐钢1260m^3高炉投产后,探尺控制系统不能满足生产工艺要求,多次发生探尺尺头掉入炉内事故,不仅增加了休风率,而且造成亏料线作业、炉况难行的不良后果,极大地束缚了高炉的生产能力。通过对运行中暴露问题的分析,我们对系统进行了改进,现介绍如下。

SINAMICS S120变频器在高炉探尺控制系统中的应用

为满足高炉生产工艺日益精细化的需求;探尺控制系统必须实现精准捕捉生产料面。结合西门子SINAMICS;S120变频器的独特性能;探尺控制系统可实现在速度控制方式和转矩控制方式之间快速切换;根据下降的速度变化精确判断生产中料面的异常变化;保证系统平稳、可靠、安全的运行。

Effects of frothers on bubbles size and flotation performance of hydrophobic minerals

Frothers facilitate the reduction of bubbles size by preventing bubbles coalescence and produce more stable froths.The collision probability of the bubbles and particles substantially increases by decreasing bubble size.For the same volume system,fewer bubbles result from a distribution of large-sized bubbles,and more bubbles result from a distribution of small-sized bubbles.In this research,fundamental two-phase frother characterization parameters were aimed to link with three-phase coal and talc flotation behavior.For this purpose,the effect of single and dual frother systems on inhibiting bubble coalescence was investigated with methyl isobutyl carbinol(MIBC),isooctanol(2 ethyl hexanol),pine oil,and Dowfroth 250.Based on the results of single frothers,isooctanol at the lowest critical coalescence concentration(CCC)value of 6×10^(−6) achieved the smallest bubbles with Sauter mean diameter of 0.80 mm.By blending Dowfroth 250 and pine oil,the bubbles size decreased significantly,reaching 0.45 mm.While the highest recoveries in coal flotation were obtained in single and frother blends where the bubbles size was measured as the smallest in two-phase system,and such a relationship was not found for talc flotation.

Improved YOLOv5-Based Inland River Floating Garbage Detection Model

Detection of floating garbage in inland rivers is crucial for water environmental protection,as it effectively reduces ecological damage and ensures the safety of water resources.To address the inefficiency of traditional cleanup methods and the challenges in detecting small targets,an improved YOLOv5 object detection model was proposed in this study.In order to enhance the model’s sensitivity to small targets and mitigate the impact of redundant information on detection performance,a bi-level routing attention mechanism was introduced and embedded into the backbone network.Additionally,a multi-scale detection head was incorporated into the model,allowing for more comprehensive coverage of floating garbage of various sizes through multi-scale feature extraction and detection.The Focal-EIoU loss function was also employed to optimize the model parameters,improving localization accuracy.Experimental results on the publicly available FloW_Img dataset demonstrated that the improved YOLOv5 model outperforms the original YOLOv5 model in terms of precision and recall,achieving a mAP(mean average precision)of 86.12%,with significant improvements and faster convergence.

Evaluation of effect of viscosity changes on bubble size in a mechanical flotation cell

In operating flotation plants, the viscosity of the pulp can vary significantly. Consequently, the resulting impact on bubble size is of interest as many plants experience seasonal changes in water temperature, or particle size changes as ore hardness, mineralogy and throughput fluctuate. However, given its importance in flotation, there existed no mathematical relationship linking bubble size created in flotation machines to the key process variable of fluid viscosity. In this study, a program of investigation to develop such a model was utilizing a pilot-scale mechanical flotation machine, to investigate the effect of water viscosity due to temperature on bubble size distribution. The bubble sizes were determined using a specific bubble viewer and imaging technology. The temperature itself was varied as a method for introducing significant viscosity change. The viscosity-temperature effect introduced a correspondingly significant change in the water viscosity（1619 to 641 μPa·s）. It is suggested that a considerably stronger relationship may exist, yielding D32 versus（μ/μ20）0.776, and hence viscosity becomes an important design consideration for plants operating where pulp temperature fluctuations, very small particles or high solid fractions are present.

Nano-microbubble flotation of fine and ultrafine chalcopyrite particles

As is well known to mineral processing scientists and engineers, fine and ultrafine particles are difficult to float mainly due to the low bubble-particle collision efficiencies. Though many efforts have been made to improve flotation performance of fine and ultrafine particles, there is still much more to be done. In this paper, the effects of nano-microbubbles （nanobuhbles and microbubbles） on the flotation of fine （-38 ＋ 14.36 μm） and ultrafine （-14.36 ＋ 5μm） chalcopyrite particles were investigated in a laboratory scale Denver flotation cell. Nano-microbubbles were generated using a specially-designed nano- microbubble generator based on the cavitation phenomenon in Venturi tubes. In order to better under- stand the mechanisms of nano-microbubble enhanced froth flotation of fine and ultrafine chalcopyrite particles, the nano-microbubble size distribution, stability and the effect of frother concentration on nano- bubble size were also studied by a laser diffraction method. Comparative flotation tests were performed in the presence and absence of nano-microbubbles to evaluate their impact on the fine and ultrafine chalcopyrite particle flotation recovery. According to the results, the mean size of nano-microbubbles increased over time, and decreased with increase of frother concentration. The laboratory-scale flotation test results indicated that flotation recovery of chalcopyrite fine and ultrafine particles increased by approximately 16-21% in the presence of nano-microbubbles, depending on operating conditions of the process. The presence of nano-microbubbles increased the recovery of ultrafine particles （-14.36 ＋ 5 μm） more than that of fine particles （-38 ＋ 14.36 μm）. Another major advantage is that the use of nano-microbubbles reduced the collector and frother consumptions by up to 75% and 50%, respectively.

Correspondence of bubble size and frother partitioning in flotation

The size of bubbles created in the flotation process is of great importance to the efficiency of the mineral separation achieved.Meanwhile,it is believed that frother transport between phases is perhaps the most important reason for the interactive nature of the phenomena occurring in the bulk and froth phases in flotation,as frother adsorbed in the surface of rising bubbles is removed from the bulk phase and then released into the froth as a fraction of the bubbles burst.This causes the increased concentration in the froth compared to the bulk concentration,named as frother partitioning.Partitioning reflects the adsorption of frother on bubbles and how to influence bubble size is not known.There currently exists no such a topic aiming to link these two key parameters.To fill this vacancy,the correspondence between bubble size and frother partitioning was examined.Bubble size was measured by sampling-for-imaging(SFI)technique.Using total organic carbon(TOC)analysis to measure the frother partitioning between froth and bulk phases was determined.Measurements have shown,with no exceptions including four different frothers,higher frother concentration is in the bulk than in the froth.The results also show strong partitioning giving an increase in bubble size which implies there is a compelling relationship between these two,represented by CFroth/CBulk and D32.The CFroth/CBulkand D32 curves show similar exponential decay relationships as a function of added frother in the system,strongly suggesting that the frother concentration gradient between the bulk solution and the bubble interface is the driving force contributing to bubble size reduction.

Bubble size measurement in three-phase system using photograph technology

A special experiment setup was designed to observe the interaction between bubbles and particle in flotation cell and to analyze the bubble characteristics such as bubble size, distribution and bubble-loading efficiency. Bubbles in water-gas system and three-phase system were measured. The results indicate that with the current setup the bubbles as small as 10 μm can be easily distinguished. The average size of the bubbles generated under the given conditions in two-phase system is 410 μm at frother concentration of 0.004%, which is in good correspondence with the results of other works. The effect of frother on bubble size was probed. Increasing frother concentration from 0 to 0.004% causes a reduction of bubble size from 700 to 400 μm. The bubble loading efficiency was reported. The result indicates that the fine particle is more easily entrapped than the coarse particle. Some factors, which have effect on measurement accuracy were discussed. The aeration speed has a significant effect on the accuracy of results, if it surpasses 30 mL/s, and the image becomes unclear due to the entrapment of fine particle. Another factor, which can affect observing results, is the sampling position. At a wrong sampling position, the images become unclear.

A novel approach to prevent bubble coalescence during measurement of bubble size in flotation

Effect of frothers in preventing bubble coalescence during flotation of minerals has long been investigated.To evaluate the performance of a frother,an apparatus to measure the bubble size is a basic necessity.McGill Bubble Size Analyzer(MBSA) or bubble viewer that has been developed and completed by McGill University's Mineral Processing Group during the last decade is a unique instrument to serve this purpose.Two parameters which are thought to influence the bubble size measurements by McGill bubble viewer include water quality and frother concentration in the chamber.Results show that there is no difference in Sauter mean(D32) when tap or de-ionized water was used instead of process water.However,the frother concentration,in this research DowFroth 250(DF250),inside the chamber exhibited a pronounced effect on bubble size.Frother concentration below a certain point can not prevent coalescence inside the chamber and therefore caution must be taken in plant applications.It was also noted that the frother concentration which has been so far practiced in plant measurements(CCC75-CCC95) is high enough to prevent coalescence with the bubble viewer.

A dynamic size-based time series feature and application in identification of zinc flotation working conditions

Conventional feature description methods have large errors in froth features due to the fact that the image during the zinc flotation process of froth flotation is dynamic,and the existing image features rarely have time series information.Based on the conventional froth size distribution characteristics,this paper proposes a size trend core feature(STCF)considering the froth size distribution,i.e.,a feature centered on the time series of the froth size distribution.The core features of the trend are extracted,the inter-frame change factor and the inter-frame stability factor are given and two calculation methods of the feature factors are proposed.Meanwhile,the STCF feature algorithm was established based on the core features by adding the inter-frame change factor and the inter-frame stability factor.Finally,a flotation condition recognition model based on BP neural network was established.The experiments show that the recognition model has achieved excellent results,proving that the method proposed effectively overcomes the limitation of the lack of dynamic information in the existing traditional size distribution features and the introduction of the two factors can improve the classification accuracy to varying degrees.

论《金匮要略》对黄疸理论的贡献及临床指导意义

黄疸是感受湿热疫毒,肝胆气机郁滞,疏泄失常,致使胆汁外溢所致的以身、目、小便俱黄为临床特征的疾病。分为阴黄、阳黄和急黄。《金匮要略》对黄疸的论述颇深,对后世中医黄疸的理论发展有深远意义,现浅析如下。1 首论因机,为后世黄疸分型奠定基础《金匮要略》认为,黄疸之病本乎先天禀赋不足,五脏内虚,加之外邪侵袭所致。故有"寸口脉浮而缓,浮则为风,缓则为痹,痹非中风,四肢苦烦,脾色必黄,瘀热以行","趺阳脉紧而数,数即为热,热则消谷;紧即为寒,食则为满。尺脉浮为伤肾,趺阳脉紧为伤脾"之论。

Hydrogen bubble fiotation of fine minerals containing calcium

One characteristic of electro-flotation is the presence of micro bubbles that are well known for improving the flotation performance of fine particles. An electro-flotation method was studied with fine scheelite and fluorite particles sized into three different fractions. Experiments were performed in a modified Hallimond tube. We investigated the effects of gas holdup, particle size, and different mesh electrode apertures on mineral recovery. Flotation results show that two size fractions show increased flotation recovery as the gas holdup increases. For the sized scheelite and fluorite, the flotation effect is diverse for different sizes of the cathode aperture. Pictures of the bubbles taken by a high speed CCD were used to determine the hydrogen bubble size distribution generated as a function of collector, current density, and electrode size. The diameters of the hydrogen bubbles ranged from 12 to 117μm in alkaline conditions.

Bubble size as a function of some situational variables in mechanical flotation machines

The specific results of the work investigating the effect of gas density and water temperature on bubble size were present.These were surrogate variables designed to investigate the effect of viscosity(varying water temperature) and altitude(varying gas density).The results show that there is a measurable but relatively small effect of gas density on bubble size.The D32 is revealed to increase proportionally as(ρ0/ρg)0.132.The projected impact on flotation kinetics at 4500 m versus sea level is small,of the order of 0.5% recovery loss for a bank of eight flotation cells.The effect of water temperature(4-40 °C) on bubble size is more significant than gas density.The relationship correlates with water viscosity values quite closely.A finding that D32 increases proportionally as(μ/μ20)0.776 highlights the importance of accounting for viscosity effects if,for example,large process temperature fluctuations or deviation from design/test conditions are expected.

Mesoscale structure of the central South China Sea detected by SCSMEX Buoy and Argo float

We addressed the mesoscale structure variation of the central South China Sea （SCS） with the measurements by a long-lived Argo float and a high-resolution ATLAS buoy during 1998-2002. T-S diagram indicates cooling and freshening events in 2000 and 2001 with lower salinity （0.5-0.8） and lower temperature （1-1.7℃）. Significant decrease in the net heat flux and increase in the precipitation suggest that the cooling and freshening is due to extra forcing by the atmosphere. Additional to large year-to-year changes, intraseasonal variability is moderate in the research area. The axis of the maximum intraseasonal temperature and salinity signals are mainly located on the thermocline, Typically, amplitude and period of intraseasonal temperature is about 2℃ and 40-60 days, and that of salinity is 0.34）.5 and 35-60 days. Rapidly-changing winds, heat flux, and precipitation are critical in controlling the intraseasonal fluctuations of the mixed layer of the area. Studies on heat and freshwater balance in the mixed-layer further suggest that horizontal advection plays an important role in intraseasonal fluctuation in the upper ocean. In addition, the energetic mesoscale propagation radiated from the east boundary is linked to the intraseasonal variability in winter.

Physical properties and filter cake structure of fine clean coal from flotation

In order to improve the dewatering rate and the effect of fine clean coal(FCC), the advanced method offine coal( 0.5 mm) dewatering and the correlated basic theory were investigated in this study. It was found that the dewatering by sleeve type press filter was an efficient way of FCC dewatering. On the other hand, the results also proved that particle size distribution, volatile matter, ash content, pore size distribution and specific surface area of coal particles of FCC samples, as well as viscosity and density of FCC slurry, were important parameters in determining the process of efficient dewatering. Especially, wet mass to dry mass, specific resistance of average mass, compressibility factor and microstructure of filter cake explained the reasons and mechanisms of fine clean coal efficient dewatering.

Characterization of Atomization Processes in Suspension/Emulsion Sprays

The characterization of suspension/emulsion sprays plays a decisive role in many industrial processes. A good example of such a process is the drying of a milk spray to produce milk powder, where the process efficiency and product quality is typically controlled by atomization parameters like flow rate, pressure, etc.. However, these parameters influence directly the droplet size and droplet velocity distributions in a spray, so that optimizing a spray drying process often involves adjusting the spray to a desired droplet size and droplet velocity distribution. This requires a measurement technique capable of characterizing in real time, the droplets in a suspension/emulsion spray. To achieve this aim, we present developments to the well-known time-shift technique for spray measurements.

High-efficiency laser-irradiation spheroidizing of NiCo_2O_4 nanomaterials

We realized the desired spheroidizing of NiCo_2O_4 nanomaterials by laser irradiating NiCo_2O_4 suspensions with different concentrations. The results reveal that the as-prepared samples are desired spheres with the maximal average size of 568 nm and the superior dispersity, which were obtained at the energy density of 0.30 J·pulse^(-1)·cm^(-2) and NiCo_2O_4 suspension concentration of 0.2 mg·mL^(-1). However, the phase segregation, which was induced by large amounts of solid redox of Co^(3+)/Co^(2+) and Ni^(3+)/Ni^(2+), also appears in the laser-irradiation process.