The floatability of andalusite and quartz was studied using sodium petroleum sulfonate as collector, being successfully applied in the real ore separation. The collecting performance on minerals was interpreted by mea...The floatability of andalusite and quartz was studied using sodium petroleum sulfonate as collector, being successfully applied in the real ore separation. The collecting performance on minerals was interpreted by means of zeta potential measurement and infrared spectroscopic analysis. The single mineral experiments showed that andalusite got good floatability in acidic pH region while quartz exhibited very poor floatability in the whole pH range. At pH 3, the presence of Fe3+ obviously activated quartz, causing the identical flotation behavior of the two minerals, and calcium lignosulphonate exhibited good selective inhibition to quartz. The real ore test results showed that andalusite concentrate with 53.46% Al2O3 and quartz concentrate with 92.74% SiO2 were obtained. The zeta potential and infrared spectroscopic analysis results indicated that chemical adsorption occurred between sodium petroleum sulfonate and andalusite.展开更多
The flotation behavior of Xixia andalusite was studied with different collectors.The tests were conducted with a pure andalusite sample in micro-flotation cell and then with an ore sample in a mechanical flotation cel...The flotation behavior of Xixia andalusite was studied with different collectors.The tests were conducted with a pure andalusite sample in micro-flotation cell and then with an ore sample in a mechanical flotation cell.The surface charge was measured on pure andalusite sample and the isoelectric point(IEP) was found to be pH 5.2.Andalusite is floated with an amine collector above IEP where mineral surface is negatively charged.In contrast,an alkyl sulfonate collector(sodium dodecyl benzene sulfonate) is effective in the pH range where andalusite surface is positively charged.Furthermore,andalusite is floated with oleate in neutral and mildly alkaline pH values.55.3% Al2O3 is produced with 75.6% andalusite recovery when using the alkyl benzene sulfonate collector.Starch is found to be an effective depressant for gangue minerals in alkyl benzene sulfonate flotation.Moreover,slimes are found to have an adverse effect on the flotation of andalusite.Therefore,pretreatment by desliming and pre-float(to remove carbonaceous species) prior to andalusite flotation is necessary.展开更多
Coal is the world's most abundant fossil fuel.Coal froth flotation is a widely used cleaning process to separate coal from mineral impurities.Flotation of coarse coal particles,ultrafine coal particles and oxidize...Coal is the world's most abundant fossil fuel.Coal froth flotation is a widely used cleaning process to separate coal from mineral impurities.Flotation of coarse coal particles,ultrafine coal particles and oxidized coal particles is well known to be difficult and complex.In this paper,the nanobubbles' effects on the flotation of the varying particle size,particle density and floatability coal samples were evaluated using a bank of pilot scale flotation cells,a laboratory scale and a pilot scale specially designed flotation column.The parameters evaluated during this study include the flow rate ratio between the nanobubble generator and the conventional size bubble generator,the superficial air velocity,collector dosage,frother concentration,flotation feed rate,feed solids concentration,feed particle size,and the superficial wash water flow rate,etc.The results show that the use of nanobubbles in a bank of mechanical cells flotation and column flotation increased the flotation recovery by 8%~27% at a given product grade.Nanobubbles increased the flotation rate constants of 600~355,355~180,180~75,and 75~0 microns size coal particles by 98.0%,98.4%,50.0% and 41.6%,respectively.The separation selectivity index was increased by up to 34%,depending on the flotation feed characteristics and the flotation conditions.展开更多
In our study we investigated a refractory copper-nickel sulfide ore separation by using a cyclonic-static micro-bubble flotation column (FCSMC). The process mineralogy of the main products was studied. Using a scannin...In our study we investigated a refractory copper-nickel sulfide ore separation by using a cyclonic-static micro-bubble flotation column (FCSMC). The process mineralogy of the main products was studied. Using a scanning electron microscope-energy dispersive system (SEM-EDS) and an X-ray spectrometer the mineral category and content of samples were analyzed. By using a mineral liberation analyzer (MLA) the mineral liberation characteristics were revealed. It is shown that in roughing feed the monomers liberation degree of nickel pyrite and chalcopyrite take up 84.11% and 88.82%, respectively. In tailings, the lost nickel pyrite and chalcopyrite are mainly monomers. Therefore, strengthening the micro-fine particle recovery capacity is the key to increase recovery.展开更多
Froth flotation is used widely for upgrading raw phosphate.The flotation recovery of coarse phosphate(-1.18+0.425 mm) is much lower than that achieved on the-0.425+0.15 mm size fraction.Enhanced recovery of coarse pho...Froth flotation is used widely for upgrading raw phosphate.The flotation recovery of coarse phosphate(-1.18+0.425 mm) is much lower than that achieved on the-0.425+0.15 mm size fraction.Enhanced recovery of coarse phosphate particles is of great economic and environmental importance for phosphate industry.In this investigation,four different phosphate samples were aquired,characterized and tested in a specially designed laboratory-scale flotation column.Significant recovery improvement of coarse phosphate flotation was achieved using cavitation-generated nanobubble though its effects differ among the four testing phosphate samples.The laboratory-scale flotation column test results indicate that nanobubble increased P_2O_5 recovery by up to 10%~30%for a given Acid Insoluble(A.I.) rejection,depending on the characteristic of phosphate samples.The improvement effect of nanobubble on the hard-to-float particles was more significant than that on easy-to-float particles,especially at lower collector dosages.Nanobubbles reduced the collector dosage by 1/3 to 1/2.Nanobubbles almost doubled the coarse phosphate flotation rate constant and increased the flotation selectivity index by up to 25%.展开更多
The Cyclonic-Static Microbubble Flotation Column (FCSMC) is currently a widely used, novel type of flotation device. The self-absorbing microbubble generator is the core component of this device. The structure of the ...The Cyclonic-Static Microbubble Flotation Column (FCSMC) is currently a widely used, novel type of flotation device. The self-absorbing microbubble generator is the core component of this device. The structure of the microbubble generator directly influences flotation column performance by affecting bubble size and distribution as well as gas holdup in the column. However, the complicated flow inside the generator results in high R&D costs and difficulty in testing. Thus, the CFD software, FLUENT, was used to simulate the gas-liquid two-phase flow inside a self-absorbing microbubble generator. The effect of area ratio, a key structural parameter, was studied in detail. Critical flow-field parameters including velocity, turbulent kinetic energy, minimum static pressure and gas holdup were obtained. The simulation results demonstrate that the optimum area ratio is 3.展开更多
Beneficiation of non-coking coal is gaining ground in India. It not only reduces the volume of inert content to be transported to the power plant and also lowers the wear in the boiler houses. For special applications...Beneficiation of non-coking coal is gaining ground in India. It not only reduces the volume of inert content to be transported to the power plant and also lowers the wear in the boiler houses. For special applications such as the fuel for integrated gasification combined cycle plant (IGCC), the ash content in the coal should preferably be below 15 %. Indian coals are characterized by high inter-grown ash content mainly due to 'drift origin' of Gondwana formation in Permian age. This warrants fine grinding of non-coking coal in order to liberate the ash forming minerals from coal macerals. A non- coking coal sample of vitrinite type from India was ground to 44 ~tm (dso) and subjected to column flotation to improve its quality. The non-coking coal analyzing 34.6 % ash, 26.2 % volatile matter, 1.3 % moisture and 37.9 % fixed carbon could be upgraded to a concentrate/froth of 14.83 % ash at 72.18 % yield by optimizing collector and frother dosages and flotation column operating parameters, namely, froth depth, superficial feed velocity and superficial air velocity. The concentrate produced by this process is suitable as fuel for IGCC in coal-to-electricity route.展开更多
Flotation column is widely used as the separation equipment for fine mineral due to its high selectivity. However, this device may be unsuitable for the coarse particle flotation and has high handling ability. A two-s...Flotation column is widely used as the separation equipment for fine mineral due to its high selectivity. However, this device may be unsuitable for the coarse particle flotation and has high handling ability. A two-stage flotation column with dimensions of 2 000 mm×1 000 mm×4 000 mm was designed to enhance the column flotation process. The energy input was modified by adjusting the flow rate and the head of circulating pump. The flotation column was designed with low energy input in the first stage(speed flotation stage) to recover easy-to-float materials quickly, and high energy input in the second stage(recovery stage) to recover difficult-to-float minerals compulsorily. Contrast experiments on the throughput and coarse coal recovery of high ash coal from the Kailuan Mine were conducted using conventional single-stage flotation column and the two-stage flotation column. The results show that the combustible matter recovery of the two-stage flotation column is 5.25% higher than that of the conventional single-stage flotation column. However, the ash contents of clean coal for both columns are similar. Less coarse coals with low ash are obtained using the two-stage flotation column than that using the single-stage column flotation with the same handling ability. The two-stage flotation column process can enhance coal flotation compared with the conventional single-stage column flotation.展开更多
Improved fluid dynamics can enhance the separation efficiency of flotation methods. A Computational Fluid Dynamics simulation using FLUENT was performed to model the fluid environment of a cyclonic-sta- tic micro bubb...Improved fluid dynamics can enhance the separation efficiency of flotation methods. A Computational Fluid Dynamics simulation using FLUENT was performed to model the fluid environment of a cyclonic-sta- tic micro bubble flotation column. The simulation results visually show the interior flow and illustrate mix- ing of the different flows within the apparatus. An analysis of the distribution in velocity and vorticity was used to analyze the separation mechanism and the synergism of the component parts and to strengthen the design of each unit. The conclusions are that axial back mixing and vortexes still exist in the separation unit even in the presence of packing media. The inverted cone structure near the tangential inlet (cone 1 ) within the cyclonic unit is the main reason for this. The cone 1 structure enhances swirling and focuses energy within the inner area of the cone where there are abundant bubbles. As a result slowly floating minerals are forcibly recovered and railings are effectively separated within this unit. However, cone 1 also reduces the vorticity downstream from it, which reduces the efficiency of railings separation within this part. Therefore, the design of cone 1 should be based on the principles of lessening disturbances to the column unit while strengthening the separation effect of the cyclonic unit. Also, the axial distance between the paired cyclonic structures at the bottom of the column (cone 2) and cone 1 poses tough requirements because of an interaction between separation of the middlings and railings.展开更多
Flotation performance of a de-slimed(-150+53μm)Jordanian siliceous phosphate was evaluated in a batch laboratory flotation column 100 cm high and 5 cm inside diameter.The collector used during anionic flotation wa...Flotation performance of a de-slimed(-150+53μm)Jordanian siliceous phosphate was evaluated in a batch laboratory flotation column 100 cm high and 5 cm inside diameter.The collector used during anionic flotation was sodium oleate while an amine acetate(AEROMINE 3100C)was used for cationic flotation.Flotation comparison at different collector dosage,superficial gas velocity,and frother concentration showed that the maximum difference in performance between cationic and anionic flotation was obtained with these flotation parameters:30×10^(-6)(mg/L)frother concentration,250 g/t collector concentration,and 3.4 cm/s superficial gas velocity.At these operating conditions amine (cationic)flotation gave 7%higher flotation recovery,a 6%cleaner concentrate grade,and was 6%more efficient at removing silica.展开更多
The flotation process is a particle-hydrophobic surface-based separation technique. To improve the essential flotation steps of collision and attachment probabilities, and reduce the step of detachment probabilities b...The flotation process is a particle-hydrophobic surface-based separation technique. To improve the essential flotation steps of collision and attachment probabilities, and reduce the step of detachment probabilities between air bubbles and hydrophobic particles, a selectively designed cavitation venturi tube combined with a static mixer can be used to generate very high numbers of pico and nano bubbles in a flotation column. Fully embraced by those high numbers of tiny bubbles, hydrophobic particles readily attract the tiny bubbles to their surfaces. The results of column flotation of Pittsburgh No. 8 seam coal are obtained in a 5.08 cm ID and 162 cm height flotation column equipped with a static mixer and cavitation venturi tube, using kerosene as collector and MIBC as frother. Design of the experimental procedure is combined with a statistical two-stepwise analysis to determine the optimal operating conditions for maximum recovery at a specified grade. The effect of independent variables on the responses has been explained. Combustible material recovery of 85–90% at clean coal product of 10–11% ash is obtained from feed of 29.6% ash, with a much-reduced amount of frother and collector than that used in conventional column flotation. The column flotation process utilizing pico and nano bubbles can also be extended to the lower limit and upper limit of particle size ranges, minus 75 lm and 300–600 lm, respectively, for better recovery.展开更多
This study was performed to investigate the effects of the cyclonic separation mechanism on the removal of magnesium from phosphate ore. An analysis of the particle-bubble collision mechanism in a cyclonic force field...This study was performed to investigate the effects of the cyclonic separation mechanism on the removal of magnesium from phosphate ore. An analysis of the particle-bubble collision mechanism in a cyclonic force field was used to design two different pulp circulation systems for a cyclonic-static micro-bubble flotation column (FCSMC). Experiments comparing the two conditions were then conducted. Size analysis of the feed and separated products was conducted with a BXF cyclone size analyzer. The results show that about 34.60% of the total MgO content in the feed exists in the -10 μm fraction. This demonstrates that magnesium removal from phosphate ore has the characteristics of a micro-fine particle flotation problem. Under conditions of cyclonic circulation the MgO level of the concentrate is 1.74g, which is lower than that obtained from the column operated in direct-flow circulation by 0.34%, These results indicate that the cyclonic circulation mechanism of the FCSMC can promote removal of micro-fine particles containing magnesium. This is attributed to the function of surface flotation and to the reduction of the lower separation limit under conditions of cyclonic circulation.展开更多
Evaluation of grade and recovery plays an important role in process control and plant profitability in mineral processing operations, especially flotation. The accurate measurement or estimation of these two parameter...Evaluation of grade and recovery plays an important role in process control and plant profitability in mineral processing operations, especially flotation. The accurate measurement or estimation of these two parameters, based on the secondary variables, is a critical issue. Data-driven modeling techniques, which entail comprehensive data analysis and implementation of machine learning methods for system forecast, provide an attractive alternative. In this paper, two types of artificial neural networks(ANNs),namely radial basis function neural network(RBFNN) and layer recurrent neural network(RNN), and also a multivariate nonlinear regression(MNLR) model were employed to predict metallurgical performance of the flotation column. The training capacity and the accuracy of these three above mentioned types of models were compared. In order to acquire data for the simulation, a case study was conducted at Sarcheshmeh copper complex pilot plant. Based on the root mean squared error and correlation coefficient values, at training and testing stages, the RNN forecasted the metallurgical performance of the flotation column better than RBF and MNLR models. The RNN could predict Cu grade and recovery with correlation coefficients of 0.92 and 0.9, respectively in testing process.展开更多
Brazil and Colombia have large reserves of coal. Those reserves in Brazil are located predominantly in the south and the main reserves in Colombia are located in the north. Despite the relative ease of exploitation, t...Brazil and Colombia have large reserves of coal. Those reserves in Brazil are located predominantly in the south and the main reserves in Colombia are located in the north. Despite the relative ease of exploitation, these resources have been underestimated as a source of energy. Currently, these countries are developing projects and partnerships aiming to qualify this mineral resource, adding quality to the final product of the processing plants. In this scenario, the processing of Brazilian and Colombian coal in flotation columns appears as a promising alternative, having been successful in mineral systems containing fine particles. The paper aims to study the overall process of column flotation for a specific Brazilian coal and a specific Colombian coal. The material used in this study consists of fine coal from Brazil (Copelmi) and Colombia (Cerrejon). The objective is to recover carbonaceous matter and reduce the ash and contaminants grade. The two coals were floated using a negative bias in a 5 cm diameter conventional flotation column of 5 m high. Flotation parameter investigated included air velocity in the range 0.6 to 1.5 cm/s. For all runs, a constant negative bias of-0.25 cm/s and a pulp concentration of 8% w/w were used. For Cerrej6n coal, 300 g/ton of frother and 907 g/ton of collector was used, whereas for Copelmi coal, 600 g/ton of frother and 1,815 g/ton of collector was employed. The frother was a commercial Aerofroth 65 (AF65), whereas the collector was Kerosene. For the Colombian coal, in general, yield, organic recovery, ash recovery and water recovery decreased with the increasing air rate. However, for Brazilian coal the air rate had no significant effect. For Colombian coal, the highest yield (60% w/w) and organic recovery (69% w/w) were obtained at the lowest air rate (0.6 cm/s).展开更多
We address problems in the development of large-scale flotation columns that use short cylinders. As a starting point, we investigated the packing medium to identify a highly efficient internal packing for the flotati...We address problems in the development of large-scale flotation columns that use short cylinders. As a starting point, we investigated the packing medium to identify a highly efficient internal packing for the flotation column. The chosen packing was a honeycomb structure with an aperture diameter of 80 mm, a web thickness of 0.80 mm, a film height of 1000 mm, packed into a 400 mm diameter space, which completely filled the vessel at optimal cost. The column consisted of a modular ring of single-hole hexagonal honeycomb tube packing made from atactic polyproplene (PP-R). The packing was tested in a cyclonic, static micro-bubble flotation column. Computational fluid dynamic modeling was used to analyze the flotation fluid in a honeycomb tube packed flotation column. Our results show that the fluid axial movement was maximized and that the transverse fluid velocities were zero in the vicinity of axial flow. Using the honeycomb tube packing for copper sulfide flotation we observed that the average concentration in the product was increased to 25.41%, from an average feed concentration of 0.729%, with an average recovery of 92.92%. The demands of on-site industrial production were met.展开更多
文摘The floatability of andalusite and quartz was studied using sodium petroleum sulfonate as collector, being successfully applied in the real ore separation. The collecting performance on minerals was interpreted by means of zeta potential measurement and infrared spectroscopic analysis. The single mineral experiments showed that andalusite got good floatability in acidic pH region while quartz exhibited very poor floatability in the whole pH range. At pH 3, the presence of Fe3+ obviously activated quartz, causing the identical flotation behavior of the two minerals, and calcium lignosulphonate exhibited good selective inhibition to quartz. The real ore test results showed that andalusite concentrate with 53.46% Al2O3 and quartz concentrate with 92.74% SiO2 were obtained. The zeta potential and infrared spectroscopic analysis results indicated that chemical adsorption occurred between sodium petroleum sulfonate and andalusite.
文摘The flotation behavior of Xixia andalusite was studied with different collectors.The tests were conducted with a pure andalusite sample in micro-flotation cell and then with an ore sample in a mechanical flotation cell.The surface charge was measured on pure andalusite sample and the isoelectric point(IEP) was found to be pH 5.2.Andalusite is floated with an amine collector above IEP where mineral surface is negatively charged.In contrast,an alkyl sulfonate collector(sodium dodecyl benzene sulfonate) is effective in the pH range where andalusite surface is positively charged.Furthermore,andalusite is floated with oleate in neutral and mildly alkaline pH values.55.3% Al2O3 is produced with 75.6% andalusite recovery when using the alkyl benzene sulfonate collector.Starch is found to be an effective depressant for gangue minerals in alkyl benzene sulfonate flotation.Moreover,slimes are found to have an adverse effect on the flotation of andalusite.Therefore,pretreatment by desliming and pre-float(to remove carbonaceous species) prior to andalusite flotation is necessary.
文摘Coal is the world's most abundant fossil fuel.Coal froth flotation is a widely used cleaning process to separate coal from mineral impurities.Flotation of coarse coal particles,ultrafine coal particles and oxidized coal particles is well known to be difficult and complex.In this paper,the nanobubbles' effects on the flotation of the varying particle size,particle density and floatability coal samples were evaluated using a bank of pilot scale flotation cells,a laboratory scale and a pilot scale specially designed flotation column.The parameters evaluated during this study include the flow rate ratio between the nanobubble generator and the conventional size bubble generator,the superficial air velocity,collector dosage,frother concentration,flotation feed rate,feed solids concentration,feed particle size,and the superficial wash water flow rate,etc.The results show that the use of nanobubbles in a bank of mechanical cells flotation and column flotation increased the flotation recovery by 8%~27% at a given product grade.Nanobubbles increased the flotation rate constants of 600~355,355~180,180~75,and 75~0 microns size coal particles by 98.0%,98.4%,50.0% and 41.6%,respectively.The separation selectivity index was increased by up to 34%,depending on the flotation feed characteristics and the flotation conditions.
基金Projects 2008BAB31B01 supported by the National Key Technology R&D Program in the 11th Five-Year Plan of China50834006 by the National Natural Science Foundation of China
文摘In our study we investigated a refractory copper-nickel sulfide ore separation by using a cyclonic-static micro-bubble flotation column (FCSMC). The process mineralogy of the main products was studied. Using a scanning electron microscope-energy dispersive system (SEM-EDS) and an X-ray spectrometer the mineral category and content of samples were analyzed. By using a mineral liberation analyzer (MLA) the mineral liberation characteristics were revealed. It is shown that in roughing feed the monomers liberation degree of nickel pyrite and chalcopyrite take up 84.11% and 88.82%, respectively. In tailings, the lost nickel pyrite and chalcopyrite are mainly monomers. Therefore, strengthening the micro-fine particle recovery capacity is the key to increase recovery.
基金the Florida Institute of Phosphate Research(FIPR),The Center for Advanced Separation Technologies(CAST) and the National Natural Science Foundation of China (Nos.50921002 and 90510002) for the financial supportCF Industry Inc and Mosaic Company for supplying specimens and ArrMaz Custom Chemicals Inc.for providing chemicals employed in this study.
文摘Froth flotation is used widely for upgrading raw phosphate.The flotation recovery of coarse phosphate(-1.18+0.425 mm) is much lower than that achieved on the-0.425+0.15 mm size fraction.Enhanced recovery of coarse phosphate particles is of great economic and environmental importance for phosphate industry.In this investigation,four different phosphate samples were aquired,characterized and tested in a specially designed laboratory-scale flotation column.Significant recovery improvement of coarse phosphate flotation was achieved using cavitation-generated nanobubble though its effects differ among the four testing phosphate samples.The laboratory-scale flotation column test results indicate that nanobubble increased P_2O_5 recovery by up to 10%~30%for a given Acid Insoluble(A.I.) rejection,depending on the characteristic of phosphate samples.The improvement effect of nanobubble on the hard-to-float particles was more significant than that on easy-to-float particles,especially at lower collector dosages.Nanobubbles reduced the collector dosage by 1/3 to 1/2.Nanobubbles almost doubled the coarse phosphate flotation rate constant and increased the flotation selectivity index by up to 25%.
基金Financial supports for this work provided by the National High Technology Research and Development Program of China (No.2008BAB31B02) is gratefully acknowledged
文摘The Cyclonic-Static Microbubble Flotation Column (FCSMC) is currently a widely used, novel type of flotation device. The self-absorbing microbubble generator is the core component of this device. The structure of the microbubble generator directly influences flotation column performance by affecting bubble size and distribution as well as gas holdup in the column. However, the complicated flow inside the generator results in high R&D costs and difficulty in testing. Thus, the CFD software, FLUENT, was used to simulate the gas-liquid two-phase flow inside a self-absorbing microbubble generator. The effect of area ratio, a key structural parameter, was studied in detail. Critical flow-field parameters including velocity, turbulent kinetic energy, minimum static pressure and gas holdup were obtained. The simulation results demonstrate that the optimum area ratio is 3.
文摘Beneficiation of non-coking coal is gaining ground in India. It not only reduces the volume of inert content to be transported to the power plant and also lowers the wear in the boiler houses. For special applications such as the fuel for integrated gasification combined cycle plant (IGCC), the ash content in the coal should preferably be below 15 %. Indian coals are characterized by high inter-grown ash content mainly due to 'drift origin' of Gondwana formation in Permian age. This warrants fine grinding of non-coking coal in order to liberate the ash forming minerals from coal macerals. A non- coking coal sample of vitrinite type from India was ground to 44 ~tm (dso) and subjected to column flotation to improve its quality. The non-coking coal analyzing 34.6 % ash, 26.2 % volatile matter, 1.3 % moisture and 37.9 % fixed carbon could be upgraded to a concentrate/froth of 14.83 % ash at 72.18 % yield by optimizing collector and frother dosages and flotation column operating parameters, namely, froth depth, superficial feed velocity and superficial air velocity. The concentrate produced by this process is suitable as fuel for IGCC in coal-to-electricity route.
基金Project(2012CB214905)supported by the National Basic Research Program of ChinaProject(51074157)supported by the National Natural Science Foundation of China
文摘Flotation column is widely used as the separation equipment for fine mineral due to its high selectivity. However, this device may be unsuitable for the coarse particle flotation and has high handling ability. A two-stage flotation column with dimensions of 2 000 mm×1 000 mm×4 000 mm was designed to enhance the column flotation process. The energy input was modified by adjusting the flow rate and the head of circulating pump. The flotation column was designed with low energy input in the first stage(speed flotation stage) to recover easy-to-float materials quickly, and high energy input in the second stage(recovery stage) to recover difficult-to-float minerals compulsorily. Contrast experiments on the throughput and coarse coal recovery of high ash coal from the Kailuan Mine were conducted using conventional single-stage flotation column and the two-stage flotation column. The results show that the combustible matter recovery of the two-stage flotation column is 5.25% higher than that of the conventional single-stage flotation column. However, the ash contents of clean coal for both columns are similar. Less coarse coals with low ash are obtained using the two-stage flotation column than that using the single-stage column flotation with the same handling ability. The two-stage flotation column process can enhance coal flotation compared with the conventional single-stage column flotation.
基金supported by the National Natural Science Foundation of China (No. 51074157)the Foundation of China University of Mining and Technology (No. 2011QNA08)
文摘Improved fluid dynamics can enhance the separation efficiency of flotation methods. A Computational Fluid Dynamics simulation using FLUENT was performed to model the fluid environment of a cyclonic-sta- tic micro bubble flotation column. The simulation results visually show the interior flow and illustrate mix- ing of the different flows within the apparatus. An analysis of the distribution in velocity and vorticity was used to analyze the separation mechanism and the synergism of the component parts and to strengthen the design of each unit. The conclusions are that axial back mixing and vortexes still exist in the separation unit even in the presence of packing media. The inverted cone structure near the tangential inlet (cone 1 ) within the cyclonic unit is the main reason for this. The cone 1 structure enhances swirling and focuses energy within the inner area of the cone where there are abundant bubbles. As a result slowly floating minerals are forcibly recovered and railings are effectively separated within this unit. However, cone 1 also reduces the vorticity downstream from it, which reduces the efficiency of railings separation within this part. Therefore, the design of cone 1 should be based on the principles of lessening disturbances to the column unit while strengthening the separation effect of the cyclonic unit. Also, the axial distance between the paired cyclonic structures at the bottom of the column (cone 2) and cone 1 poses tough requirements because of an interaction between separation of the middlings and railings.
基金done during the first author's Fulbright fellowship at the Center for Advanced Separation (CAST)/Virginia Technical Institute and State University-USA. Salah would like to thank all the people who work at CAST for their friendship and support during his stay in Blacksburg, VA.
文摘Flotation performance of a de-slimed(-150+53μm)Jordanian siliceous phosphate was evaluated in a batch laboratory flotation column 100 cm high and 5 cm inside diameter.The collector used during anionic flotation was sodium oleate while an amine acetate(AEROMINE 3100C)was used for cationic flotation.Flotation comparison at different collector dosage,superficial gas velocity,and frother concentration showed that the maximum difference in performance between cationic and anionic flotation was obtained with these flotation parameters:30×10^(-6)(mg/L)frother concentration,250 g/t collector concentration,and 3.4 cm/s superficial gas velocity.At these operating conditions amine (cationic)flotation gave 7%higher flotation recovery,a 6%cleaner concentrate grade,and was 6%more efficient at removing silica.
基金provided by West Virginia State Coal and Energy Research Bureau (CERB)the Department of Mining Engineering,West Virginia University
文摘The flotation process is a particle-hydrophobic surface-based separation technique. To improve the essential flotation steps of collision and attachment probabilities, and reduce the step of detachment probabilities between air bubbles and hydrophobic particles, a selectively designed cavitation venturi tube combined with a static mixer can be used to generate very high numbers of pico and nano bubbles in a flotation column. Fully embraced by those high numbers of tiny bubbles, hydrophobic particles readily attract the tiny bubbles to their surfaces. The results of column flotation of Pittsburgh No. 8 seam coal are obtained in a 5.08 cm ID and 162 cm height flotation column equipped with a static mixer and cavitation venturi tube, using kerosene as collector and MIBC as frother. Design of the experimental procedure is combined with a statistical two-stepwise analysis to determine the optimal operating conditions for maximum recovery at a specified grade. The effect of independent variables on the responses has been explained. Combustible material recovery of 85–90% at clean coal product of 10–11% ash is obtained from feed of 29.6% ash, with a much-reduced amount of frother and collector than that used in conventional column flotation. The column flotation process utilizing pico and nano bubbles can also be extended to the lower limit and upper limit of particle size ranges, minus 75 lm and 300–600 lm, respectively, for better recovery.
基金supported by the National Key Technology R&D Program for the 11th Five-Year Plan of China(No. 2008BAB31B01)
文摘This study was performed to investigate the effects of the cyclonic separation mechanism on the removal of magnesium from phosphate ore. An analysis of the particle-bubble collision mechanism in a cyclonic force field was used to design two different pulp circulation systems for a cyclonic-static micro-bubble flotation column (FCSMC). Experiments comparing the two conditions were then conducted. Size analysis of the feed and separated products was conducted with a BXF cyclone size analyzer. The results show that about 34.60% of the total MgO content in the feed exists in the -10 μm fraction. This demonstrates that magnesium removal from phosphate ore has the characteristics of a micro-fine particle flotation problem. Under conditions of cyclonic circulation the MgO level of the concentrate is 1.74g, which is lower than that obtained from the column operated in direct-flow circulation by 0.34%, These results indicate that the cyclonic circulation mechanism of the FCSMC can promote removal of micro-fine particles containing magnesium. This is attributed to the function of surface flotation and to the reduction of the lower separation limit under conditions of cyclonic circulation.
基金the support of the Department of Research and Development of Sarcheshmeh Copper Plants for this research
文摘Evaluation of grade and recovery plays an important role in process control and plant profitability in mineral processing operations, especially flotation. The accurate measurement or estimation of these two parameters, based on the secondary variables, is a critical issue. Data-driven modeling techniques, which entail comprehensive data analysis and implementation of machine learning methods for system forecast, provide an attractive alternative. In this paper, two types of artificial neural networks(ANNs),namely radial basis function neural network(RBFNN) and layer recurrent neural network(RNN), and also a multivariate nonlinear regression(MNLR) model were employed to predict metallurgical performance of the flotation column. The training capacity and the accuracy of these three above mentioned types of models were compared. In order to acquire data for the simulation, a case study was conducted at Sarcheshmeh copper complex pilot plant. Based on the root mean squared error and correlation coefficient values, at training and testing stages, the RNN forecasted the metallurgical performance of the flotation column better than RBF and MNLR models. The RNN could predict Cu grade and recovery with correlation coefficients of 0.92 and 0.9, respectively in testing process.
文摘Brazil and Colombia have large reserves of coal. Those reserves in Brazil are located predominantly in the south and the main reserves in Colombia are located in the north. Despite the relative ease of exploitation, these resources have been underestimated as a source of energy. Currently, these countries are developing projects and partnerships aiming to qualify this mineral resource, adding quality to the final product of the processing plants. In this scenario, the processing of Brazilian and Colombian coal in flotation columns appears as a promising alternative, having been successful in mineral systems containing fine particles. The paper aims to study the overall process of column flotation for a specific Brazilian coal and a specific Colombian coal. The material used in this study consists of fine coal from Brazil (Copelmi) and Colombia (Cerrejon). The objective is to recover carbonaceous matter and reduce the ash and contaminants grade. The two coals were floated using a negative bias in a 5 cm diameter conventional flotation column of 5 m high. Flotation parameter investigated included air velocity in the range 0.6 to 1.5 cm/s. For all runs, a constant negative bias of-0.25 cm/s and a pulp concentration of 8% w/w were used. For Cerrej6n coal, 300 g/ton of frother and 907 g/ton of collector was used, whereas for Copelmi coal, 600 g/ton of frother and 1,815 g/ton of collector was employed. The frother was a commercial Aerofroth 65 (AF65), whereas the collector was Kerosene. For the Colombian coal, in general, yield, organic recovery, ash recovery and water recovery decreased with the increasing air rate. However, for Brazilian coal the air rate had no significant effect. For Colombian coal, the highest yield (60% w/w) and organic recovery (69% w/w) were obtained at the lowest air rate (0.6 cm/s).
基金Project 2007AA05Z339 supported by the National High-Tech Research and Development Program of China
文摘We address problems in the development of large-scale flotation columns that use short cylinders. As a starting point, we investigated the packing medium to identify a highly efficient internal packing for the flotation column. The chosen packing was a honeycomb structure with an aperture diameter of 80 mm, a web thickness of 0.80 mm, a film height of 1000 mm, packed into a 400 mm diameter space, which completely filled the vessel at optimal cost. The column consisted of a modular ring of single-hole hexagonal honeycomb tube packing made from atactic polyproplene (PP-R). The packing was tested in a cyclonic, static micro-bubble flotation column. Computational fluid dynamic modeling was used to analyze the flotation fluid in a honeycomb tube packed flotation column. Our results show that the fluid axial movement was maximized and that the transverse fluid velocities were zero in the vicinity of axial flow. Using the honeycomb tube packing for copper sulfide flotation we observed that the average concentration in the product was increased to 25.41%, from an average feed concentration of 0.729%, with an average recovery of 92.92%. The demands of on-site industrial production were met.