利用浮质方法将硝酸盐和PDDA-Pt(IV)复合溶液合成纯净及Pt掺杂的ZnO颗粒(英文)

Pure and Pt-doped ZnO nanophase particles were synthesized using the ultrasonic spray pyrolysis. Particles were obtained through decomposition of zinc nitrate and new developed Pt（IV） complex with 1,3-propylenediamine-N,N-diacetate ligand （pdda） belonging to the tetradentate class. The complex is characterized by elemental analysis, electronic absorption and infrared spectra. The crystal structure of trans-[Pt（pdda）Br2]·H2O complex has been determined implying that Pt（IV） ion has a distorted octahedral coordination due to intramolecular N-H ...Br interaction. Ultrasonically derived pure and Pt-doped ZnO particles were characterized by XRD, SEM, EDS and TEM analysis. It was shown that zincite phase exhibits different growing morphologies influenced by precursor chemistry and processing parameters. The composite inner structure, primary particle size and mechanism of Pt 4+ ion introducing into ZnO cell is discussed based on structural refinement and selected area electron diffraction analysis.

Effect of temperature on suspension magnetization roasting of hematite using biomass waste as reductant:A perspective of gas evolution

The magnetization reduction of hematite using biomass waste can effectively utilize waste and reduce CO_(2) emission to achieve the goals of carbon peaking and carbon neutrality.The effects of temperatures on suspension magnetization roasting of hematite using biomass waste for evolved gases have been investigated using TG-FTIR,Py-GC/MS and gas composition analyzer.The mixture reduction process is divided into four stages.In the temperature range of 200-450℃ for mixture,the release of CO_(2),acids,and ketones is dominated in gases products.The yield and concentration of small molecules reducing gases increase when the temperature increases from 450 to 900℃.At 700℃,the volume concentrations of CO,H_(2) and CH_(4) peak at 8.91%,8.90% and 4.91%,respectively.During the suspension magnetization roasting process,an optimal iron concentrate with an iron grade of 70.86%,a recovery of 98.66% and a magnetic conversion of 45.70% is obtained at 700℃.Therefore,the magnetization reduction could react greatly in the temperature range of 600 to 700℃ owing to the suitable reducing gases.This study shows a detail gaseous evolution of roasting temperature and provides a new insight for studying the reduction process of hematite using biomass waste.

水下滑翔机浮力调节机构布局研究

水下滑翔机是一种新型的海洋观测平台。通过力学关系对浮力调节机构的布局进行了详细研究,分析了将浮力调节机构布置在艏部和艉部的优缺点,在此基础上提出了将浮力调节机构布置在中段的某一位置,在定量的打油或回油过程中,质浮心距保持基本不变,为水下滑翔机的机构设计提供了参考。

有机生态型浮板栽培技术研究

本次试验通过草炭、蛭石、珍珠岩、河沙、羊粪、鸡粪等有机基质按试验设计的要求配制不同的比例,通过对生菜各项生长发育指标的观察记载和分析,结果表明在冬季栽培,是草炭:珍珠岩:河沙:鸡粪=1:1:1:1(B配方)的配方最适宜生菜生长。

燃烧后处理溶剂二氧化碳吸收中试塔技术进展

烟道气后处理二氧化碳溶剂吸收技术包括基础研究和中试塔,演示塔,经济型塔的实际连续操作,业内已经使用大量的中试塔,演示塔和经济型吸收塔,但相关成果在国内少见报道,这篇综述专注这一领域的化工技术进展。中试塔和演示塔中的基础研究和技术开发成果,可用于调式二氧化碳吸收技术的真实操作,为操作大型工业经济型吸收塔提供应用指导。二氧化碳吸收的中试塔和演示塔化工装置和相关吸收技术十分丰富,但它们始终致力提高有机胺为基础溶剂的二氧化碳吸收技术的耐久性和实用性,在以下几方面:吸收尾气排放,工艺操作问题,溶剂配方管理,腐蚀,塔尺寸减少,新型混合胺溶剂,非胺溶剂。演示塔的出现,同时体现测量标准和开始应用的测量和分析方法需求。

Voltage property analysis of piezoelectric floating mass actuator used in middle ear implant

Aiming at a kind of middle ear implant（MEI）, the driving voltage of a piezoelectric floating mass actuator is analyzed using a 0. 7Pb （Mg1/3Nb2/3） O3-0. 3PbTiO3 （ PMN- 30% PT）stack as a new type of vibrator. For the purpose of facilitating the analysis, a simplified coupling model of the ossicular chain and the piezoelectric actuator is constructed. First, a finite element model of a human middle ear is constructed by reverse engineering technology, and the validity of this model is confirmed by comparing the simulated motion of the stapes footplate obtained by this model with experimental measurements. Then the displacement impedance of the incus long process is analyzed, and a single mass-spring-damper equivalent model of the ossicular chain attached with the clamp is derived. Finally, a simplified coupling model of the ossicular chain and the piezoelectric actuator is established and used to analyze the driving voltage property of the actuator. The results show that the required driving voltage decreases with the increase in the frequency, and the maximum required driving voltage is 20. 9 V in the voice frequencies. However, in the mid-high frequencies where most sensorineural hearing loss occurs, the maximum required driving voltage is 3.8 V, which meets the low-voltage and low-power requirements of the MEI.

Microthermokinetic study of xanthate adsorption on impurity-doped galena

Six kinds of galena with different impurities were synthesized and the effects of impurities on the floatability of galena were investigated. The thermodynamic and kinetic parameters on the galena surface were measured using microcalorimetry, and the adsorption configuration and energy of butyl xanthate on the surfaces of galena with different impurities were simulated by density functional theory. Flotation experiments showed that Ag and Bi significantly promoted the recovery of galena, while Zn, Sb, Mn, and Cu reduced the recovery of the flotation. Microthermokinetic results indicated that the absolute value of xanthate adsorption heat was directly proportional to the flotation recovery of galena. Adsorption heat and reaction rate coefficients of xanthate on galena containing Ag or Bi were larger than those on pure galena, but smaller on galena containing Cu or Sb. Additionally, the relationship between the heat of unsaturated adsorption of xanthate and the adsorption energy of impurity atom on galena surface was investigated.

Distribution of Turbidity and Fluorescence of SPM in Adjacent Waters of Taiwan Bank in Summer

The turbidity and fluorescence of suspended particulate matter （SPM） in the Taiwan Bank and adjacent waters were investigated during July-August, 2004, to examine the effects of the marine sediments re-suspension and sedimentary processes on the turbidity and fluorescence distribution of SPM. The results show that the turbidity of SPM is affected by the re-suspension of marine sediment in the near shore and continental shelf outer fringe, but not obvious in the shoal. The enrichment of phytoplankton has some effects on the turbidity in the continental shelf outer fringe, but not evident in the near shore. This is helpful for better understanding the distribution of turbidity and fluorescence in the adjacent waters of Taiwan Bank.

Studies on Parameters Affecting Embryogenesis of Protoplasts Isolated from Suspension of Embryogenic Cells in Loblolly Pine

Protoplasts of embryogenic suspension cells of loblolly pine (Pinus taeda L).were isolated at exponential growth stage.Influences of various concentrations of basal medium,levels of BA,and concentrations of inositol on the differentiation of embryonal suspensor mass (ESM),early stage somatic embryos (ESE) ,and lae stage somatic embryos (LSE) were investigated .A study of the effect of various concentrations of LP basal medium sowed that the optimal basal medium concentration of ESM,ESE,and LSE differentiation was 1.25 LP medium.The effects of various levels of BA and inositol showed that the optimal concentrations of BA for the formation of ESM,ESE and LSE were 4 mg/L ,2mg/L and 1mg/L,respectively ,and the optimal concentrations of inositol for the ESM ,ESE and LSM formation were 400mg/L,800mg/L and 1,200mg/L,respectively.

The Application of Seedling Nursing on Moist Trays and Fermentation Heating Using Farmyard Manure Methods in High-altitude Tobacco Areas of Fenggang County

To solve the problems of long seedling culture time and poor quality of tobacco seedlings bred by floating culture technique of seedlings in high-altitude tobacco areas, a comparative trial between seedling nursing on moist trays ＋ fermentation heating using farmyard manure and conventional floating culture of seedlings in Fenggang County was carried out in 2013. The results showed that seedling nursing on moist trays ＋ fermentation heating using farmyard manure can improve 4-5 ℃ of pool water temperature, shorten 8 d of seedling age, increase 4.45 cm of seedling height, thicken 0.46 cm of stem girth and make lateral root system developed. The method can shorten the time of floating breeding of flue-cured tobacco,improve the quality of tobacco seedlings, thus it was suitable to popularize in highaltitude tobacco areas of Fenggang County.

鱼雷水下发射的6-DOF运动仿真

为了直观、量化地描述鱼雷在发射出管的运动状态,研究质浮心间距对于鱼雷航行质心轨迹及姿态角的影响,本文通过建立鱼雷发射的网格模型,运用重叠网格方法和6-DOF方法对鱼雷出管的运动状态进行数值仿真分析。对仿真数据进行分析,得到了鱼雷运动时质心轨迹随时间的变化规律、姿态角随时间的变化规律、质心轨迹和姿态角随发射速度的变化规律和质浮心间距对于鱼雷运动姿态角的影响,以及鱼雷运动时的瞬态速度场分布。为鱼雷发射后运动姿态的调整和控制提供理论依据。

MEMS Inductor Consisting of Suspended Thick Crystalline Silicon Spiral with Copper Surface Coating

A novel MEMS inductor consisting of a planar single crystalline silicon spiral with a copper surface coating as the conductor is presented. Using a silicon-glass anodic bonding and deep etching formation-and-release process,a 40μm-thick silicon spiral is formed, which is suspended on a glass substrate to eliminate substrate loss. The surfaces of the silicon spiral are coated with highly conformal copper by electroless plating to reduce the resis- tive loss in the conductor,with thin nickel film plated on the surface of the copper layer for final surface passivation. The fabricated inductor exhibits a self-resonance frequency higher than 15GHz,with a quality factor of about 40 and an inductance of over 5nil at 11.3GHz. Simulations based on a compact equivalent circuit model of the inductor and parameter extraction using a characteristic-function approach are carried out,and good agreement with measurements is obtained.

Numerical Study of Water and Suspended Matter Exchange Between the Yellow Sea and the East China Sea

POM was used to study the monthly mean circulation in the Yellow Sea and East China Sea. The calculated results showed almost all major characteristics of the circulation system. The calculated circulation system and observational data were used to determine the sediment concentration, volume transport, heat flux and suspended matter flux between the Yellow Sea and the East China Sea. The conclusions obtained were that the volume and heat are transported northward through the 32°N section during each season; that in winter and autumn, total suspended matter is transported southward, and is larger in winter than in autumn. The reason is that the Yellow Sea Coastal Current is strong and always contains more suspend matter in winter and autumn. The seasonal suspended matter exchange between the Yellow Sea and the East China Sea are 0.58×10 7 tons in spring, 2.81×10 7 tons in summer, -2.60×10 7 tons in autumn and -3.40×10 7 tons in winter. Net flux of suspended matter from the Yellow Sea to the East China Sea is 2.61×10 7 tons every year.

Characterization of suspended solids and particle-bound heavy metals in a first flush of highway runoff

To investigate the dynamic characteristics of total suspended solids (TSS) and their particle-bound heavy metals in a first flush, the runoff sampling together with its flow rate measuring was conducted for three rainfall events at outfalls of highway in Shanghai from June to September 2007. Field samples were analyzed to determine the concentrations of TSS and particle-bound heavy metals, such as Zn, Pb, and Cu. Results show that the wash off behavior of TSS under varying runoff rate condition can be explained by different antecedent dry weather period (ADWP). Contribution of fine fraction (<45 μm) to TSS was generally higher than that of coarse fraction (>45 μm). When the runoff flow increased obviously, a significant contribution of the coarse fraction was observed for a certain rainfall events with long antecedent dry weather condition. The changes of total metals concentration and particle-bound metal concentrations were strongly dependent on the TSS variation. TSS was generally well correlated with most particulate-bound heavy metals. Of the heavy metals, the concentration of Zn was found considerably high and that of Pb was significantly low at North Zhongshan 2 Road, in Shanghai, China, but they are still within the range reported in the literature. Fluctuation of heavy metal contents in the coarse fraction during a first flush period was more significant compared with that in the fine fraction. The results will assist in the development of effective control strategies to minimize heavy metals and solids in highway runoff.

A comparison of anionic and cationic flotation of a siliceous phosphate rock in a column flotation cell

Flotation performance of a de-slimed（-150＋53μm）Jordanian siliceous phosphate was evaluated in a batch laboratory flotation column 100 cm high and 5 cm inside diameter.The collector used during anionic flotation was sodium oleate while an amine acetate（AEROMINE 3100C）was used for cationic flotation.Flotation comparison at different collector dosage,superficial gas velocity,and frother concentration showed that the maximum difference in performance between cationic and anionic flotation was obtained with these flotation parameters：30×10^（-6）（mg/L）frother concentration,250 g/t collector concentration,and 3.4 cm/s superficial gas velocity.At these operating conditions amine （cationic）flotation gave 7%higher flotation recovery,a 6%cleaner concentrate grade,and was 6%more efficient at removing silica.

Selective separation of silica from a siliceous-calcareous phosphate rock

Selective separation of silica from a siliceous-calcareous phosphate ore that had been sieved into different size fractions is investigated by a combination of chemical analysis,zeta potential measurement and FTIR and XPS techniques.Scrubbing is a better choice than flotation for removing silica from the coarse fractions.The P_2O_5 grade of the coarse fractions is increased to about 30%by scrubbing and the product yields are higher than those obtained by flotation.The silica in the fine fraction is separated by reverse flotation.An alkyl amine salt(DAH)is an effective collector and the P_2O_5 grade of the fine fraction can be increased by 7%to beyond 30%under acidic conditions.The higher zeta potential obtained using DAH suggests that it is more strongly absorbed onto the ore particles than the other cationic collectors. FTIR and XPS results confirm physical absorption of the cationic collector onto the ore surface.They also indicate that calcite is dissolved at low pH values,which increases the Si concentration on the ore surface.

Study on Selection and Application of New Matrixes for Floating Tobacco Seedlings

[Objective] This study aimed to verify the effects of new matrixes on tobacco seedlings on floating platform or field, and their effects on tobacco leaf yield and quality. [Method] The ratio of peat： carbonized rice hull： perlite： sand in the four new matrixes was 10∶40∶30∶20, 20∶40∶10∶30, 20∶40∶30∶10 and 20∶50∶10∶20, marked as T1, T2, T3 and T4, respectively. The ratio in control matrix was 35∶40∶25∶0. [Result]In formulas T1, T2, T3 and T4, the peat consumption was reduced by 70.1%,41.5%, 41.5%, and 41.5% respectively, which saved 12.5%, 23.1%, 8.2% and 12.8%of the cost. The new matrixes can effectively increase the seedling emergence rate of tobacco. The quality and duration of seedlings in float system with new matrixes showed no difference from those of control matrix. The values of output using the new matrixes were 323.10, 92.25, 39.30 and 2 250.60 Yuan/hm2higher than that of the control. Besides, the proportion of the first- and second-rate tobacco leaves was also improved. [Conclusion] These four new matrixes can be widely applied to raise seedling in a float system, and T4 is the best choice.

The flocculation research on treating suspended solids contained mine drainage through goaf

Mine drainage could be filtered and purified through goaf. This innovative technique shows merits, such as high treatment efficiency, remarkable economic benefit and extensive wastewater recycle use. However, it was detected that capacities of purifying mine drainage for goaf were decreased after a period of application. As a result, the effluent could not meet the standard of recycle water. To solve the problem, coagulant was considered to add into mine drainage reducing its high turbid degrees to certain level. After the preliminary flocculation treatment, mine drainage was piped into goaf to purify. In this way, the load of goaf was eased up. Its usage time was also prolonged. Therefore, this paper carried out the coagulation-flocculation jar test for mine drainage to discuss the flocculation parameters. By the experiment, 10 % iron trichloride is selected from four inorganic coagulants as the optimum coagulant. The optimum dose, PH value and sedirs6-7 and 25 min. Velocity mentation time are respectively 2 mL per 800 mL Wastewater gradient G during the process of mixing and reaction is 696 .And the value of GT is 6.264 × 10^5. The values of G and GT will supply the basis for the design of flocculation pool in the project. The flocculation parameters will be significant for the reference of practice.

Levels and statistical analysis of aerosol phase PAHs over Qingdao alongshore

Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) were measured during various seasons at six different cities/locations in Qingdao alongshore. The annual average PAHs concentration ranged from 16 ng/m3 (at a clean com- pared site) to 308 ng/m3 (in an industry site). The average total particulate PAHs concentration was 74.5 ng/m3 with a higher concentration of particulate PAHs in winter. Based on a year-round dataset, the sources of PAHs in the air of Qingdao were drawn by principal factor analysis and correlation analysis. The results indicated that vehicle emissions and oil burning were the main source of PAHs in Qingdao alongshore.