In order to offer high grade concentrate to produce alumina by Bayer, the reverse-flotation technology of bauxite was investigated. The results show that sodium hexmetaphosphate has different depression on the flotati...In order to offer high grade concentrate to produce alumina by Bayer, the reverse-flotation technology of bauxite was investigated. The results show that sodium hexmetaphosphate has different depression on the flotation of diaspore and kaolinite. The recoveries of diaspore decrease markedly with the increase of the concentration of sodium hexmetaphosphate with dodecyl-amine as collector. Fourier transform infrared spectra indicate that the absorbance band 875cm -1 of the asymmetric stretching vibration of bridge oxygen P—O—P shifts to 880cm -1 , and the 1264cm -1 of the asymmetric stretching vibration of the bridge PO2 shifts to 1267cm -1 in the diaspore’s spectra. This demonstrates that sodium hexmetaphosphate interacts through bridging PO2 groups with the Al atoms exposed on the diaspore and kaolinite surfaces to form P—O—Al bond. Adsorption measurements also testify that sodium hexmetaphosphate adsorbs easily on the surface of diaspore. The adsorption density of PO-3 on the surface of diaspore is about 4.7×10 -6 mol/m2, while that on the kaolinite is only about 3.5×10 -7 mol/m2 when pH value is 6.展开更多
The interaction mechanism of collector DLZ in the flotation process of chalcopyrite and pyrite was investigated through flotation experiments,zeta potential measurements and infrared spectrum analysis.Flotation test r...The interaction mechanism of collector DLZ in the flotation process of chalcopyrite and pyrite was investigated through flotation experiments,zeta potential measurements and infrared spectrum analysis.Flotation test results indicate that DLZ is the selective collector of chalcopyrite.Especially,the recovery of chalcopyrite is higher than 90% in neutral and weak alkaline systems,while the recovery of pyrite is less than 10%.When using CaO as pH regulator,at pH=7-11,the floatability of pyrite is depressed and the recovery is less than 5%.Zeta potential analysis shows that the zeta potential of chalcopyrite decreases more obviously than that of pyrite after interaction with DLZ,confirming that collector DLZ shows selectivity to chalcopyrite and pyrite.And FTIR results reveal that the flotation selectivity of collector DLZ is due to chemical absorption onto chalcopyrite surface and only physical absorption onto pyrite surface.展开更多
Froth image features of coal flotation have been extracted and studied by neighboring grey level dependence matrix, spatial grey level dependence matrix and grey level histogram. In this paper, a basic algorithm of un...Froth image features of coal flotation have been extracted and studied by neighboring grey level dependence matrix, spatial grey level dependence matrix and grey level histogram. In this paper, a basic algorithm of unsupervised learning pattern classification is presented, and coal flotation froth images are classified by means of self organizing map (SOM). By extracting features from 51 flotation froth images with laboratory column, four types of froth images are classified. The correct rate of SOM cluster is satisfactory. And a good relationship of froth type with average ash content is also observed.展开更多
Flotation column is widely used as the separation equipment for fine mineral due to its high selectivity. However, this device may be unsuitable for the coarse particle flotation and has high handling ability. A two-s...Flotation column is widely used as the separation equipment for fine mineral due to its high selectivity. However, this device may be unsuitable for the coarse particle flotation and has high handling ability. A two-stage flotation column with dimensions of 2 000 mm×1 000 mm×4 000 mm was designed to enhance the column flotation process. The energy input was modified by adjusting the flow rate and the head of circulating pump. The flotation column was designed with low energy input in the first stage(speed flotation stage) to recover easy-to-float materials quickly, and high energy input in the second stage(recovery stage) to recover difficult-to-float minerals compulsorily. Contrast experiments on the throughput and coarse coal recovery of high ash coal from the Kailuan Mine were conducted using conventional single-stage flotation column and the two-stage flotation column. The results show that the combustible matter recovery of the two-stage flotation column is 5.25% higher than that of the conventional single-stage flotation column. However, the ash contents of clean coal for both columns are similar. Less coarse coals with low ash are obtained using the two-stage flotation column than that using the single-stage column flotation with the same handling ability. The two-stage flotation column process can enhance coal flotation compared with the conventional single-stage column flotation.展开更多
Influence of factors such as potential of electrolyte, electrolyzing time, concentration of electrolyte, and pH value on flotation and desulfurization of coal was researched. The result shows that the electrochemical ...Influence of factors such as potential of electrolyte, electrolyzing time, concentration of electrolyte, and pH value on flotation and desulfurization of coal was researched. The result shows that the electrochemical reduction can enhance the desulfurization effect and increase the yield of clean coal under certain conditions. So it is an effective method.展开更多
The flotation process is a particle-hydrophobic surface-based separation technique. To improve the essential flotation steps of collision and attachment probabilities, and reduce the step of detachment probabilities b...The flotation process is a particle-hydrophobic surface-based separation technique. To improve the essential flotation steps of collision and attachment probabilities, and reduce the step of detachment probabilities between air bubbles and hydrophobic particles, a selectively designed cavitation venturi tube combined with a static mixer can be used to generate very high numbers of pico and nano bubbles in a flotation column. Fully embraced by those high numbers of tiny bubbles, hydrophobic particles readily attract the tiny bubbles to their surfaces. The results of column flotation of Pittsburgh No. 8 seam coal are obtained in a 5.08 cm ID and 162 cm height flotation column equipped with a static mixer and cavitation venturi tube, using kerosene as collector and MIBC as frother. Design of the experimental procedure is combined with a statistical two-stepwise analysis to determine the optimal operating conditions for maximum recovery at a specified grade. The effect of independent variables on the responses has been explained. Combustible material recovery of 85–90% at clean coal product of 10–11% ash is obtained from feed of 29.6% ash, with a much-reduced amount of frother and collector than that used in conventional column flotation. The column flotation process utilizing pico and nano bubbles can also be extended to the lower limit and upper limit of particle size ranges, minus 75 lm and 300–600 lm, respectively, for better recovery.展开更多
Pilot scale column flotation studies were conducted on a low grade siliceous limestone ore. Silica content was reduced to less than 13g in the concentrate so that it became satisfactory for use in the paper or rubber ...Pilot scale column flotation studies were conducted on a low grade siliceous limestone ore. Silica content was reduced to less than 13g in the concentrate so that it became satisfactory for use in the paper or rubber industries. The limestone sample was crystalline and constituted primarily of calcite that contained quartz, feldspar, pyroxene, and biotite as gangue minerals. Quartz is the major silicate gangue whereas feldspar, pyroxene, and biotite exist in minor to trace quantities. Traces of pyrite were also observed within the sample. A reverse flotation process was adopted where the silicate gangue minerals were floated using two different commercial cationic collectors: Chem-750 F or Floatamine-D. The studies clearly suggest it is possible to produce a limestone concentrate assaying around 96-97% CaCO3 containing less than 1 % Si02. The effect of feed flow rate, percent solids, froth depth, and wash water on the grade and recovery of the CaC03 concentrate is discussed.展开更多
The electrode process of diethyldithiocarbamate on the surface of pyrrhotite was studied using systematic electrochemical analysis, including cyclic voltammetry, chronopotentiometry and galvanostatic. Experimental res...The electrode process of diethyldithiocarbamate on the surface of pyrrhotite was studied using systematic electrochemical analysis, including cyclic voltammetry, chronopotentiometry and galvanostatic. Experimental results show that tetraethylthioram disulphide(TETD) is electrodeposited on pyrrhotite electrode surface in the presence of 1.0×10^-4 mol/L diethyldithiocarbamate when the electrode potential is higher than 0.25 V. The electrochemical kinetics parameters of the electrode process of diethyldithiocarbamate on surface of pyrrhotite are calculated as follows: the exchange current density is 2.48μA/cm^2 , and the transmission coefficient is 0.46. The electrodeposition includes two steps electrochemical reaction. The first reaction is electrochemical adsorption of diethyldithiocarbamatc ion, then the adsorbed ion associates with a diethyldithiocarbamate ion from the solution and forms tetraethylthioram disulphide on the surface of pyrrhotite.展开更多
Effect of frothers in preventing bubble coalescence during flotation of minerals has long been investigated.To evaluate the performance of a frother,an apparatus to measure the bubble size is a basic necessity.McGill ...Effect of frothers in preventing bubble coalescence during flotation of minerals has long been investigated.To evaluate the performance of a frother,an apparatus to measure the bubble size is a basic necessity.McGill Bubble Size Analyzer(MBSA) or bubble viewer that has been developed and completed by McGill University's Mineral Processing Group during the last decade is a unique instrument to serve this purpose.Two parameters which are thought to influence the bubble size measurements by McGill bubble viewer include water quality and frother concentration in the chamber.Results show that there is no difference in Sauter mean(D32) when tap or de-ionized water was used instead of process water.However,the frother concentration,in this research DowFroth 250(DF250),inside the chamber exhibited a pronounced effect on bubble size.Frother concentration below a certain point can not prevent coalescence inside the chamber and therefore caution must be taken in plant applications.It was also noted that the frother concentration which has been so far practiced in plant measurements(CCC75-CCC95) is high enough to prevent coalescence with the bubble viewer.展开更多
Effect of magnetization on oxygen concentration, pH, surface zeta potential, and wet heat of flotation pulp were researched. The result shows that magnetization treatment can improve the floatablility of coal and incr...Effect of magnetization on oxygen concentration, pH, surface zeta potential, and wet heat of flotation pulp were researched. The result shows that magnetization treatment can improve the floatablility of coal and increase the difference in wet heat among coal, refuse, and pyrite, which is favorable for slime flotation and for removing sulfur and ash from coal.展开更多
In this paper an attempt is made to recover sillimanite by flotation tree analysis process and conventional flotation process from non magnetic fraction of red sediments.The experimental results of both the processes ...In this paper an attempt is made to recover sillimanite by flotation tree analysis process and conventional flotation process from non magnetic fraction of red sediments.The experimental results of both the processes are presented.The data reveal that the deslimed sample contains 33.2%(by weight) total heavy minerals and out of which the sillimanite mineral content is 3.6%(by weight).It is observed that flotation tree analysis needs 10 cells to get five output products and where as conventional flotation process needs 15 cells to recover similar grade of five output products.Thus,flotation tree analysis is not only economic process but also efficient process(to say efficient process,the tree analysis product should be higher grade).展开更多
Conventional feature description methods have large errors in froth features due to the fact that the image during the zinc flotation process of froth flotation is dynamic,and the existing image features rarely have t...Conventional feature description methods have large errors in froth features due to the fact that the image during the zinc flotation process of froth flotation is dynamic,and the existing image features rarely have time series information.Based on the conventional froth size distribution characteristics,this paper proposes a size trend core feature(STCF)considering the froth size distribution,i.e.,a feature centered on the time series of the froth size distribution.The core features of the trend are extracted,the inter-frame change factor and the inter-frame stability factor are given and two calculation methods of the feature factors are proposed.Meanwhile,the STCF feature algorithm was established based on the core features by adding the inter-frame change factor and the inter-frame stability factor.Finally,a flotation condition recognition model based on BP neural network was established.The experiments show that the recognition model has achieved excellent results,proving that the method proposed effectively overcomes the limitation of the lack of dynamic information in the existing traditional size distribution features and the introduction of the two factors can improve the classification accuracy to varying degrees.展开更多
文摘In order to offer high grade concentrate to produce alumina by Bayer, the reverse-flotation technology of bauxite was investigated. The results show that sodium hexmetaphosphate has different depression on the flotation of diaspore and kaolinite. The recoveries of diaspore decrease markedly with the increase of the concentration of sodium hexmetaphosphate with dodecyl-amine as collector. Fourier transform infrared spectra indicate that the absorbance band 875cm -1 of the asymmetric stretching vibration of bridge oxygen P—O—P shifts to 880cm -1 , and the 1264cm -1 of the asymmetric stretching vibration of the bridge PO2 shifts to 1267cm -1 in the diaspore’s spectra. This demonstrates that sodium hexmetaphosphate interacts through bridging PO2 groups with the Al atoms exposed on the diaspore and kaolinite surfaces to form P—O—Al bond. Adsorption measurements also testify that sodium hexmetaphosphate adsorbs easily on the surface of diaspore. The adsorption density of PO-3 on the surface of diaspore is about 4.7×10 -6 mol/m2, while that on the kaolinite is only about 3.5×10 -7 mol/m2 when pH value is 6.
基金Project(50674102) supported by the National Natural Science Foundation of China
文摘The interaction mechanism of collector DLZ in the flotation process of chalcopyrite and pyrite was investigated through flotation experiments,zeta potential measurements and infrared spectrum analysis.Flotation test results indicate that DLZ is the selective collector of chalcopyrite.Especially,the recovery of chalcopyrite is higher than 90% in neutral and weak alkaline systems,while the recovery of pyrite is less than 10%.When using CaO as pH regulator,at pH=7-11,the floatability of pyrite is depressed and the recovery is less than 5%.Zeta potential analysis shows that the zeta potential of chalcopyrite decreases more obviously than that of pyrite after interaction with DLZ,confirming that collector DLZ shows selectivity to chalcopyrite and pyrite.And FTIR results reveal that the flotation selectivity of collector DLZ is due to chemical absorption onto chalcopyrite surface and only physical absorption onto pyrite surface.
基金National Natural Science Foundation of China( 5 99740 32 )
文摘Froth image features of coal flotation have been extracted and studied by neighboring grey level dependence matrix, spatial grey level dependence matrix and grey level histogram. In this paper, a basic algorithm of unsupervised learning pattern classification is presented, and coal flotation froth images are classified by means of self organizing map (SOM). By extracting features from 51 flotation froth images with laboratory column, four types of froth images are classified. The correct rate of SOM cluster is satisfactory. And a good relationship of froth type with average ash content is also observed.
基金Project(2012CB214905)supported by the National Basic Research Program of ChinaProject(51074157)supported by the National Natural Science Foundation of China
文摘Flotation column is widely used as the separation equipment for fine mineral due to its high selectivity. However, this device may be unsuitable for the coarse particle flotation and has high handling ability. A two-stage flotation column with dimensions of 2 000 mm×1 000 mm×4 000 mm was designed to enhance the column flotation process. The energy input was modified by adjusting the flow rate and the head of circulating pump. The flotation column was designed with low energy input in the first stage(speed flotation stage) to recover easy-to-float materials quickly, and high energy input in the second stage(recovery stage) to recover difficult-to-float minerals compulsorily. Contrast experiments on the throughput and coarse coal recovery of high ash coal from the Kailuan Mine were conducted using conventional single-stage flotation column and the two-stage flotation column. The results show that the combustible matter recovery of the two-stage flotation column is 5.25% higher than that of the conventional single-stage flotation column. However, the ash contents of clean coal for both columns are similar. Less coarse coals with low ash are obtained using the two-stage flotation column than that using the single-stage column flotation with the same handling ability. The two-stage flotation column process can enhance coal flotation compared with the conventional single-stage column flotation.
基金The National Natural Science F oundation of China ( 5 0 1740 5 4)
文摘Influence of factors such as potential of electrolyte, electrolyzing time, concentration of electrolyte, and pH value on flotation and desulfurization of coal was researched. The result shows that the electrochemical reduction can enhance the desulfurization effect and increase the yield of clean coal under certain conditions. So it is an effective method.
基金provided by West Virginia State Coal and Energy Research Bureau (CERB)the Department of Mining Engineering,West Virginia University
文摘The flotation process is a particle-hydrophobic surface-based separation technique. To improve the essential flotation steps of collision and attachment probabilities, and reduce the step of detachment probabilities between air bubbles and hydrophobic particles, a selectively designed cavitation venturi tube combined with a static mixer can be used to generate very high numbers of pico and nano bubbles in a flotation column. Fully embraced by those high numbers of tiny bubbles, hydrophobic particles readily attract the tiny bubbles to their surfaces. The results of column flotation of Pittsburgh No. 8 seam coal are obtained in a 5.08 cm ID and 162 cm height flotation column equipped with a static mixer and cavitation venturi tube, using kerosene as collector and MIBC as frother. Design of the experimental procedure is combined with a statistical two-stepwise analysis to determine the optimal operating conditions for maximum recovery at a specified grade. The effect of independent variables on the responses has been explained. Combustible material recovery of 85–90% at clean coal product of 10–11% ash is obtained from feed of 29.6% ash, with a much-reduced amount of frother and collector than that used in conventional column flotation. The column flotation process utilizing pico and nano bubbles can also be extended to the lower limit and upper limit of particle size ranges, minus 75 lm and 300–600 lm, respectively, for better recovery.
文摘Pilot scale column flotation studies were conducted on a low grade siliceous limestone ore. Silica content was reduced to less than 13g in the concentrate so that it became satisfactory for use in the paper or rubber industries. The limestone sample was crystalline and constituted primarily of calcite that contained quartz, feldspar, pyroxene, and biotite as gangue minerals. Quartz is the major silicate gangue whereas feldspar, pyroxene, and biotite exist in minor to trace quantities. Traces of pyrite were also observed within the sample. A reverse flotation process was adopted where the silicate gangue minerals were floated using two different commercial cationic collectors: Chem-750 F or Floatamine-D. The studies clearly suggest it is possible to produce a limestone concentrate assaying around 96-97% CaCO3 containing less than 1 % Si02. The effect of feed flow rate, percent solids, froth depth, and wash water on the grade and recovery of the CaC03 concentrate is discussed.
文摘The electrode process of diethyldithiocarbamate on the surface of pyrrhotite was studied using systematic electrochemical analysis, including cyclic voltammetry, chronopotentiometry and galvanostatic. Experimental results show that tetraethylthioram disulphide(TETD) is electrodeposited on pyrrhotite electrode surface in the presence of 1.0×10^-4 mol/L diethyldithiocarbamate when the electrode potential is higher than 0.25 V. The electrochemical kinetics parameters of the electrode process of diethyldithiocarbamate on surface of pyrrhotite are calculated as follows: the exchange current density is 2.48μA/cm^2 , and the transmission coefficient is 0.46. The electrodeposition includes two steps electrochemical reaction. The first reaction is electrochemical adsorption of diethyldithiocarbamatc ion, then the adsorbed ion associates with a diethyldithiocarbamate ion from the solution and forms tetraethylthioram disulphide on the surface of pyrrhotite.
基金Project supported by the Chair in Mineral Processing at McGill University,under the Collaborative Research and Development Program of NSERC(Natural Sciences and Engineering Research Council of Canada)with industrial sponsorship from Vale,Teck Cominco,Xstrata Process Support,Agnico-Eagle,Shell Canada,Barrick Gold,COREM,SGS Lakefield Research and Flottec
文摘Effect of frothers in preventing bubble coalescence during flotation of minerals has long been investigated.To evaluate the performance of a frother,an apparatus to measure the bubble size is a basic necessity.McGill Bubble Size Analyzer(MBSA) or bubble viewer that has been developed and completed by McGill University's Mineral Processing Group during the last decade is a unique instrument to serve this purpose.Two parameters which are thought to influence the bubble size measurements by McGill bubble viewer include water quality and frother concentration in the chamber.Results show that there is no difference in Sauter mean(D32) when tap or de-ionized water was used instead of process water.However,the frother concentration,in this research DowFroth 250(DF250),inside the chamber exhibited a pronounced effect on bubble size.Frother concentration below a certain point can not prevent coalescence inside the chamber and therefore caution must be taken in plant applications.It was also noted that the frother concentration which has been so far practiced in plant measurements(CCC75-CCC95) is high enough to prevent coalescence with the bubble viewer.
基金Naturalscience Research Programmer of Jiangsu Province High School P.R.C( 0 3 KJB44 0 13 3 ) China Postdoctoral ScienceFoundation( 2 0 0 3 0 3 3 3 3 7) +1 种基金China Coal Science F oundation( 97Process1190 7) Creative Programmer of Key UniversityTeachers
文摘Effect of magnetization on oxygen concentration, pH, surface zeta potential, and wet heat of flotation pulp were researched. The result shows that magnetization treatment can improve the floatablility of coal and increase the difference in wet heat among coal, refuse, and pyrite, which is favorable for slime flotation and for removing sulfur and ash from coal.
文摘In this paper an attempt is made to recover sillimanite by flotation tree analysis process and conventional flotation process from non magnetic fraction of red sediments.The experimental results of both the processes are presented.The data reveal that the deslimed sample contains 33.2%(by weight) total heavy minerals and out of which the sillimanite mineral content is 3.6%(by weight).It is observed that flotation tree analysis needs 10 cells to get five output products and where as conventional flotation process needs 15 cells to recover similar grade of five output products.Thus,flotation tree analysis is not only economic process but also efficient process(to say efficient process,the tree analysis product should be higher grade).
基金Project(U1701261)supported by the National Science Foundation of China,Guangdong Joint Fund of Key ProjectsProject(61771492)supported by the National Natural Science Foundation of ChinaProject(2018GK4016)supported by Hunan Province Strategic Emerging Industry Science and Technology Research and Major Science and Technology Achievement Transformation Project,China。
文摘Conventional feature description methods have large errors in froth features due to the fact that the image during the zinc flotation process of froth flotation is dynamic,and the existing image features rarely have time series information.Based on the conventional froth size distribution characteristics,this paper proposes a size trend core feature(STCF)considering the froth size distribution,i.e.,a feature centered on the time series of the froth size distribution.The core features of the trend are extracted,the inter-frame change factor and the inter-frame stability factor are given and two calculation methods of the feature factors are proposed.Meanwhile,the STCF feature algorithm was established based on the core features by adding the inter-frame change factor and the inter-frame stability factor.Finally,a flotation condition recognition model based on BP neural network was established.The experiments show that the recognition model has achieved excellent results,proving that the method proposed effectively overcomes the limitation of the lack of dynamic information in the existing traditional size distribution features and the introduction of the two factors can improve the classification accuracy to varying degrees.