目的建立基于^(87)Sr/^(86)Sr和δ^(13)C稳定同位素比质谱法(stable isotope ratio mass spectrometry,IRMS)的进口大麦产地溯源技术。方法样品干燥粉碎后,经硝酸消解,锶特效树脂净化后利用热电离质谱法(thermal ionization mass spectr...目的建立基于^(87)Sr/^(86)Sr和δ^(13)C稳定同位素比质谱法(stable isotope ratio mass spectrometry,IRMS)的进口大麦产地溯源技术。方法样品干燥粉碎后,经硝酸消解,锶特效树脂净化后利用热电离质谱法(thermal ionization mass spectrometry,TIMS)分析检测^(87)Sr/^(86);样品用锡囊包裹后,利用元素分析-稳定同位素比质谱法分析检测δ^(13)C;利用SPSS 25.0软件对进口大麦的^(87)Sr/^(86)Sr和δ^(13)C进行正态性验证、方差分析、事后多重比较分析和判别分析。结果不同进口国大麦中的^(87)Sr/^(86)Sr和δ^(13)C具有显著性差异,经判别分析,进口自澳大利亚、法国和美国的大麦可以达到100%正确判别率,整体正确判别率达到86.2%,若将美国和加拿大进口的大麦归类为北美洲进口大麦,则可实现进口自北美、法国和澳大利亚大麦的100%正确判别率。结论利用^(87)Sr/^(86)Sr和δ^(13)C可以对不同进口国大麦进行产地溯源分析。展开更多
We analyzed the ^(87)Sr/^(86)Sr ratios of basaltic rocks and basin water in Xuyi,China,and found a big difference,which may challenge conventional wisdom on the contribution of basalt weathering in end-member analysis...We analyzed the ^(87)Sr/^(86)Sr ratios of basaltic rocks and basin water in Xuyi,China,and found a big difference,which may challenge conventional wisdom on the contribution of basalt weathering in end-member analysis.Results of an in-house weathering experiment suggest that rainwater and dust are not responsible for the difference.By isolating the major minerals in basalt,we found that plagioclase has much higher ^(87)Sr/^(86)Sr ratios than bulk basalt and basin water,which might explain the difference in ^(87)Sr/^(86)Sr ratios of basalt and basin water.We inferthatlow-temperaturehydrothermalalteration increased the ^(87)Sr/^(86)Sr ratios of plagioclase.Future analyses of end-member contribution in a mixed-rock basin should take into account that basin water and plagioclase have higher ^(87)Sr/^(86)Sr ratios than basaltic rocks.展开更多
To analyze the genesis of Sr isotopes in groundwater of Hebei plain, time-accumulative effect of ^87Sr/^86Sr ratio was studied. It is shown that ^87Sr/^86Sr ratio increases with the increasing age and depth of groundw...To analyze the genesis of Sr isotopes in groundwater of Hebei plain, time-accumulative effect of ^87Sr/^86Sr ratio was studied. It is shown that ^87Sr/^86Sr ratio increases with the increasing age and depth of groundwater and has a positive correlation to 4Heexc and a negative correlation to δ^18O and δD.The groundwater is divided into three groups to discuss the relation between ^87Sr/^86Sr ratio and Sr^2＋ content： ① moderate Sr^2＋ content and higher ^87Sr/^86Sr ratio （water Ⅰ）; ② lower Sr^2＋ content and higher ^87Sr/^86Sr ratio （water Ⅱ）; and ③ higher Sr^2＋ content and lower ^87Sr/^86Sr ratio （water Ⅲ）, that is hot water. On the basis of integrated analysis, it was considered that ① the radiogenic Sr in the Quaternary groundwater （Q4-Q1） originates from weathering of silicate rich in Na and Rb, mainly from plagioclase; ② the radiogenic Sr of hot water in Huanghua port is attributed to carbonate dissolution, with lower ^87Sr/^86Sr ratio and higher Sr/Na ratio; ③ the recharge area is laterally recharged by the groundwater flowing through igneous and metamorphic rocks, with moderate ^87Sr/^86Sr ratio. However, the formation mechanism of Sr isotopes in Tertiary groundwater needs further studies.展开更多
文摘目的建立基于^(87)Sr/^(86)Sr和δ^(13)C稳定同位素比质谱法(stable isotope ratio mass spectrometry,IRMS)的进口大麦产地溯源技术。方法样品干燥粉碎后,经硝酸消解,锶特效树脂净化后利用热电离质谱法(thermal ionization mass spectrometry,TIMS)分析检测^(87)Sr/^(86);样品用锡囊包裹后,利用元素分析-稳定同位素比质谱法分析检测δ^(13)C;利用SPSS 25.0软件对进口大麦的^(87)Sr/^(86)Sr和δ^(13)C进行正态性验证、方差分析、事后多重比较分析和判别分析。结果不同进口国大麦中的^(87)Sr/^(86)Sr和δ^(13)C具有显著性差异,经判别分析,进口自澳大利亚、法国和美国的大麦可以达到100%正确判别率,整体正确判别率达到86.2%,若将美国和加拿大进口的大麦归类为北美洲进口大麦,则可实现进口自北美、法国和澳大利亚大麦的100%正确判别率。结论利用^(87)Sr/^(86)Sr和δ^(13)C可以对不同进口国大麦进行产地溯源分析。
基金Support for this work comes from National Natural Science Foundation of China(Grant No.41422205)
文摘We analyzed the ^(87)Sr/^(86)Sr ratios of basaltic rocks and basin water in Xuyi,China,and found a big difference,which may challenge conventional wisdom on the contribution of basalt weathering in end-member analysis.Results of an in-house weathering experiment suggest that rainwater and dust are not responsible for the difference.By isolating the major minerals in basalt,we found that plagioclase has much higher ^(87)Sr/^(86)Sr ratios than bulk basalt and basin water,which might explain the difference in ^(87)Sr/^(86)Sr ratios of basalt and basin water.We inferthatlow-temperaturehydrothermalalteration increased the ^(87)Sr/^(86)Sr ratios of plagioclase.Future analyses of end-member contribution in a mixed-rock basin should take into account that basin water and plagioclase have higher ^(87)Sr/^(86)Sr ratios than basaltic rocks.
基金This paper is supported by China Geological Survey Project (No. 200320150002).
文摘To analyze the genesis of Sr isotopes in groundwater of Hebei plain, time-accumulative effect of ^87Sr/^86Sr ratio was studied. It is shown that ^87Sr/^86Sr ratio increases with the increasing age and depth of groundwater and has a positive correlation to 4Heexc and a negative correlation to δ^18O and δD.The groundwater is divided into three groups to discuss the relation between ^87Sr/^86Sr ratio and Sr^2＋ content： ① moderate Sr^2＋ content and higher ^87Sr/^86Sr ratio （water Ⅰ）; ② lower Sr^2＋ content and higher ^87Sr/^86Sr ratio （water Ⅱ）; and ③ higher Sr^2＋ content and lower ^87Sr/^86Sr ratio （water Ⅲ）, that is hot water. On the basis of integrated analysis, it was considered that ① the radiogenic Sr in the Quaternary groundwater （Q4-Q1） originates from weathering of silicate rich in Na and Rb, mainly from plagioclase; ② the radiogenic Sr of hot water in Huanghua port is attributed to carbonate dissolution, with lower ^87Sr/^86Sr ratio and higher Sr/Na ratio; ③ the recharge area is laterally recharged by the groundwater flowing through igneous and metamorphic rocks, with moderate ^87Sr/^86Sr ratio. However, the formation mechanism of Sr isotopes in Tertiary groundwater needs further studies.
