海底单极直流输电中海水作为输电回路的原理实验及分析

海底观测网的供电具有长期、连续、远距离的特点,采用单极直流输电方案成为一种趋势。单极直流输电采用光电复合缆中的一根铜线和海水作为输电回路,既节约了成本又减少了输电回路的损耗。文中分析了单极直流输电模式中海水作为输电回路的关键技术,通过实验验证了海水回路电阻的主要影响因素,并分析了海水作为输电回路对海洋环境、人类、海洋生命安全的影响。

Electrochemical properties of magnesium alloy anodes discharged in seawater

Magnesium alloys can be developed as anode materials for seawater activated batteries. The electrochemical properties of AZ31, AP65 and Mg-3%Ga-2%Hg alloy anodes discharged in seawater were studied. The potentiodynamic polarization shows that the Mg-3%Ga-2%Hg alloy provides more negative corrosion potentials than AZ31 or AP65 alloy. The galvanostatic discharge results show that the Mg-3%Ga-2%Hg alloy exhibits good electrochemical properties as anodes in seawater. And the EIS studies reveal that the magnesium alloy anode/seawater interfacial process is determined by an activation controlled reaction. The Mg3Hg and Mg21Ga5Hg3 phases in Mg-3%Ga-2%Hg alloy improve its electrochemical properties better than the Mg17（Al,Zn）12 phase in AZ31 and Mg（Pb） solid solution phase in AP65 alloys.

Discharge behavior and electrochemical properties of Mg-Al-Sn alloy anode for seawater activated battery

Mg-Al-Sn alloy is one of the new developed anode materials for seawater activated batteries. The potentiodynamic polarization, galvanostatic discharge and electrochemical impedance spectroscopy of Mg-6%Al-1%Sn and Mg-6%Al-5%Sn(mass fraction) alloys in seawater were studied and compared with the commercial AZ31 and AP65 alloys. The results show that the Mg-6%Al-1%Sn alloy obtains the most negative discharge potential of average-1.611V with a electric current density of 100 mA/cm2. EIS studies reveal that the Mg-Al-Sn alloy/seawater interfacial electrochemical process is determined by an activation controlled reaction. The assembled prototype batteries with Mg-6%Al-1%Sn alloy as anodes and Ag Cl as cathodes exhibit a satisfactory integrated discharge properties.

SICPS-5型外加电流保护装置电位漂移故障分析与排除

SICPS-5型外加电流保护装置是通过外加电流对船舶不同部位进行防腐防污实施保护的装置,文章利用该型装置首次自主修理,对装置的工作原理进行阐述,对电位漂移故障现象进行综合分析,并对分析结果逐一排查,最终得出导致故障现象的本质原因。

Corrosion behavior of 907 steel under thin electrolyte layers of artificial seawater

The corrosion behavior of 907 steel under thin electrolyte layer(TEL) has been investigated by means of cathodic polarization curve measurement, electrochemical impedance spectroscopy(EIS) and scanning electron microscopy(SEM). The results show that the cathodic diffusion current density presents the variation trend of initial increase and subsequent decrease with the decrease of TEL thickness, and the maximum deposits at 58 μm. The cotangent-hyperbolic impedance(O) is rationally first introduced to study the diffusion process of the reactants through the corrosion products layer with many permeable holes. The initial corrosion rate of 907 steel under different TEL thickness increases with the decrease of TEL thickness except that of 104 μm,whereas the corrosion rate after long time corrosion can be ranked as 104 μm﹥402 μm﹥198 μm﹥301 μm﹥bulk solution.

Effects of Uncertainties in the Position and Orientation of Both the Transmitter and Receivers on Marine Controlled-Source Electromagnetic Data

Simulation and interpretation of marine controlled-source electromagnetic(CSEM) data often approximate the transmitter source as an ideal horizontal electric dipole(HED) and assume that the receivers are located on a flat seabed.Actually,however,the transmitter dipole source will be rotated,tilted and deviated from the survey profile due to ocean currents.And free-fall receivers may be also rotated to some arbitrary horizontal orientation and located on sloping seafloor.In this paper,we investigate the effects of uncertainties in the transmitter tilt,transmitter rotation and transmitter deviation from the survey profile as well as in the receiver's location and orientation on marine CSEM data.The model study shows that the uncertainties of all position and orientation parameters of both the transmitter and receivers can propagate into observed data uncertainties,but to a different extent.In interpreting marine data,field data uncertainties caused by the position and orientation uncertainties of both the transmitter and receivers need to be taken into account.

Use of microelectrodes for electrochemical measurement of nitric oxide in natural seawater

In this paper, the application of a homemade Nafion and Co(Salen) modified platinum microelec-trode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nafion and Co(Salen) modified platinum microelectrode.

Electromagnetic fields from a horizontal electrical dipole buried in ocean

Marine controlled source electromagnetic signal could be used in mineral resource exploration,reservoir appraisal and communicative technique in ocean. It's necessary to study the electromagnetic generated by MCSEM. The propagation of the electromagnetic fields from a controlled source in the marine environment was studied with virtual interface method combined with discrete complex image method. Transmitter of finite length current source is approximated by dipole (HED) . A three-layered model is accepted,with sea water as intermediate conductive layer under air and a relatively high resistive seabed as basement,possibly containing a hydrogen layer of higher resistivity. The electromagnetic fields in whole space thus computed show that: (1) the spatial distribution of field component depends on its type; (2) inline Ex component is more sensitive to reservoir layer than that in broadside; (3) The airwave affects marine electromagnetic (MEM) exploration when sea water is relatively shallow; in the case of deep water MEM exploration,the airwave influence could be neglected; and (4) an appropriate frequency should be selected in order to balance the signal strength and electromagnetic induction effect.

研究新型高压直流连接线的环境要求

意大利撒丁岛与意大利半岛之间新建的高压直流海底输电项目(SAPEI)的额定输送容量为1000MW,±500kV直流,跨海长度超过400km。在开发此项目过程中,环保要求起到了非常重要的作用。在项目立项报批过程中,解决了几项技术问题。